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31.
32.
In [2] we proved that ifG is a finite group containing an involution whose centralizer has order bounded by some numberm, thenG contains a nilpotent subgroup of class at most two and index bounded in terms ofm. One of the steps in the proof of that result was to show that ifG is soluble, then ¦G/F(G) ¦ is bounded by a function ofm, where F (G) is the Fitting subgroup ofG. We now show that, in this part of the argument, the involution can be replaced by an arbitrary element of prime order. 相似文献
33.
Hartley Rogers Jr. 《Mathematische Annalen》1959,138(2):125-140
34.
Thallous ion can be coulometrically titrated to thallic oxide in strongly alkaline medium by means of ferricyanide ion generated by anodic oxidation of ferrocyanide ion at a platinum anode. The equivalence point may be detected either potentiometrically or amperometrically. With 8 to 20 mg of thallous ion in 125 ml the accuracy and precision are within ± 0.2%. 相似文献
35.
Fengfeng Ren Kody J. Day Dr. C. Scott Hartley 《Angewandte Chemie (International ed. in English)》2016,55(30):8620-8623
Simple discotic cores functionalized with reactive arms have been assembled into two‐ and three‐tiered covalent stacks through imine formation. The targets are obtained in good yields, but competing formation of misassembled byproducts highlights some of the challenges inherent to the thermodynamically controlled assembly of rigid, compact, three‐dimensional architectures. The structures comprise a central stack of arenes surrounded by a triple helix of interconnected arms. The racemization rate is strongly dependent on the number of tiers, suggesting cooperative conformational coupling in these multi‐tiered structures. 相似文献
36.
Redox active metal ions, carbon-centered radicals, and oxygen-centered radicals are important to oxidative stress. A radical detector combining a nitrone spin trap, a phenol, and a cyclopropane radical clocklike unit was prepared and used with EPR spectroscopy to detect and distinguish between hydroxyl radicals, methyl radicals, and iron(III) ions. Iron(III) reacts with the phenol unit inducing opening of the cyclopropane ring and cyclization to generate a stable nitroxyl radical. 相似文献
37.
38.
There are only finitely many locally projective regular polytopes of type {5, 3, 5}. They are covered by a locally spherical polytope whose automorphism group is J1×J1×L2(19), where J1 is the first Janko group, of order 175560, and L2(19) is the projective special linear group of order 3420. This polytope is minimal, in the sense that any other polytope that covers all locally projective polytopes of type {5, 3, 5} must in turn cover this one. 相似文献
39.
Chalmers S Caldwell ST Quin C Prime TA James AM Cairns AG Murphy MP McCarron JG Hartley RC 《Journal of the American Chemical Society》2012,134(2):758-761
Depolarization of an individual mitochondrion or small clusters of mitochondria within cells has been achieved using a photoactivatable probe. The probe is targeted to the matrix of the mitochondrion by an alkyltriphenylphosphonium lipophilic cation and releases the protonophore 2,4-dinitrophenol locally in predetermined regions in response to directed irradiation with UV light via a local photolysis system. This also provides a proof of principle for the general temporally and spatially controlled release of bioactive molecules, pharmacophores, or toxins to mitochondria with tissue, cell, or mitochondrion specificity. 相似文献
40.
Fraser SJ Mulet X Martin L Praporski S Mechler A Hartley PG Polyzos A Separovic F 《Langmuir : the ACS journal of surfaces and colloids》2012,28(1):620-627
A strategy for tethering lipid liquid crystalline submicrometer particles (cubosomes) to a gold surface for the detection of proteins is reported. Time-resolved quartz crystal microbalance (QCM-D) was used to monitor the cubosome-protein interaction in real time. To achieve specific binding, cubosomes were prepared from the nonionic surfactant phytantriol, block-copolymer, Pluronic F-127, and a secondary biotinylated lipid, 1,2-distearoyl-sn-glycero-3-phosphoethanolamine-N-[biotinyl(polyethyleneglycol)-2000], which enabled attachment of the particles to a neutravidin (NAv)-alkanethiol monolayer at the gold surface of the QCM sensor chip. A second set of cubosomes was further functionalized with addition of the glycolipid (G(M1)) to facilitate a specific binding uptake of the protein, cholera toxin B subunit (CT(B)), from solution. QCM-D confirmed the specificity of the cubosome-NAv binding. The analysis of titration experiments, also performed with QCM, suggests that an optimal concentration of cubosomes is required for the efficient packing of the particles at the surface: high cubosome concentrations lead to chaotic cubosome binding onto the surface, sterically inhibiting surface attachment, or require significant reorganization to permit uniform cubosome coverage. The methodology enabled the straightforward preparation of a complex nanostructured edifice, which was then used to specifically capture analyte proteins (cholera toxin B subunit or free NAv) from solution, supporting the potential for development of this approach as a biosensing platform. 相似文献