Pd (II)‐catalyzed vinyl addition polymerization of novel functionalized norbornene bearing dimethyl carboxylate groups

Three novel functionalized polynorbornenes (PNB) with pendant dimethyl carboxylate group (carboxylates—acetate, propionate, and butyrate) are synthesized as a vinyl‐type with a palladium (II) catalyst in high yield. The effects of size of substitutents, molar ratio of monomer to catalyst, solvent polarity, reaction time, and temperature on the polymerization of exo‐norbornene dimethyl propionate were systematically investigated. The low molar ratio and temperature, as well as high polarity of solvent, and long reaction time, are favorable for the enhancement of the monomer conversion, especially, the solvent have an obvious effect on the catalyst activity. The resulting poly(cis‐norbornene‐exo‐2,3‐dimethyl carboxylates) (PNB‐dimethyl carboxylates) show good solubility in common organic solvent and high thermal stability up to 360 °C. The glass transition temperature was detected by DMA at 331, 324, and 318 °C for acetate, propionate, and butyrate, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3391–3399, 2007     

用超磁致伸缩调谐光纤光栅的光分/插复用器

提出并研究了一种新型多信道切换的全光分/插复用器,它主要由光纤Bragg光栅(FBG)和一对光环行器组成.采用了一种高效的超磁致伸缩材料(GMM)使FBG产生有效的Bragg波长偏移.用控制电流来调控FBG的应变和Bragg波长偏移.用4只相同的FBG与波长叠加技术相结合,可建立能提供15种不同下路信道方式的OADM.     

CH3S CH2SH异化反应的理论研究

利用密度泛函理论(DFT)和从头算(ab initio)研究了CH3S←→CH2SH互异化的反应机理．采用HF、B3LYP、MP2理论水平和中等基组6-31(d)，计算了CH3S、CH2SH及其过渡态的结构参数、谐振频率、零点能(ZPF)、总能量和相对能量，并利用B3LYP／6-31(d)的方法计算了反应的内禀反应坐标(IRC)，给出了分子构型和自旋污染沿反应坐标的变化曲线，以及最小能量曲线(MEP)、绝热能量曲线．此外，利用传统过渡态理论(CTST)研究了该互异化反应的速率常数和平衡常数在200～1000K的变化．     

Response to high acidity and basicity at a platinum electrode in chronopotentiometry

A simple and rapid method is developed to determine the high acidity and the basicity of solutions by chronopotentiometry with a platinum working electrode. The acidity range from 5.0 mol/l H⁺ to 1.0 mol/l OH⁻ can be measured by the adjustment of deposition potential and time. The response mechanism to acidity and basicity has been explored. The transition potential plateau in chronopotentiograms is caused from the oxidation of hydrogen adsorbed on electrode surface.     

荧光光纤温度传感器激励光源的选择

本文分析计算了荧光光纤温度传感器的温敏元件——GsAlAs/GaAs双异质结半导体材料的荧光辐射效率与激励光波长的关系。讨论了温度测量范围及温敏元件GaAlAs层铝含量对激励光源的限制,在0～200℃测温范围内,若采用LED作激励光源,其峰值波长应在0.70～0.76μm之间选择。     

On the Strong Law of Large Numbers and the Law of the Logarithm for Weighted Sums of Independent Random Variables with Multidimensional Indices

Let (X, X ; ^d} be a field of independent identically distributed real random variables, 0 < p < 2, and {a _, ; ( , ) ^d × ^d, ≤ } a triangular array of real numbers, where ^d is the d-dimensional lattice. Under the minimal condition that sup _, |a _, | < ∞, we show that | |^{− 1/p} ∑ _≤ a _, X → 0 a.s. as | | → ∞ if and only if E(|X|^p(L|X|)^{d − 1}) < ∞ provided d ≥ 2. In the above, if 1 ≤ p < 2, the random variables are needed to be centered at the mean. By establishing a certain law of the logarithm, we show that the Law of the Iterated Logarithm fails for the weighted sums ∑ _≤ a _, X under the conditions that EX = 0, EX² < ∞, and E(X²(L|X|)^{d − 1}/L₂|X|) < ∞ for almost all bounded families {a _, ; ( , ) ^d × ^d, ≤ of numbers.     

Existence of weak solution and semiclassical limit for quantum drift-diffusion model

The existence and semiclassical limit of the solution to one-dimensional transient quantum drift-diffusion model in semiconductor simulation are discussed. Besides the proof of existence of the weak solution, it is also obtained that the semiclassical limit of this solution solves the classical drift-diffusion model. The key estimates rest on the entropy inequalities derived from separation of quantum quasi-Fermi level.     

Monte Carlo simulations on magnetic behavior of a spin-chain system in triangular lattice doped with antiferromagnetic bonds

A three-dimensional Ising-like model doped with anti-ferromagnetic (AFM) bonds is proposed to investigate the magnetic properties of a doped triangular spin-chain system by using a Monte-Carlo simulation. The simulated results indicate that a steplike magnetization behavior is very sensitive to the concentration of AFM bonds. A low concentration of AFM bonds can suppress the stepwise behavior considerably, in accordance with doping experiments on Ca₃Co₂O₆. The analysis of spin snapshots demonstrates that the AFM bond doping not only breaks the ferromagnetic ordered linear spin chains along the hexagonal c-axis but also has a great influence upon the spin configuration in the ab-plane.      

具有突变结构开放腔的矩阵分析

利用模式展开与场匹配原理，建立了突变波导的散射矩阵(S参数矩阵)，在此基础上分析研究了具有突变结构的波导开放式谐振腔，并由矩阵级联建立了开放腔总的S参数矩阵.通过Matlab编制计算程序对具有多级突变结构的开放式输出腔进行了数值计算和分析，并通过与实验数据和软件模拟的结果比较对该方法得到的数据结果进行了验证. 关键词： 回旋管 开放式谐振腔 突变结构 S参数矩阵