Separating bounded group homomorphisms on ?-groups of functions

A necessary and sufficient condition is given for separating bounded group homomorphisms on ?-groups of real-valued continuous functions to be weighted composition maps.     

Pyrazolones as Building Blocks in Heterocyclic Synthesis: Synthesis of New Pyrazolopyran,Pyrazolopyridazine and Pyrazole Derivatives of Expected Antifungicidal Activity

A series of new pyrazolone and pyrazole derivatives with expected antifungicidal activity have been prepared through the reactions 3‐phenyl‐1‐H‐pyrazol‐5(4H)‐one ( 3 ) and 4‐(dimethylaminomethylene)‐3‐phenyl‐1H‐pyrazol‐5(4H)‐one ( 5 ) with a variety of electrophilic reagents and nucleophilic reagents. The newly synthesized compounds were characterized by IR, ¹H NMR, ¹³C NMR and mass spectral studies.     

Thermal,structure and morphological properties of lithium disilicate glasses doped with copper oxide and their glass–ceramic derivatives

This research aims to investigate and compare the structural and the morphological properties of both lithium disilicate glasses doped with copper oxide and their glass–ceramic derivatives. Density measurements were measured for all samples by Archimedes method at room temperature. Differential scanning calorimetric analysis was used to determine the glass transition temperature (T_g) and crystallization temperature (T_c) for all glasses. The glass transition temperature was observed to decrease with increasing CuO concentration indicating the formation of non-bridging oxygen bonds in the glass network. X-ray analysis patterns reveal the appearance of crystalline lithium metasilicate phase as the main phase within the glass–ceramic derivatives, and their crystallite sizes were observed to decrease as the CuO increased. Experimental infrared absorption data indicate the existence of characteristic vibrational bands due to structural building SiO₄ units in resemblance to the same vibrations observed from traditional crystalline silicates. Scanning electron microscopic investigations show the vitreous nature for lithium disilicate glasses and the distinct crystalline morphological features for the corresponding glass–ceramic derivatives.     

Metalorganic chemical vapor deposition of mesoporous SiTiOC nanostructured thin films

SiTiOC mesoporous thin films have been obtained by metalorganic chemical vapor deposition (MOCVD) using titanium iso-propoxide (TIP) and tetraethylorthosilicate (TEOS) as starting precursors. The influences of both carrier gas and deposition temperature on the properties of the produced films were extensively studied. The low-angle XRD analysis confirms that, all produced films under different conditions (gas type and temperature) have the mesoporous structure. However, the deposition temperature was found to be much effective in controlling both morphology and composition of the final films than the type of carrier gas. The morphology of the produced films was totally converted from spherical shape-like nanoparticles at 700 °C to lengthy at higher temperature of 1000 °C. The SEM-EDX investigations proved that the composition of the produced films was composed of SiTiOC structure system. The PL analysis has demonstrated along with FT-IR data that all the deposited films at various deposition parameters were composed mainly of SiO₂, SiOC, SiC, TiO₂ and TiOC bond structures and most probably nanocomposite SiTiOC system thin films.     

The Two-stage Assembly Flow Shop Scheduling with an Availability Constraint: Worst Case Analysis

In this paper, we are interested in handling the limited availability of machines in the two-stage assembly flow shop scheduling problems. Emphasis is put on the semiresumable case with respect to the minimization of the makespan. We provide, when possible, heuristics with a tight worst-case ratio bound of 2.     

On a compound Poisson risk model with dependence and in the presence of a constant dividend barrier

In this paper, we consider a classical risk process with dependence and in the presence of a constant dividend barrier. The dependence structure between the claim amounts and the interclaim times is introduced through a Farlie–Gumbel–Morgenstern copula. We analyze the expectation of the discounted penalty function and the expectation of the present value of the distributed dividends. For each function, an integro‐differential equation with boundary conditions is derived, and the solution is provided. Finally, we find an explicit solution for each function when the claim amounts are exponentially distributed. We illustrate the impact of the dependence on these two quantities. Copyright © 2012 John Wiley & Sons, Ltd.     

Influence of pi-stacking on the redox properties of oligothiophenes: (alpha-alkyloligo-thienyl)para[2.2]cyclophanes

[structure: see text] Oligothienyl-substituted paracyclophanes bearing alpha-thienyl substituents, which block polymerization at these sites, undergo oxidation to form stable radical cations and dications. Splitting of the first voltammetric oxidation wave of stacked dimers into two single-electron processes corresponding to formation of the stacked mono(radical cation) and the stacked bis(radical cation) illustrates the influence of pi-stacking on the behavior of conjugated chains, which serve as models for stacked polarons in conjugated polymers.     

Nonlinear bending inertia of a vibrating beam

Zusammenfassung Die bei Querschwingungen schlanker Stäbe mit zeitabhängiger Längsbelastung in der Bewegungsdifferentialgleichung auftretenden nichtlinearen Trägheitsterme, herrührend von der Longitudinalbewegung, werden hier im Gegensatz zu früheren Arbeiten mitberücksichtigt. Die sich daraus ergebenden nichtlinearen Korrekturen der Eigenfrequenzen des entsprechenden linearen Systems werden abgeschätzt.