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181.
Osamah Al-Hashimi Khalid Hashim Edward Loffill Tina Marolt ebaek Ismini Nakouti Ayad A. H. Faisal Nadhir Al-Ansari 《Molecules (Basel, Switzerland)》2021,26(19)
The provision of safe water for people is a human right; historically, a major number of people depend on groundwater as a source of water for their needs, such as agricultural, industrial or human activities. Water resources have recently been affected by organic and/or inorganic contaminants as a result of population growth and increased anthropogenic activity, soil leaching and pollution. Water resource remediation has become a serious environmental concern, since it has a direct impact on many aspects of people’s lives. For decades, the pump-and-treat method has been considered the predominant treatment process for the remediation of contaminated groundwater with organic and inorganic contaminants. On the other side, this technique missed sustainability and the new concept of using renewable energy. Permeable reactive barriers (PRBs) have been implemented as an alternative to conventional pump-and-treat systems for remediating polluted groundwater because of their effectiveness and ease of implementation. In this paper, a review of the importance of groundwater, contamination and biological, physical as well as chemical remediation techniques have been discussed. In this review, the principles of the permeable reactive barrier’s use as a remediation technique have been introduced along with commonly used reactive materials and the recent applications of the permeable reactive barrier in the remediation of different contaminants, such as heavy metals, chlorinated solvents and pesticides. This paper also discusses the characteristics of reactive media and contaminants’ uptake mechanisms. Finally, remediation isotherms, the breakthrough curves and kinetic sorption models are also being presented. It has been found that groundwater could be contaminated by different pollutants and must be remediated to fit human, agricultural and industrial needs. The PRB technique is an efficient treatment process that is an inexpensive alternative for the pump-and-treat procedure and represents a promising technique to treat groundwater pollution. 相似文献
182.
183.
N. Rodziah M. Hashim I.R. IdzaI. Ismayadi A.N. HapishahM.A. Khamirul 《Applied Surface Science》2012,258(7):2679-2685
The microstructure evolution in several polycrystalline yttrium iron garnet samples as a result of a sintering scheme was studied in detail, in parallel with the changes in their magnetic properties. Samples with nanometer sized starting powder were synthesized by employing the High-Energy Ball Milling technique and then sintering toroidal compacts of the milled powder. Nine sintered samples were obtained, each corresponding to a particular sintering from 600 °C to 1400 °C. The samples were characterized for their evolution in crystalline phases, microstructure and magnetic hysteresis-loops parameters. The results showed an increasing tendency of the saturation magnetization and saturation induction with grain size, which is attributed to crystallinity increase and to reduction of demagnetizing fields in the grains. The variation in coercivity could be related to anisotropy field changes within the samples due to grain size changes. In particular, the starting appearance of room temperature ferromagnetic order suggested by the sigmoid-shaped B-H loops seems to be dependent on a sufficient number of large enough magnetic domain-containing grains having been formed in the microstructure. Viewed simultaneously, the hysteresis loops appear to belong to three groups with different magnetism-type dominance, respectively dependent on phase purity and three different groups of grain size distributions. 相似文献
184.
The present analysis is concerned with flow reversal phenomena of the fully-developed laminar combined free and forced MHD convection in a vertical parallel-plate channel. The effect of viscous dissipation is taken into account. Flow reversal adjacent to the cold (or hot) wall is found to exist within the channel as Gr/Re is above (or below) a threshold value. Parameter zones for the occurrence of reversed flow are presented. 相似文献
185.
There has recently been much interest in exploiting the unusual properties associated with fluorocarbons to modulate the physicochemical properties of proteins. Here we present a detailed investigation into the effect on structure and stability of systematically repacking the hydrophobic core of a model protein with the extensively fluorinated (fluorous) amino acid l-5,5,5,5',5',5'-hexafluoroleucine (hFLeu). The starting point was a 27-residue peptide, alpha(4)-H, that adopts an antiparallel 4-alpha-helix bundle structure, and in which the hydrophobic core comprises six layers of leucine residues introduced at the "a" and "d" positions of the canonical heptad repeat. A series of peptides were synthesized in which the central two (alpha(4)-F(2))(,) four (alpha(4)-F(4)), or all six layers (alpha(4)-F(6)) of the core were substituted hFLeu. The free energy of unfolding increases by 0.3 (kcal/mol)/hFLeu on repacking the central two layers and by an additional 0.12 (kcal/mol)/hFLeu on repacking additional layers, so that alpha(4)-F(6) is approximately 25% more stable than the nonfluorinated protein alpha(4)-H. One-dimensional proton, two-dimensional (1)H-(15)N HSQC, and (19)F NMR spectroscopies were used to examine the effect of fluorination on the conformational dynamics of the peptide. Unexpectedly, increasing the degree of fluorination also appears to result in peptides that possess a more structured backbone and less fluid hydrophobic core. The latter only occurs in alpha(4)-F(4) and alpha(4)-F(6), suggesting that crowding of the hFLeu residues may restrict the amplitude and/or time scales for rotation of the side chains. 相似文献
186.
