全文获取类型
收费全文 | 325篇 |
免费 | 11篇 |
专业分类
化学 | 252篇 |
力学 | 6篇 |
数学 | 6篇 |
物理学 | 72篇 |
出版年
2021年 | 3篇 |
2020年 | 4篇 |
2019年 | 4篇 |
2017年 | 2篇 |
2016年 | 9篇 |
2015年 | 3篇 |
2014年 | 4篇 |
2013年 | 6篇 |
2012年 | 14篇 |
2011年 | 11篇 |
2010年 | 11篇 |
2009年 | 15篇 |
2008年 | 14篇 |
2007年 | 18篇 |
2006年 | 12篇 |
2005年 | 14篇 |
2004年 | 24篇 |
2003年 | 20篇 |
2002年 | 7篇 |
2001年 | 7篇 |
2000年 | 9篇 |
1999年 | 7篇 |
1998年 | 2篇 |
1997年 | 4篇 |
1996年 | 2篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1992年 | 4篇 |
1991年 | 7篇 |
1990年 | 3篇 |
1989年 | 4篇 |
1988年 | 4篇 |
1987年 | 7篇 |
1986年 | 2篇 |
1985年 | 9篇 |
1984年 | 6篇 |
1983年 | 8篇 |
1982年 | 6篇 |
1981年 | 5篇 |
1980年 | 6篇 |
1979年 | 3篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1975年 | 5篇 |
1974年 | 3篇 |
1973年 | 4篇 |
1971年 | 2篇 |
1970年 | 2篇 |
1968年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有336条查询结果,搜索用时 15 毫秒
31.
Hydroxoiridium/Chiral Diene Complexes as Effective Catalysts for Asymmetric Annulation of α‐Oxo‐ and Iminocarboxamides with 1,3‐Dienes 下载免费PDF全文
Miyuki Hatano Dr. Takahiro Nishimura 《Angewandte Chemie (International ed. in English)》2015,54(37):10949-10952
The asymmetric [3+2] annulation of α‐oxo‐ and α‐iminocarboxamides with 1,3‐dienes catalyzed by hydroxoiridium/chiral diene complexes was realized, giving high yields of the corresponding γ‐lactams with high enantioselectivity. 相似文献
32.
C‐Selective and Diastereoselective Alkyl Addition to β,γ‐Alkynyl‐α‐imino Esters with Zinc(II)ate Complexes 下载免费PDF全文
Dr. Manabu Hatano Kenji Yamashita Mai Mizuno Orie Ito Prof. Dr. Kazuaki Ishihara 《Angewandte Chemie (International ed. in English)》2015,54(9):2707-2711
Since umpolung α‐imino esters contain three electrophilic centers, regioselective alkyl addition with traditional organometallic reagents has been a serious problem in the practical synthesis of versatile chiral α‐amino acid derivatives. An unusual C‐alkyl addition to α‐imino esters using a Grignard reagent (RMgX)‐derived zinc(II)ate was developed. Zinc(II)ate complexes consist of a Lewis acidic [MgX]+ moiety, a nucleophilic [R3Zn]? moiety, and 2 [MgX2]. Therefore, the ionically separated [R3Zn]? selectively attacks the imino carbon atom ,which is most strongly activated by chelation of [MgX]+. In particular, chiral β,γ‐alkynyl‐α‐imino esters can strongly promote highly regio‐ and diastereoselective C‐alkylation because of structural considerations, and the corresponding optically active α‐quaternary amino acid derivatives are obtained within 5 minutes in high to excellent yields. 相似文献
33.
We here consider open quantum systems defined on discretized space, motivated by experimental and theoretical interest in the electronic conduction through nanoscale devices such as molecular junctions and quantum dots. We particularly focus on effects of resonances on the conductance through the systems. We develop a method of calculating the conductance with the use of Green's function expansion with respect to the eigenstates of the effective Hamiltonian for the open quantum systems. Unlike previous methodologies where one can treat only narrow resonances far from the band edges in a satisfactory manner with a Lorentzian profile, our method provides a novel resonance profile which can be used to describe any isolated resonance in the spectrum even close to the band edges. 相似文献
34.
We have investigated the pressure-induced Raman spectral changes of 1-ethyl-3-methylimidazolium tetrafluoroborate ([emim][BF4]). We found that [emim][BF4] did not crystallize up to 1.2 GPa. The Raman CH stretching spectra arising from the CH3 groups of the ethyl-chain and the CH3 group adjacent to the imidazolium-ring in [emim]+ cation largely changed against pressure. Moreover, the Raman intensity of the CH2 (N) bending band arising from the alkyl-chain drastically changes with increasing pressure, but that of the imidazolium-ring in-plane bending band arising from the imidazolium-ring is independent of pressure. Our results show that the environment around the alkyl-chain of [emim][BF4] is largely perturbed rather than that around the imidazolium-ring upon compression. 相似文献
35.
Yukihiro Aiba Naomichi Hatano Hideki Takayasu Kouhei Marumo Tokiko Shimizu 《Physica A》2002,310(3-4):467-479
We first show that there are in fact triangular arbitrage opportunities in the spot foreign exchange markets, analyzing the time dependence of the yen–dollar rate, the dollar–euro rate and the yen–euro rate. Next, we propose a model of foreign exchange rates with an interaction. The model includes effects of triangular arbitrage transactions as an interaction among three rates. The model explains the actual data of the multiple foreign exchange rates well. 相似文献
36.
37.
38.
Hiroo Wada Keisuke Makino Tamio Takeuchi Hiroyuki Hatano Kohji Noguchi 《Journal of chromatography. A》1985,320(2)
The chromatographic behaviour in aqueous solution of pullulans, polyethylene glycols, peptides and proteins with different molecular weights on newly developed polyvinyl alcohol columns (Asahipak GS column series: GS-310, GS-320, GS-510 and GS-520) has been investigated. Pullulans and polyethylene glycols eluted according to the gel filtration mode, so both series of compounds produced almost equal calibration curves for GS-310 and GS-320 and for GS-510 and GS-520; the exclusion limits on GS-310 and GS-320 and on GS-510 and GS-520 were found to be ca. 40,000 and 300,000, respectively. Peptides and proteins were found to adsorb slightly on the columns. However, the plots of the elution volumes against the logarithm of the molecular weights for many of the substrates tested gave rise to the linear calibration curves. Recovery of several crude proteins was also studied for the columns and high values were obtained (81–100%). The effects of changes in the flow-rate, temperature and concentration of electrolytes added to the eluents, on the retention of all four types of compound are also reported. 相似文献
39.
40.
The magnetic moments of excited states of mono-cyclic non-alternant conjugated hydrocarbons with 3-9 carbon atoms were theoretically calculated using wavefunctions determined on the basis of the LCAO MO method. The predicted value is in good agreement with experiment for the tropylium cation. 相似文献