Influence of Cr interlayer on the structure and optical properties of Ag films on glass substrate by magnetron sputtering

Optical properties and microstructure of Ag film on glass substrate with Cr intermediate layer were studied by using spectrophotometer and XRD. The spectra results showed that introducing Cr intermediate layer reduced the surface roughness and promoted the reflectivity of Ag film. The XRD analysis showed that the crystalline grains increased and the stress decreased. The adhesion was also improved by using the tape test method.     

Preparing polymer brushes on polytetrafluoroethylene films by free radical polymerization

Films of polytetrafluoroethylene (PTFE) were exposed to sodium naphthalenide (Na/naphtha) etchant so as to defluorinate the surface for obtaining hydroxyl functionality. Surface-initiators were immobilized on the PTFE films by esterification of 4,4′-azobis(4-cyanopentanoic acid) (ACP) and the hydroxyl groups covalently linked to the surface. Grafting of polymer brushes on the PTFE films was carried out by the surface-initiated free radical polymerization. Homopolymers brushes of methyl methacrylate (MMA) were prepared by free radical polymerization from the azo-functionalized PTFE surface. The chemical composition and topography of the graft-functionalized PTFE surfaces were characterized by X-ray photoelectron spectroscopy (XPS), attenuated total reflectance (ATR) FT-IR spectroscopy and atomic force microscopy (AFM). Water contact angles on PTFE films were reduced by surface grafting of MMA.     

Towards Strong Duality in Integer Programming

We consider in this paper the Lagrangian dual method for solving general integer programming. New properties of Lagrangian duality are derived by a means of perturbation analysis. In particular, a necessary and sufficient condition for a primal optimal solution to be generated by the Lagrangian relaxation is obtained. The solution properties of Lagrangian relaxation problem are studied systematically. To overcome the difficulties caused by duality gap between the primal problem and the dual problem, we introduce an equivalent reformulation for the primal problem via applying a pth power to the constraints. We prove that this reformulation possesses an asymptotic strong duality property. Primal feasibility and primal optimality of the Lagrangian relaxation problems can be achieved in this reformulation when the parameter p is larger than a threshold value, thus ensuring the existence of an optimal primal-dual pair. We further show that duality gap for this partial pth power reformulation is a strictly decreasing function of p in the case of a single constraint. Dedicated to Professor Alex Rubinov on the occasion of his 65th birthday. Research supported by the Research Grants Council of Hong Kong under Grant CUHK 4214/01E, and the National Natural Science Foundation of China under Grants 79970107 and 10571116.     

On the deformation and fracture of porous materials

The constitutive behavior of porous materials (including the yield loci, the void growth rate, the macro stress-strain relation and the strain to localization instability) is examined based on the lower bound approach proposed by the present authors. These results are then compared with the experimental and the finite element results as well as those predicted by Gurson's equations. Emphasis is placed on approaching the real behavior from the upper and the lower bound analysis. Calculation is also made on the influence of void nucleation on the critical strain to instability and a modified strain-controlled nucleation criterion is proposed. Finally the instability and fracture of AISI4340 steel in plane strain tension is examined and comparison is made between theoretical and experimental results.     

Fourier transform IR product study of the reaction of CFO radicals with O2 at 298 K

Experimental results are presented of a Fourier transform IR product study at 298 K of the reaction system CFO+O₂ at oxygen pressures between 3 and 250 mbar. Pulsed photolysis of oxalyl fluoride (CFO)₂ or formyl fluoride (CHFO) at 193 nm was used to produce CFO. As stable products we detected bis-fluoroformyl peroxide, carbonyl fluoride and carbon dioxide. The yields of the peroxide and of CF₂O were measured as a function of [O₂]/[precursor] and are discussed qualitatively.     

Use of zwitterionic buffer additives to improve the separation of proteins in capillary zone electrophoresis

In CZE, the adsorption of the proteins on the capillary wall is a common problem. This paper describes the simple method of utilizing zwitterionic buffer additives to improve the separation of proteins in untreated fused silica capillaries at neutral pH. Three kinds of zwitterion are evaluated in the separation of acidic, neutral, and basic proteins, including their effect on protein efficiency, mobility, separation, and resolution; the difference between the effects of the different additives are also highlighted. The method has proved to be a possible means of reducing protein adsorption, especially for basic proteins.     

Elevation of the glass transition temperature in flexible‐chain semicrystalline polymers

In the idealized two‐phase model of a semicrystalline polymer, the amorphous intercrystalline layers are considered to have the same properties as the fully‐amorphous polymer. In reality, these thin intercrystalline layers can be substantially influenced by the presence of the crystals, as individual polymer molecules traverse both crystalline and amorphous phases. In polymers with rigid backbone units, such as poly(etheretherketone), PEEK, previous work has shown this coupling to be particularly severe; the glass transition temperature (T_g) can be elevated by tens of degrees celsius, with the magnitude of the elevation correlating directly with the thinness of the amorphous layer. However, this connection has not been explored for flexible‐chain polymers, such as those formed from vinyl‐type monomers. Here, we examine T_g in both isotactic polystyrene (iPS) and syndiotactic polystyrene (sPS), crystallized under conditions that produce a range of amorphous layer thicknesses. T_g is indeed shown to be elevated relative to fully‐amorphous iPS and sPS, by an amount that correlates with the thinness of the amorphous layer; the magnitude of the effect is severalfold less than that in PEEK, consistent with the minimum lengths of polymer chain required to make a fold in the different cases. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1198–1204, 2007     

非园断面通道层流摩擦阻力与换热理论研究的新进展

本文介绍作者近些年来对椭圆、矩形、扇形、任意三角形、正多边形、环形等各种非圆断面通道层流摩擦阻力与换热理论的研究成果，给出大量新的速度与温度场表达式，以及摩擦阻力与换热的新的计算公式。本文对传统的层流阻力与换热理论进行了一次系统的补充与完善，同时考虑到工程需要，对所有繁杂的理论公式都进行了化简，给出形式简单而且精度相当高的近似公式。     

局部对称共形平坦黎曼流形中具有平行平均曲率向量的子流形

本文把[1]的结论推广到了环绕空间是局部对称共形平坦的情形,即获得了:设M~是局部对称共形平坦黎曼流形N~+p(p>1)中具有平行平均曲率向量的紧致子流形,如果则M~位于N~+p的全测地子流形N~+1中。其中S,H分别是M~的第二基本形式长度的平方和M~的平均曲率,T_C、t_c分别是N~+p的Ricci曲率的上、下确界,K是N~+p的数量曲率。