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991.
A hybrid photonic-crystal structure is presented as a candidate for enhancing transmission through sharp photonic-crystal waveguide bends built on a perforated dielectric slab. This structure, which we refer to as a polycrystalline structure, combines two photonic-crystal lattices. Polycrystalline photonic-crystal structures offer the ability to minimize reflections as well as mismatches that a propagating wave might encounter while undergoing a sharp corner or a discontinuity between different waveguide sections. The availability of polycrystalline structures in photonic crystals opens a broad range of possibilities for the development of optical devices. Numerical experiments are performed with two- and three-dimensional finite-difference time domain methods. 相似文献
992.
Mohamed Mokhtar Mohamed Ibrahim Mekkawy 《Journal of Physics and Chemistry of Solids》2003,64(2):299-306
The dc and ac conductivities as well as the dielectric constant () were measured for different zeolites encapsulated gold (AuCl3) samples at different temperatures (300-500 K) and various frequencies (5 kHz-1 MHz). The conductivity was found to change in the order Au/FSM-27>Au/NaY>Au/FSM-47. Sorbed water contained inside zeolites assists greatly the proton mobility (zeolite protons) and the ion mobility (Na+ and Au+) and hence enhance the electric conduction in the temperature range 300-373 K. Raising the temperature over 373 K induces dehydration effect that assists the metallic gold formation and thus a dramatic loss in conductivity was revealed. The conduction mechanism was expected to be partially ionic and partially electronic. The IR study showed that the exposure of Au zeolites to CO gas produced a characteristic band of Au+-CO at 2180 cm−1 that tends to decrease with temperatures and even vanishes at 376 K in favor of Au0-CO at 2128 cm−1. Similarly, a phase transition at 338 K, that occurs in the range 300-376 K, was confirmed by DTA to further emphasize the temperature regions of either Au+ cations (338 K) or Au0 (376 K) formation. 相似文献
993.
The photoionization and photoelectron spectroscopy of He nanodroplets (10(4) atoms) has been studied by photoelectron imaging with photon energies from 22.5-24.5 eV. Total electron yield measurements reveal broad features, whose onset is approximately 1.5 eV below the ionization potential of atomic He. The photoelectron spectra are dominated by very low energy electrons, with less than 0.6 meV. These results are attributed to the formation and autoionization of highly vibrationally excited He(*)(n) Rydberg states within the cluster, followed by strong final state interactions between the photoelectron and the droplet. 相似文献
994.
Eibl M Gaertner S Bourennane M Kurtsiefer C Zukowski M Weinfurter H 《Physical review letters》2003,90(20):200403
We observe polarization entanglement between four photons produced from a single down-conversion source. The nonclassical correlations between the measurement results violate a generalized Bell inequality for four qubits. The characteristic properties and its easy generation with high interferometric contrast make the observed four-photon state well suited for implementing advanced quantum communication schemes such as multiparty quantum key distribution, secret sharing, and telecloning. 相似文献
995.
Nelson ML Ismail MY McIntyre L Bhatia B Viski P Hawkins P Rennie G Andorsky D Messersmith D Stapleton K Dumornay J Sheahan P Verma AK Warchol T Levy SB 《The Journal of organic chemistry》2003,68(15):5838-5851
A diverse collection of tetracycline derivatives has been synthesized utilizing Heck, Suzuki, and other palladium-coupling reactions via tetracycline arenediazonium and iodoarene salts. Large numbers of tetracyclines are now possible via these reactions, including numerous upper periphery derivatives of doxycycline, minocycline, sancycline, and methacycline modified at positions C7, C9, and C6-C13 on the tetracycline naphthacene ring. Application of palladium-coupling reactions to the tetracyclines has yielded new tetracycline classes with differing structural attributes, greatly increasing the structural diversity of this family of antibiotics, one of the last of the early antibiotic families to be expanded by organic and medicinal chemistry. 相似文献
996.
Nuzhat Jabeen Ejaz ur Rehman Shafaat Ahmed 《Journal of Radioanalytical and Nuclear Chemistry》2003,258(2):427-430
The isotopic composition of lithium in seawater has been determined by thermal ionization mass spectrometry (TIMS) based on the use of lithium hydroxide as the ion source. Isotopic measurements in a reference material supplied by IAEA (L-SVEC Li2CO3) were made to check the reproducibility of the method and 6Li indicates mobilization of light isotope of lithium form the sediment. 相似文献
997.
The ability to synthesize nonribosomally small bioactive peptides that find application in modern medicine is widely spread among microorganisms. As broad as the spectrum of biological activities is the structural diversity of these peptides, which are mostly cyclic or branched cyclic compounds containing non-proteinogenic amino acids, small heterocyclic rings and other unusual modifications in the peptide backbone. They are synthesized by multimodular enzymes, the so-called nonribosomal peptide synthetases (NRPSs), from simple building blocks. Biochemical and genetic studies have unveiled the key principles of nonribosomal peptide syntheses, as well as the realization of many structural features of these peptides. This review focuses on recent results in NRPS research and highlights how this knowledge can be exploited for biotechnological purposes. In addition, possibilities and limitations for prediction of structural features of uncharacterized NRPSs and approaches for their engineering are discussed. 相似文献
998.
999.
Riaz N Anis I Malik A Ahmed Z Aziz-ur-rehman Muhammad P Nawaz SA Choudhary MI 《Chemical & pharmaceutical bulletin》2003,51(3):252-254
Paeonins A and B, new monoterpene galactosides have been isolated from the chloroform-soluble fraction of the roots of Paeonia emodi and showed potent lipoxygenase inhibitory activity. The structures of 1 and 2 have been assigned on the basis of spectral analysis including one- and two-dimensional NMR techniques. 相似文献
1000.
Fernández EJ López-De-Luzuriaga JM Monge M Olmos ME Pérez J Laguna A Mohamed AA Fackler JP 《Journal of the American Chemical Society》2003,125(8):2022-2023
The X-ray structure of (Tl[Au(C(6)Cl(5))(2)])(n), 1, consists of 1-D linear polymer chains parallel to the crystallographic z axis. The crystal structure of 1 has channels that run parallel to these chains with interatom distances in the range 3.231-4.076 A. There are holes in these channels with diameters as large as 10.471 A, which can accommodate a variety of solvents. Complex 1 displays reversible vapochromic emission and absorption spectral behavior when the solid is exposed to a variety of organic vapors such as acetone, acetonitrile, triethylamine, acetylacetone, tetrahydrothiophene, 2-fluoropyridine, tetrahydrofuran, and pyridine. Complex 1 is luminescent at room temperature and at 77 K in the solid state. UV excitation at 495 nm leads to an emission at 531 nm. 相似文献