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261.
Manoj Gaur Mayurika Goel L. Sridhar Tara Devi S. Ashok S. Prabhakar P. Dureja P. Raghunathan S. V. Eswaran 《Monatshefte für Chemie / Chemical Monthly》2012,44(15):283-288
Abstract
Click chemistry was used to synthesize a series of biaryl-based bis(1,2,3-triazoles). Their antifungal activity was evaluated against three soil-borne plant pathogenic fungi, viz. Rhizoctonia bataticola, Sclerotium rolfsii, and Fusarium oxysporum, using the food poison technique at concentrations of 62.5–500 μg/cm3. 相似文献262.
Isotope fractionation by thermal diffusion in silicate melts 总被引:1,自引:0,他引:1
Lacks DJ Goel G Bopp CJ Van Orman JA Lesher CE Lundstrom CC 《Physical review letters》2012,108(6):065901
Isotopes fractionate in thermal gradients, but there is little quantitative understanding of this effect in complex fluids. Here we present results of experiments and molecular dynamics simulations on silicate melts. We show that isotope fractionation arises from classical mechanical effects, and that a scaling relation based on Chapman-Enskog theory predicts the behavior seen in complex fluids without arbitrary fitting parameters. The scaling analysis reveals that network forming elements (Si and O) fractionate significantly less than network modifiers (e.g., Mg, Ca, Fe, Sr, Hf, and U). 相似文献
263.
o-Vanillinoxime has now been used for the gravimetric determination of copper and nickel alone and in presence of many foreign ions. Copper can be estimated in presence of appreciable amounts of cadmium, zinc, cobalt and lead. The interference due to iron (III), antimony (III), bismuth (III) and tin (II) can be removed by suitable masking agents. Determination of copper and nickel in presence of each other has also been carried out. 相似文献
264.
The dimethyl platinum(II) complex containing mixed ligands, cis-[Pt(CH3)2(PEt3)(AsPh3)] reacted with one equivalent of hydrogen chloride yielding trans-[PtCl(CH3)(PEt3)(AsPh3)]. The X-ray crystal structure of the molecule shows the trans orientation of the PEt3 and AsPh3 ligands. 相似文献
265.
M J Singh S K Goel R Shanker D O Kataria N Madhavan P Sugathan J J Das D K Avasthi A K Sinha 《Pramana》1997,49(5):521-533
An on-line facility to measure coincidences between the recoil ions and the scattered projectiles (SCORPION) has been designed,
fabricated and commissioned at Nuclear Science Centre (NSC), New Delhi. The facility consists of a four jaw slit assembly,
a time of flight (TOF) spectrometer, a parallel plate electrostatic charge analyser and a one dimensional position sensitive
parallel plate avalanche counter (PPAC). Details of the design and working principles of various components and the test results
obtained for the Si
q+-Ar collision system are presented to highlight the performance of the system. A multiple loss of up to four electrons has
been observed for 60 MeV Si4+ ions colliding with argon atoms in a single collision condition. Spectra of recoil ions detected in coincidence with a particular
charge state of the scattered projectile show a bell shaped distribution as a function of the recoil charge state (r) for the electron loss events. However, the yield of recoil ions drops asr increases for the direct ionization channel. Also for electron loss, the peak of the recoil ion distribution is seen to shift
to a higher recoil charge state as the number of lost electrons from the projectile increases. 相似文献
266.
Ting-Ih Hsu Gerald Swift Jitendra Goel John Berenz Kenichi Nakano 《International Journal of Infrared and Millimeter Waves》1986,7(7):999-1004
A 44-GHz amplifier using 0.25-m gate length and double-heterojunction structure HEMT devices is described. Higher gain and power performance have been obtained from the amplifier using this device at millimeter-wave frequencies. A spot gain of 9.4 dB and a 1-dB gain compression point of +7.5 dBm has been achieved at 43.5 GHz.This work was supported by the Air Force Space Division under Contract No. F04701-84-C-0113. 相似文献
267.
Ultrasound-assisted synthesis of bioactive isoacoramone (1), a metabolite of Piper marginatum and Acorus tararinowii, has been achieved by oxidation of toxic beta-asarone (2) with potassium permanganate/copper sulphate/alumina into asaronaldehyde (3) followed by treatment with ethylmagnesium iodide to provide 1-(2,4,5-trimethoxy)phenyl-1-propanol (4) which upon further oxidation with potassium permanganate/copper sulphate afforded 1 in 64% yield (overall 32%). Toxicological evaluation of 1 reveals it to be nontoxic up to 60 mg/kg b.w. 相似文献
268.
Development of a Cr(III)-specific potentiometric sensor using Aurin tricarboxylic acid modified silica 总被引:1,自引:0,他引:1
A new chelating resin, Aurin tricarboxylic acid modified silica, was synthesized. The resin behaves as a selective chelating ion exchanger for Cr(III) at a pH 3.8-5.5. A polyvinyl chloride-based membrane electrode of the modified silica has been fabricated and explored as sensor for Cr(III) ions. The membrane works well over the concentration range 7.0 × 10−6 to 1 × 10−1 M of Cr(III) with a Nernstian slope of 19.0 mV per decade of concentration. The response time of the sensor is 10 s and it can be used for a period of 5 months. The performance of the sensor is best in the pH range 3.5-6.5 and it also works well in partially non-aqueous medium. The selectivity coefficient values depicts that the membrane exhibits good selectivity over a number of interfering ions. Moreover, the membrane sensor has been applied to analyse the concentration of chromium in certified steel sample and food materials with greater than 97% accuracy. 相似文献
269.
The dielectric behaviour and the electrical polarization in as-cast and polarized films of styrene-acrylonitrile (SAN) copolymer have been investigated using the Thermally Stimulated Current (TSC) technique. Films were polarized with various field strengths in the range 20 to 80 kV cm?1. The TSC spectrum showed four peaks (at ~ 70, 105, 130 and ~ 180°); their origins are explained in terms of the relaxation of the nitrile side-groups, glass-transition of the copolymer and the space-charge displacement. Thermal peak-cleaning and partial-heating techniques were applied in order to determine the exact positions of the peaks and the activation energies associated with the processes. 相似文献
270.
R.?Vijayaraghavan V.?K.?Goel S.?Dey T.?P.?SinghEmail author 《Structural chemistry》2005,16(4):445-452
To develop a complete set of design rules with α,β-dehydro residues, a tripeptide N-Boc-Phe-ΔPhe-Ile-OCH3 was synthesized. The synthesis was carried out in solution phase using azlactone procedure. The three-dimensional structure of the peptide was determined by X-ray diffraction method and refined to an R-factor of 0.085. The structure contains three peptide molecules in the asymmetric unit. In all the three crystallographically independent molecules ΔPhe residue adopts one of the three conformations that have been reported for a ΔPhe residue. The overall conformations of three peptide molecules in the asymmetric unit are not similar. Two out of three crystallographically independent molecules adopt type II β-turn conformations whereas the third molecule is found having the characteristic S-shaped conformation in which the values of dihedral angles φ, ψ have opposite signs alternately. One of these two types of conformations has been observed when a ΔPhe is introduced at (i+2) position of a tetrapeptide. The β-turn conformation is stabilized by a 4→1 hydrogen bond where the hydrophobic side chains of residues at (i+1) and (i+3) positions stabilized the unfolded conformation with van der Waals interactions. The three independent molecules are locked together by three hydrogen bonds between molecules A and B and two hydrogen bonds between molecules B and C. 相似文献