In this note we study an abstract class of weakly dissipative second-order systems with finite memory. We establish the polynomial decay of Rivera, Naso and Vegni for the solution of the system under a very weak condition on the relaxation function. 相似文献
187.
In the current work, zinc oxide (ZnO) nano/microstructures are synthesized using a modified thermal-evaporation process by introducing germanium oxide (GeO2) powder mixed with metallic Zn powder as the raw material. Without the use of any catalyst and oxygen flow in the furnace system, GeO2 is utilized to provide an oxygen source for the growth of ZnO structure. The samples are treated by different temperatures ranging from 500 to 900 °C. Morphology, phase structure, and photoluminescence properties are investigated by scanning electron microscopy (SEM), X-ray diffractometer (XRD) and photoluminescence (PL) spectrometer. The structures and morphologies of the samples were found to vary with growth temperature. The XRD diffraction peaks show that the films grown at temperature from 600 to 800 °C consist of hexagonal wurtzite ZnO structures. Room-temperature PL measurement revealed ZnO spectra representing two bands: near-band-edge emission in the ultraviolet (UV) region and broad deep-level emission centered at about 500 nm. The strong UV emission in the PL spectra indicates that the GeO2 supplies sufficient oxygen for formation of ZnO structures with few oxygen vacancies. The growth mechanism and the roles of GeO2 for formation of ZnO structures are discussed in detail. 相似文献
188.
5‐Phenyl‐1,3,4‐oxadiazole‐2‐thiol/polyamide‐montmorillonite microbicides nanocomposites as drug delivery system 下载免费PDF全文
Nehal Salahuddin Ahmed Elbarbary Nanis G. Allam Ayat F. Hashim 《Journal of Physical Organic Chemistry》2018,31(7)
The preparation and structural characterization of polymeric microbicides consisting of 5‐phenyl‐1,3,4‐oxadiazole‐2‐thiol covalently bound to polyamide based on diethyl‐2,3‐dihydroxysuccinate and polyoxypropylenetriamine Jeffamine (T403) are described. Two different mole ratios of 5‐phenyl‐1,3,4‐oxadiazole‐2‐thiol was reacted with chloroacetylated diethyl‐2,3‐dihydroxysuccinate followed by polycondensation with Jeffamine (T403). The nanocomposites were prepared by modification of microbicide polyamides to yield polymers with phosphonium salt or amine hydrochloride salt followed by ion exchange process between the phosphonium salt or amine hydrochloride of the polyamides and the intermellar sodium cation of the clay mineral montmorillonite. The monomers were characterized by mass spectrum, proton nuclear magnetic resonance. The polymers showed good or moderate antimicrobial activities. Nanocomposites were characterized by Fourier transformed infrared spectroscopy, X‐ray diffraction, thermal gravimetric analysis, and transmission electron microscope. The swelling behavior and release of 5‐phenyl‐1,3,4‐oxadiazole‐2‐thiol in different pH values (2.3, 5.8, and 7.4) were studied. A slow release, ranging from 12% to 28% after 50 hours was recorded from nanocomposites. However, the release profile reached almost 70% from polyamides. The antimicrobial activity of the polyamides was studied against gram‐negative bacteria, gram‐positive bacteria, yeast, and the filamentous fungi by well diffusion method. The polyamides showed better antimicrobial activities than 5‐phenyl‐1,3,4‐oxadiazole‐2‐thiol. 相似文献
189.
M. H. A. Mhareb S. Hashim A. S. Sharbirin Y. S. M. Alajerami R. S. E. S. Dawaud N. Tamchek 《Optics and Spectroscopy》2014,117(4):552-559
The study on the optical properties of alkali borate glasses doped with rare earths is an interesting area of research. Dysporosium doped lithium magnesium borate glasses were prepared by melt-quenching technique with dysporosium concentration varying from 0.3 to 1.0 mol %. Physical and optical properties of Lithium Magnesium Borate doped with different concentration of Dy3+ were observed based on its physical parameters, emission spectra and absorption spectra. The absorption spectra of this study exhibits eight absorption bands with hypersensitive peak at 1260 nm (6 H 9/2). Two emitted spectra transitions were also observed at 4 F 9/2 → 6 H 15/2, 4 F 9/2 → 6 H 13/2. Lastly, important physical parameters for each concentration of dopant such as density, ions concentration, polaron radius, inter-nuclear distance, refractive index, oscillator strength and other parameters were determined. 相似文献
190.
Yulita Molliq R M.S.M. Noorani I. Hashim 《Nonlinear Analysis: Real World Applications》2009,10(3):1854-1869
This paper applies the variational iteration method to obtaining analytical solutions of fractional heat- and wave-like equations with variable coefficients. Comparison with the Adomian decomposition method shows that the VIM is a powerful method for the solution of linear and nonlinear fractional differential equations. 相似文献