首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   26215篇
  免费   4521篇
  国内免费   3009篇
化学   18750篇
晶体学   260篇
力学   1541篇
综合类   147篇
数学   2855篇
物理学   10192篇
  2024年   102篇
  2023年   603篇
  2022年   984篇
  2021年   1065篇
  2020年   1178篇
  2019年   1109篇
  2018年   995篇
  2017年   858篇
  2016年   1292篇
  2015年   1288篇
  2014年   1536篇
  2013年   1907篇
  2012年   2335篇
  2011年   2294篇
  2010年   1572篇
  2009年   1441篇
  2008年   1529篇
  2007年   1436篇
  2006年   1371篇
  2005年   1178篇
  2004年   866篇
  2003年   733篇
  2002年   775篇
  2001年   551篇
  2000年   522篇
  1999年   596篇
  1998年   470篇
  1997年   458篇
  1996年   450篇
  1995年   383篇
  1994年   321篇
  1993年   261篇
  1992年   221篇
  1991年   191篇
  1990年   202篇
  1989年   153篇
  1988年   111篇
  1987年   70篇
  1986年   83篇
  1985年   80篇
  1984年   41篇
  1983年   33篇
  1982年   31篇
  1981年   25篇
  1980年   11篇
  1979年   3篇
  1977年   3篇
  1957年   4篇
  1930年   5篇
  1916年   3篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
991.
In this study we investigate the collective behavior of the generalized Kuramoto model with an external pinning force in which oscillators with positive and negative coupling strengths are conformists and contrarians, respectively. We focus on a situation in which the natural frequencies of the oscillators follow a uniform probability density. By numerically simulating the model, it is shown that the model supports multistable synchronized states such as a traveling wave state, π state and periodic synchronous state: an oscillating π state. The oscillating π state may be characterized by the phase distribution oscillating in a confined region and the phase difference between conformists and contrarians oscillating around π periodically. In addition, we present the parameter space of the oscillating π state and traveling wave state of the model.  相似文献   
992.
We study the Einstein-Podolsky-Rosen steering and quantum phase transitions of the transverse Ising and antiferromagnetic XXZ spin-1/2 chains. By making use of steerable weight, we calculate the steerability for the bipartite subsystems of the models. It is shown that steerability vanishes abruptly and its value maintains zero in a region close to the critical point for the Ising chain. This result is quite different from the information provided by entanglement and quantum discord. While for the XXZ chain, steerability increases and reaches maximal at the critical point, indicating the occurrence of quantum phase transition.  相似文献   
993.
Effective measurement of the reflective or transparent surface of an object has always been a disadvantage in laser scanning modeling. We propose a fast and complete three-dimensional (3D) reconstruction method for small static objects using laser scanning and the structure from motion (SFM) algorithm. Meanwhile, a complete reconstruction workflow is designed and a multi-angle 3d reconstruction system is set up. To generate the complete point cloud model of the object, the SFM algorithm is used to reconstruct the surface part of the object, the data for which cannot be obtained by the laser measuring instrument. The experimental results show that this method not only improves the speed, accuracy, integrity, and visual effect of 3D reconstruction of small objects, but also extends the scope of 3D reconstruction of laser measurement.  相似文献   
994.
Solution synthesis of ZnO nanotubes via a template-free hydrothermal route   总被引:1,自引:0,他引:1  
ZnO nanotubes were successfully synthesized by a simple template-free hydrothermal method. X-ray powder diffraction and transmission electron microscopy were used to characterize the as-prepared ZnO nanotubes. The average size of the nanotubes is 200-500 nm in length and 20-30 nm in diameter. In addition, a further investigation of the optimized synthetic conditions has been carried out.  相似文献   
995.
