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排序方式: 共有287条查询结果,搜索用时 31 毫秒
31.
Teena Goel Manoj Kumbhakar Tulsi Mukherjee Haridas Pal 《Journal of photochemistry and photobiology. A, Chemistry》2010,209(1):41-48
The effect of different hydrotropic salts on the microenvironment at the anionic head group region of sodium dodecyl sulphate (SDS) micelle has been studied through time-resolved fluorescence anisotropy measurements of a solubilized probe, coumarin-153 (C153). The organic cations of the hydrotropic salts used in this study, i.e. aniline hydrochloride (AHC) and o-, m- and p-toluidine hydrochlorides (OTHC, MTHC and PTHC, respectively), differ in their charge to size ratio and hydrophobicity. Present study utilizes the sensitivity of the fluorescence technique to understand the changes in the micropolarity and microviscosity experienced by the fluorescent probe, C153, solubilized in the micellar Stern layer, on addition of different hydrotropic salts. Significant changes are observed in the rotational relaxation dynamics of the probe with increasing concentration of the salts. The changes in the rotational relaxation dynamics clearly reflect the sphere to rod transition in the SDS micelles and correspond nicely with the reported results from dynamic light scattering measurements. The growth behavior of SDS micelles is found to be sensitive to the hydrophobicity of the organic cations. The charge to size ratio of the organic cations also indicated to play a role in inducing the sphere to rod transition in the SDS micelles. The interesting observation made from this study is that the sphere to rod transition of SDS micelles is largely facilitated by the presence of the hydrotropic salts and such a transition is successfully indicated by the simple fluorescence anisotropy measurements of a probe in the micelle carried out in the presence of different hydrotropic salts. 相似文献
32.
Kumari H Kline SR Schuster NJ Atwood JL 《Chemical communications (Cambridge, England)》2011,47(45):12298-12300
The stability of copper-seamed C-alkylpyrogallol[4]arene hexamers with varying chain lengths in solution has been studied using small-angle neutron scattering (SANS). The progression in diameter of spherical capsules with increasing alkyl chain lengths of copper-seamed hexamers in solution suggests both robustness as well as a close correlation between the solid phase and solution phase structures. 相似文献
33.
Hugo R. Fernandes Dilshat U. Tulyaganov Ashutosh Goel José M. F. Ferreira 《Journal of Thermal Analysis and Calorimetry》2011,103(3):827-834
This article aims to shed some light on the structure and thermo-physical properties of lithium disilicate glasses in the
system Li2O–SiO2–Al2O3–K2O. A glass with nominal composition 23Li2O–77SiO2 (mol%) (labelled as L23S77) and glasses containing Al2O3 and K2O with SiO2/Li2O molar ratios (3.13–4.88) were produced by conventional melt-quenching technique in bulk and frit forms. The glass-ceramics
(GCs) were obtained from nucleation and crystallisation of monolithic bulk glasses as well as via sintering and crystallisation
of glass powder compacts. The structure of glasses as investigated by magic angle spinning-nuclear magnetic resonance (MAS-NMR)
depict the role of Al2O3 as glass network former with four-fold coordination, i.e., Al(IV) species while silicon exists predominantly as a mixture
of Q
3
and Q
4
(Si) structural units. The qualitative as well as quantitative crystalline phase evolution in glasses was followed by differential
thermal analysis (DTA), X-ray diffraction (XRD) adjoined with Rietveld-reference intensity ratio (R.I.R.) method, Fourier
transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The possible correlation amongst structural
features of glasses, phase composition and thermo-physical properties of GCs has been discussed. 相似文献
34.
