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51.
Christophe Roussel Loc Dayon Henrik Jensen Hubert H. Girault 《Journal of Electroanalytical Chemistry》2004,570(2):187-199
A series of electrogenerated selective electrophiles based on substituted benzoquinones has been characterized as tags for l-cysteine and cysteine residues in proteins. The electrophiles are generated electrochemically from the corresponding hydroquinones. It is shown from mass spectrometry analysis that the electrogenerated benzoquinone can tag the biomolecules. The rate constants pertaining to the addition of l-cysteine onto the electrogenerated benzoquinones have been determined using electrochemical techniques. The substitution patterns have been unraveled leading to the assessment of site-specific rate constants. It is shown that the rate constants are primarily dependent on the electronic nature of the substituents as expressed by the Hammett substitution constant. The apparent tagging yields observed for l-cysteine in nanospray mass spectrometry experiments do not correspond to the yields expected from the electrochemical study, as the ionisation efficiencies are highly dependent on the tag. Finally, the on-line tagging has been tested using β-lactoglobulin A and myoglobin. Based on these results, it is concluded that the tagging reaction is selective towards cysteine when it takes place in the nanospray interface. The results show that the methodology presented can be used for a rapid characterization and identification of reactive sites in biomolecules. 相似文献
52.
53.
Ri Cheng XUAN* Wei Xiao HU Zhong Yu YANG Ya Ping LU College of Pharmaceutical Sciences Zhejiang University of Technology Hangzhou 《中国化学快报》2004,(2)
2-Chloro-5-methylpyridine is an important intermediate for the preparation of biological active compounds, especially insecticides1, e.g. imidacloprid2, and is usually manufac- tured from 3-methylpyridine N-oxide. However, the manufacturing process also forms the by-products: 3-methylpyridine and its isomer 2-chloro-3-methylpyridine3. The pro- perties of the isomers are similar, it is difficult to separate by ordinary methods, such as distillation. Scheme 1 79.4%13.6%5.2%NClCH3NCH3ClNC… 相似文献
54.
Dmitri V Sevenard Vyacheslav Ya SosnovskikhAlexander A Kolomeitsev Martin H KönigsmannGerd-Volker Röschenthaler 《Tetrahedron letters》2003,44(41):7623-7627
In a convenient and efficient procedure, the nucleophilic 1,4-trifluoromethylation of several α,β-enones using (trifluoromethyl)trimethylsilane was achieved. The high regioselectivity of the reaction has been reached by blocking the carbonyl moiety of the electrophile with a bulky aluminum-centered Lewis acid. 相似文献
55.
S. Ya. Kotkovskii 《JETP Letters》1997,65(10):768-772
The probability of inclusive semileptonic decay of B mesons is calculated in the constituent-quark model. A compact formula is obtained for the differential decay width of a
B meson in terms of the corresponding decay width of a free b quark and the wave function of the internal motion of the quarks in the B meson. Numerical values of semileptonic-decay widths are obtained for a series of models of the wave function.
Pis’ma Zh. éksp. Teor. Fiz. 65, No. 10, 734–737 (25 May 1997) 相似文献
56.
The nearest-neighbor two-point correlation function of the Z-invariant inhomogeneous eight-vertex model in the thermodynamic limit is computed using the free-field representation.
Pis’ma Zh. éksp. Teor. Fiz. 68, No. 3, 243–247 (10 August 1998)
Published in English in the original Russian journal. Edited by Steve Torstveit. 相似文献
57.
A. Ya. Kazakov 《Theoretical and Mathematical Physics》1998,117(1):1182-1193
We investigate a Cauchy problem in the Fock space for a system consisting of a two-level atom, a quantum field, and a classical
field. A solution estimate is obtained for the Cauchy problem with initial data from a special class. This class is invariant
with respect to the dynamic semigroup of the system. We propose an averaging method for solving the Cauchy problem in the
case where the Hamiltonian parameters differ greatly in the order of magnitude. An estimate of the averaging error is obtained.
Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 117, No. 1, pp. 92–106, October, 1998. 相似文献
58.
59.
V. O. Kur'yanov T. F. Zhelobetskaya A. E. Zemlyakov V. Ya. Chirva 《Chemistry of Natural Compounds》1993,29(1):103-106
The synthesis has been effected of derivatives of MDP having a spacer with an amino or carboxy group. The final stage of the synthesis was the condensation of Boc-L-Ala-D-iGln with 6-aminohexanol (followed by the two-stage replacement of the hydroxy by an azido group) or with benzyl 6-aminohexanoate.Simferopol' State University. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 122–125, January–February, 1993. 相似文献
60.
Montgomery Multiplication in GF(2k) 总被引:8,自引:0,他引:8
We show that the multiplication operation c=a · b · r-1 in the field GF(2k can be implemented significantly faster in software than the standard multiplication, where r is a special fixed element of the field. This operation is the finite field analogue of the Montgomery multiplication for modular multiplication of integers. We give the bit-level and word-level algorithms for computing the product, perform a thorough performance analysis, and compare the algorithm to the standard multiplication algorithm in GF(2k. The Montgomery multiplication can be used to obtain fast software implementations of the discrete exponentiation operation, and is particularly suitable for cryptographic applications where k is large. 相似文献