The chemisorption and dissociation pathways of NO on the Rh(1 0 0), (1 1 0), and (1 1 1) surfaces are studied by the plane-wave density functional theory (DFT) with CASTEP program. In addition, the electronic and geometrical effects that affect the NO dissociation reactions have been investigated in detail. The calculation results are presented as following: The effective activation energies of the best NO dissociation pathways on the Rh(1 0 0), the Rh(1 1 0), and the Rh(1 1 1) are 0.63, 0.66 and 1.77 eV, respectively. The activity of the Rh planes for NO dissociation is in the order of Rh(1 0 0) ≈ Rh(1 1 0) > Rh(1 1 1). The low dissociation barrier for Rh(1 0 0) and Rh(1 1 0) is associated with the existence of a lying-down NO structure which acts as a precursor for dissociation. By Mulliken population analysis and structure analysis, both electronic and geometrical effects are found to affect the NO dissociation reactions, but the geometrical effect exceed the electronic. The energy decomposition scheme has been used to provide further insight into the NO dissociation reactions. Based on the calculations, the interaction energy between N and O in the transition state on the Rh(1 1 1) is found much larger than that on the Rh(1 0 0) and the Rh(1 1 0). The major differences of should originate from the variation of the bonding competition effect.  相似文献   
996.
利用可调谐同步辐射真空紫外光电离和分子束质谱技术探测和鉴别了低压预混层流吡啶/氧气/氩气火焰中的三重态氮宾.通过测量光电离效率谱和理论计算确定了氮宾的电离能.结果表明氮宾的基态为三重态,其第一和第二绝热电离能分别为8.04和9.15§0.05 eV.另外,根据已探测到的物种提出了氮宾的形成和消耗通道.氮宾是燃烧化学中探测到的第一个含氮双自由基,因此,在吡啶火焰的动力学模型中应该将它考虑进去.  相似文献   
997.
Some photonic crystals (PCs) consisting of complex lattices of dielectric cylinders can have an effective refraction index (neffneff) of −1. Subwavelength imaging by a slab of a honeycomb PC of dielectric cylinders with neff=−1neff=1 is investigated and an open resonator with a quality factor higher than 3000 is designed with the same PC. Air–PC interfaces with low reflection are also used for the slab lens and open resonator.  相似文献   
998.
依据最弱受约束电子势模型理论,计算了铕原子4f76snd6D9/2(n≥13)、4f76snd8D9/2(n≥17)、4f76snd8D5/2(n≥15)和4f76snd8D3/2(n≥21)里德堡系列能级.计算结果与实验值的最大相对误差为4×10-5,最大绝对误差是1.91cm-1,达到了较高精度,这表明文中的外推数据是可信的.  相似文献   
999.
The title compounds, several Schiff bases with D-π-D type have been successfully synthesized from reaction of 4-(N-dialkylamino) benzaldehyde and hydrazine or p-phenylenediamine in ethanol. These compounds were characterized by IR, 1H NMR, elemental analysis and electronspray mass spectrometry. One-photon fluorescence and two-photon fluorescence properties have been investigated. The two-photon absorption (TPA) cross section (σ) of these compounds was obtained by using the open-aperture Z-scan technique. Based on theoretical calculations and factual test, the influence that a series of substituted groups and the conjugated frame imposed on TPA cross section were systematically discussed.  相似文献   
1000.
In this work, highly activated graphene oxide/multiwalled carbon nanotube/Fe3O4 ternary nanocomposite adsorbent was prepared from a simple hydrothermal route by using ferrous sulfate as precursor. For this purpose, the graphene oxide/multiwalled carbon nanotube architectures were formed through the π-π attractions between them, followed by attaching Fe3O4 nanoparticles onto their surface. The structure and composition of as-prepared ternary nanocomposite were characterized by XRD, FTIR, XPS, SEM, TEM, Raman, TGA, and BET. It was found that the resultant porous graphene oxide/multiwalled carbon nanotube/Fe3O4 ternary nanocomposite with large surface area could effectively prevent the π-π stacking interactions between graphene oxide nanosheets and greatly improve sorption sites on the surfaces. Thus, owing to the unique ternary nanocomposite architecture and synergistic effect among various components, as-prepared ternary nanocomposite exhibited high separation efficiency when they were used to remove the Cu (II) and methylene blue from aqueous solutions. Furthermore, the adsorption isotherms of ternary nanocomposite structures for Cu (II) and methylene blue removal fitted the Langmuir isotherm model. This work demonstrated that the graphene oxide/multiwalled carbon nanotube/Fe3O4 ternary nanocomposite was promising as an efficient adsorbent for heavy metal ions and organic dye removal from wastewater in low concentration.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号