Hong Chen J.A. Peters Yue Pan J.J. Heremans N. Goel S.J. Chung M.B. Santos W. Van Roy G. Borghs 《Physica E: Low-dimensional Systems and Nanostructures》2006,34(1-2):374
Spin–orbit interaction in two-dimensional electron systems can lead to a spin-dependent reflection of carriers off a lithographic barrier. Scattering of a spin-unpolarized beam from the barrier leads to the creation of two fully spin-polarized side beams in addition to an unpolarized specularly reflected beam. We experimentally demonstrate a method to create spin-polarized beams of ballistic electrons in mesoscopic samples fabricated on InSb/InAlSb and InAs/AlGaSb heterostructures. We describe two geometries, one open and one closed, in which the spin-dependent reflection and spin-dependent semiclassical trajectories were observed. 相似文献
35.
M.J. Singh S.K. Goel R. Shanker D.O. Kataria N. Madhavan P. Sugathan J.J. Das D.K. Avasthi A.K. Sinha 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1998,4(1):7-13
Measurements were carried out to deduce the transverse kinetic energies of highly charged argon recoil ions produced in single
collisions of 120 MeV ions with argon atoms in which the post collision charge states of the projectiles were not determined. A time of flight
spectrometer was designed and fabricated to detect the charge states of recoils. Experimental procedures for optimizing the
spectrometer for extraction, transmission and detection of recoils are described. A simple approach for determining the transverse
kinetic energy of the recoil ions from FWHM of the peaks is reported. This method is shown to be independent of the choice
of collision partners and requires only the knowledge of the physical values of “optimized parameters” of time-of-flight spectrometer
used in the experiment. The transverse kinetic energy of the recoil ions determined from the present approach is found to
vary from 0.03 eV for to 4.02 eV for Ar10+. These values are compared with the results reported by earlier workers and are shown to follow a q2-behaviour up to a charge state q
=8+ of the recoil ions.
Received: 5 February 1998 / Revised: 8 June 1998 / Accepted: 11 June 1998 相似文献
36.
C. V. Chaudhari K. A. Dubey Y. K. Bhardwaj Virendra Kumar N. K. Goel S. Sabharwal 《Journal of Radioanalytical and Nuclear Chemistry》2008,278(1):47-53
Radiation induced grafting of acrylonitrile (ACN) on ethylene-propene diene terpolymer (EPDM) rubber film was investigated
by mutual radiation grafting technique. Effect of experimental variables viz. radiation dose, dose rate, type of solvent and
monomer content on extent of grafting was studied. From the kinetic studies a mathematical relation R
g
α[M]0.7
D
0.68 showing non-linear relationship for rate of grafting with monomer concentration and dose was deduced. The grafted samples
showed increased hardness and oil resistance. 相似文献
37.
J.-C. Alder H. Behrens F.W. Brasse W. Fehrenbach J. Gayler S.P. Goel R. Haidan V. Korbel J. May M. Merkwitz 《Nuclear Physics B》1975,99(1):1-12
Results on the reaction ep→e′nπ+ are presented in the mass range 1.355 ?W ?1.775 GeV at q2=1GeV2 and in the range 1.415 ? W ? 1.595 GeV at q2=0.6 GeV2. From the angular distribution of the π+ meson the polarization terms σu + ?σL, σp and σI have been determined in the range of production angles 0 <θπ+ ?63° 相似文献
38.
39.
We have measured the near-normal incidence reflectivity of single crystal RuO2 (rutile) for 6 -axis and ⊥ -axis at room temperature in the photon energy range 0.5 – 9.5 eV. From a Kramers-Kronig analysis of the reflectivity we have obtained the spectral dependence of the real, ?1(ω), and imaginary, ?2(ω), parts of the complex dielectric constant. Comparison with recent band structure and density of states calculations and past experimental studies of related solids has enabled us to gain further insight into the nature of the oxygen -electrons and metal -electrons in this material. 相似文献
40.
Palladium (II) catalyzed cleavage of phenyl-antimony and phenyl-phosphorus groups of Ph3Sb and Ph3P under carbon-dioxide or CO/NO atmosphere leading to benzoic acid, has been demonstrated. 相似文献