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Mixtures of 2-, 3-, and 4-nitoroanilines, are simultaneously analyzed with spectrophotometry, based on their different kinetic properties. These nitroanilines react differentially with 1,2-naphtoquinone-4-sulphonate (NQS) at pH 7 in micellar medium to produce colored product. The differential kinetic spectra were monitored and recorded at 500 nm, and the data obtained from the experiments were processed by chemometric approaches, such as back-propagation neural networks (BPNNs), radial basis function neural networks (RBFNNs), and partial least squares (PLS). Experimental conditions were optimized and training the network was performed using principal components (PCs) of the original data. A set of synthetic mixtures of nitroanilines was evaluated and the results obtained by the application of these chemometric approaches were discussed and compared. The analytical performance of the models was characterized by relative standard errors. It was found that the artificial neural networks model affords relatively better results than PLS. The proposed method was applied to the determination of considered nitroanilines in water samples. 相似文献
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Gholam Babaei Chalmardi Mahmood Tajbakhsh Nahid Hasani Ahmadreza Bekhradnia 《Tetrahedron》2018,74(18):2251-2260
A novel Schiff base fluorescent sensor N,N′-bis(salicylidene)-2,6-bis(4-aminophenyl)-4-phenylpyridine (P3) was synthesized through condensation of 2,6-bis(4-aminophenyl)-4-phenylpyridine and 2-hydroxybenzaldehyde. The obtained results from fluorescence analysis revealed that by excess of Cr3+ to P3, a remarkable increase was observed in the fluorescent intensity of the Schiff base at 663?nm with the ratio of CH3CN/H2O (95/5%), even though the other cations would likely have no impact on the fluorescence intensity. The cause of this trend might be ascribed to the formation of a 1:1 stoichiometric P3-Cr3+ complex, confirmed by Job's plot, which is resulted in preventing the photo-induced electron transfer (PET) process. From fluorescence titration, the association constant Ka was gained 2.28?×?105?M?1 and the limit of detection (LOD) was determined to be 1.3?×?10?7?M. Furthermore, the optimized structure together with the electronic spectra of the proposed complex was determined by DFT and TDDFT calculations. 相似文献
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Mohammad Hasani Prof. Jeffery L. Yarger Prof. C. Austen Angell 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(37):13312-13319
The need for reliable means of ordering and quantifying the Lewis basicity of anions is discussed and the currently available methods are reviewed. Concluding that there is need for a simple impurity‐insensitive tool, we have sought, and here describe, a new method using NMR spectroscopy of a weak base, a substituted urea, 1,3‐dimethyl‐2‐imidazolidinone (DMI), as it is protonated by Brønsted acids of different strengths and characters. In all cases studied the product of protonation is a liquid (hence a protic ionic liquid). NMR spectroscopy detects changes in the electronic structure of the base upon interaction with the proton donors. As the proton‐donating ability, that is, acidity, increases, there is a smooth but distinct transition from a hydrogen‐bonded system (with no net proton transfer) to full ionicity. The liquid state of the samples and high concentration of nitrogen atoms, despite the very low natural abundance of its preferred NMR‐active isotope (15N), make possible the acquisition of 15N spectra in a relatively short time. These 15N, along with 13C, chemical shifts of the carbonyl atom, and their relative responses to protonation of the carbonyl oxygen, can be used as a means, sensitive to anion basicity and relatively insensitive to impurities, to sort anions in order of increasing hydrogen bond basicity. The order is found to be as follows: SbF6?<BF4?<NTf2?>ClO4?>FSO3?<TfO?<HSO4?<Cl?<MsO?. 相似文献
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H. Hajiabadi A. Nowroozi M. Hasani P. Mohammadzadeh Jahani H. Raissi 《International journal of quantum chemistry》2012,112(5):1384-1391
MP2 study of O? H…N intramolecular hydrogen bond (IMHB) in 3‐imino‐propen‐1‐ol and its derivatives were performed and their IMHB energies were obtained using the related rotamers and open‐close methods. Also the topological properties of electron density distribution and charge transfer energy associated with IMHB were gained by quantum theory of atoms in molecules and natural bond orbital theory, respectively. The computational results reveal that the related rotamers method energies are well correlates with geometrical parameters, topological parameters at hydrogen bond and ring critical points, integrated properties, proton transfer barrier and charge transfer energy of O? H…N unit. Surprisingly, it was found that the open‐close hydrogen bond energies cannot represent good linear correlations with these parameters. Consequently, we extrapolate a number of equations that can be used in estimation of O? H…N IMHB energy in complex biological systems. © 2011 Wiley Periodicals, Inc. Int J Quantum Chem, 2012 相似文献
36.
