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161.
A novel technique, named "core suction," for fabricating optical fiber preforms has been devised. The technique involves drawing the molten nonconventional core glass material into the cladding tube to form the preform. The developed technique is simple, inexpensive, and shows great potential for fabricating preforms of highly nonlinear nonconventional glasses as the core material. Preforms were made with Schott SF6 and a lead-tellurium-germanate glass in silica cladding tubes, and these preforms were then pulled into fibers. 相似文献
162.
The results of a computer simulation study of K? capture in emulsion nuclei are used to reappraise experimental data pertaining to the question of existence of a ‘neutron halo’ on the surface of heavy nuclei. Our results indicate that the conclusion of the experimental study that there is an excess of neutrons on the surface of heavy nuclei is substantially correct though the neutron-to-proton ratio may be lower (~ 3) than its initially estimated value (~ 5). 相似文献
163.
A Riemannian space of embedding class two is characterised by two symmetric tensors a
ij
, b
ij
and a vector si, satisfying the equations of Gauss, Codazzi and Ricci. It is proved that the Gauss equations together with one set of Codazzi equations imply the other set of Codazzi equations and the Ricci equations, provided that the matrix of the tensor b
ij
(or a
ij
) is nonsingular. (The class m generalisation of the result has also been suggested). The result so proved has further been utilized in finding explicitly the a
ij
's and b
ij
's in the case of the static spherically symmetric line element. It is further indicated that the a
ij
's and b
ij
's so obtained are responsible for the different types of embeddings of the spacetime considered. 相似文献
164.
A fourth order numerical method for solving the general second order differential equation is suggested. This method is self starting, P-stable (when applied to ), and it involves only two function evaluations per step. Easily calculable and simple truncation error estimates are given, which can be used for automatic error control in computations. The method is illustrated on numerical examples. 相似文献
165.
New monomeric dialkyl- or diphenyl-silylbisamidoximes and dialkyl(ethoxy)silylamidoximes have been characterised. Their infrared spectra have been interpreted and diamagnetic susceptibility of some of them has been determined. 相似文献
166.
The infrared absorption spectra of 2,3- and 3,5-dichloroanilines have been recorded in the region 250–4000 cm−1. The spectra of the latter are recorded in solid phase (KBr and Nujol mull) and in CS2/CCl4 and CHCl3 solutions while that of the former in thin film only. The spectra have been analysed assuming C
3
and C2v
point group symmetry respectively and a tentative assignment of the observed bands to different fundamental modes has been
made. 相似文献
167.
Characteristics of hyperfragments produced from K? capture in nuclear emulsion are investigated through computer simulation and compared with corresponding experimental results. The nuclear cascade is completely simulated and the nucleus is de-excited through evaporation after estimating the excitation energy. Characteristics of hyperfragments particularly their mass distribution and the prong distribution of their production star can be used in favour of the peripheral hypothesis of K? absorption. The calculated and the observed range distributions of the heavy hyperfragments are not in complete agreement, a feature leading to the inference that spallation may not be the only process responsible for the production of such hyperfragments. 相似文献
168.
An efficient and convenient synthesis of 2-amino-6-aryl-4-methylsulfanylnicotinonitriles (2), 2-amino-6-aryl-4-substituted-aminonicotinonitriles (4), and 2-amino-6-aryl-4-substituted-aminopyridines (6) has been delineated and illustrated through base-catalyzed ring transformation of 6-aryl-3-cyano-4-methylsulfanyl/substituted-amino-2H-pyran-2-ones (1, 3, and 5) with cyanamide and ammonium carbonate separately. 相似文献
169.
Goel A Singh FV Kumar V Reichert M Gulder TA Bringmann G 《The Journal of organic chemistry》2007,72(20):7765-7768
A one-pot general synthesis of highly functionalized quateraryls through carbanion-induced, base-catalyzed ring transformation of 5,6-diaryl-2H-pyran-2-ones and core-substituted phenylacetones is delineated. These conversions were found to give diversely functionalized benzenes bearing peripheral aryl rings, some of which possess inherent atropisomerism. Exemplarily for one of the quateraryls, the optical resolution of the respective atropo-enantiomers by HPLC on a chiral phase and the assignment of their absolute axial configurations succeeded by LC-CD coupling in combination with semiempirical CNDO/S and TDDFT CD calculations. This synthetic approach offers-in a transition metal-free environment-high flexibility in the construction of quateraryls with the desired conformational freedom along the molecular axis, which may help in exploring and developing new potential ligands for asymmetric synthesis. 相似文献
170.
Alok Goel David Savage Paula N. Kelly Dermot O’Sullivan Peter T.M. Kenny 《Journal of organometallic chemistry》2007,692(6):1292-1299
A series of N-meta-ferrocenyl benzoyl dipeptide esters 2-5 have been prepared by coupling meta-ferrocenyl benzoic acid 1b to the dipeptide ethyl esters using the conventional 1,3-dicyclohexylcarbodiimide (DCC), 1-hydroxybenzotriazole (HOBt) protocol. The dipeptides employed in the synthesis were AlaGly(OEt) (2), AlaAla(OEt) (3), AlaLeu(OEt) (4) and AlaPhe(OEt) (5). The compounds were fully characterized by a range of NMR spectroscopic techniques, mass spectrometry (MALDI-MS, ESI-MS), and cyclic voltammetry (CV). In addition, the X-ray crystal structure and cytotoxicity of N-{meta-(ferrocenyl)-benzoyl}-l-alanine-glycine ethyl ester (2) towards lung cancer cells has been determined. 相似文献