Kinetics of electron donor-acceptor (EDA) complex formation of imipramine and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) was investigated spectrophotometrically in acetonitrile, 1,2-dichloroethane, and chloroform solutions using soft- and hard-modelling approaches. From the results of exploratory analysis of kinetic data and the spectral changes by soft-modelling approaches, evolving factor analysis (EFA) and orthogonal projection approach (OPA), a consecutive two-steps reaction with two intermediates was proposed for the process in acetonitrile and 1,2-dichloroethane media and one with a single intermediate in chloroform solution. Secondly, by applying, multivariate nonlinear least squares hard-modelling approach on the collected experimental kinetic data matrix, the nonlinear parameters (rate constants) as well as the linear parameters (spectral profiles) were obtained by fitting the collected experimental kinetic data matrix to the proposed model. Small values of standard deviation in the resulting parameters and sum of squares of the residuals (ssq) obtained showed the proper selection of the model. Furthermore, the values of lack of fit and percent of explained variance confirmed the correct identified models. Identification of the model with the aid of soft-modelling approaches followed by application of the hard-modelling approaches decreases significantly the rotational ambiguity associated with the obtained concentration and spectral profiles. Variations in the kinetic constants were in complete agreement with the model proposed and the solvent polarities. 相似文献
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Magnetothermoelastic creep behavior of thick-walled spheres made of functionally graded materials (FGM) placed in uniform magnetic and distributed temperature fields and subjected to an internal pressure is investigated using method of successive elastic solution. The material creep, magnetic and mechanical properties through the radial graded direction are assumed to obey the simple power law variation. Using equations of equilibrium, stress-strain and strain-displacement a differential equation, containing creep strains, for displacement is obtained. A semi-analytical method in conjunction with the Mendelson’s method of successive elastic solution has been developed to obtain history of stresses and strains. History of stresses, strains and effective creep strain rate from their initial elastic distribution at zero time up to 55 years are presented in this paper. Stresses, strains and effective creep strain rate are changing in time with a decreasing rate so that after almost 50 years the time-dependent solution approaches the steady state condition when there is no distinction between stresses and strains at 50 and 55 years. 相似文献
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Hasani M Irandoust M Shamsipur M 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2006,63(2):377-382
The formation of molecular complexes between 2,4,6-trinitrophenol (TNP) and aza-substituted macrocycles diaza-18-crown-6 (DA18C6), tetraaza-14-crown-4 (TA14C4) and cryptand C222 in 1,2-dichloroethane solution was investigated spectrophotometrically and conductometrically. The mole ratio and continuous variations studies based on both physicochemical techniques employed clearly revealed the formation of both 1:1 and 2:1 (TNP:macrocycle) adducts in solution. Formation of the resulting complexes was also confirmed by 1H NMR and IR spectroscopic studies. Formation constants of the resulting complexes were evaluated from computer fitting of the corresponding mole ratio data. Stability of the resulting complexes was found to vary in the order C222 approximately TA14C4 > DA18C6. 相似文献
40.
Masoumeh Hasani Masoud Shariati-Rad Elahe Bidad 《Journal of the Iranian Chemical Society》2014,11(4):1137-1145
A simple procedure for the quantitative determination of mixtures of nitrophenols pollutants in environmental and biological samples based on continuous spectrophotometric acid–base titrations and multivariate curve resolution has been proposed. The procedure simultaneously takes into account the spectroscopic and acid–base properties of the nitrophenols, which leads to a higher selectivity. The quantitative determination of analyte in the presence of unknown and uncalibrated interferences is a general benefit of the method. Moreover, only one single synthetic standard containing of the analyte of interest is enough to perform the analysis. Because of the rank-deficiency phenomena, the pure spectra and concentration profiles of the species of interest can only be recovered through matrix augmentation. Even in the presence of the rank deficiencies, in most cases accurate quantitation with relative errors in prediction lower than 5 % was obtained. The percent recoveries obtained (92–108 %) were satisfactory. 相似文献