全文获取类型
收费全文 | 308篇 |
免费 | 11篇 |
国内免费 | 5篇 |
专业分类
化学 | 235篇 |
晶体学 | 2篇 |
力学 | 12篇 |
数学 | 24篇 |
物理学 | 51篇 |
出版年
2023年 | 2篇 |
2022年 | 2篇 |
2017年 | 4篇 |
2016年 | 7篇 |
2015年 | 6篇 |
2014年 | 7篇 |
2013年 | 10篇 |
2012年 | 24篇 |
2011年 | 20篇 |
2010年 | 9篇 |
2009年 | 7篇 |
2008年 | 18篇 |
2007年 | 33篇 |
2006年 | 26篇 |
2005年 | 17篇 |
2004年 | 17篇 |
2003年 | 5篇 |
2002年 | 6篇 |
2001年 | 3篇 |
2000年 | 6篇 |
1999年 | 4篇 |
1998年 | 4篇 |
1997年 | 6篇 |
1996年 | 5篇 |
1995年 | 3篇 |
1992年 | 5篇 |
1985年 | 3篇 |
1984年 | 7篇 |
1983年 | 4篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1976年 | 5篇 |
1975年 | 6篇 |
1974年 | 2篇 |
1973年 | 3篇 |
1972年 | 4篇 |
1971年 | 1篇 |
1970年 | 2篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1966年 | 3篇 |
1943年 | 2篇 |
1941年 | 1篇 |
1932年 | 1篇 |
1908年 | 1篇 |
1891年 | 2篇 |
排序方式: 共有324条查询结果,搜索用时 343 毫秒
51.
52.
53.
Izod K Liddle ST Clegg W Harrington RW 《Dalton transactions (Cambridge, England : 2003)》2006,(28):3431-3437
The secondary phosphines Ar(C6H4-2-CH2NMe2)PH [Ar = mes (3), Tripp (4)] may be isolated in good yields from reactions between Li(C6H4-2-CH2NMe2) and the respective dichlorophosphine, followed by reduction with LiAlH4 [mes = 2,4,6-Me3C6H2, Tripp = 2,4,6-Pri3C6H2]. Metalation of either 3 or 4 with BunLi gives the corresponding lithium compound; the lithium derivative of 3 was isolated as the separated ion pair complex [Li(12-crown-4)2][(mes)(C6H4-2-CH2NMe2)P].THF (5). The lithium complexes Ar(C6H4-2-CH2NMe2)PLi undergo metathesis reactions with either NaOBut or KOBut to give the heavier alkali metal phosphides {Ar(C6H4-2-CH2NMe2)P}M.1/2OEt2 [Ar = mes, M = Na (8), K (9); Ar = Tripp, M = K (10)]. Metathesis reactions between 9 and LaI3(THF)4 give only intractable products; in contrast, a metathesis reaction between 10 and LaI3(THF)4 yields the heteroleptic complex {(Tripp)(C6H4-2-CH2NMe2)P}2LaI (11). Compound 11 reacts cleanly with K{N(SiMe3)2} to give {(Tripp)(C6H4-2-CH2NMe2)P}2La{N(SiMe3)2} (14). Compounds 3-5, 8-11 and 14 have been characterised by multi-element NMR spectroscopy; in addition, compounds 5, 11 and 14 have been studied by X-ray crystallography. 相似文献
54.
Argent SP Adams H Riis-Johannessen T Jeffery JC Harding LP Clegg W Harrington RW Ward MD 《Dalton transactions (Cambridge, England : 2003)》2006,(42):4996-5013
The coordination chemistry of a series of di- and tri-nucleating ligands with Ag(I), Hg(I) and Hg(II) has been investigated. Most of the ligands contain two or three N,N'-bidentate chelating pyrazolyl-pyridine units pendant from a central aromatic spacer; one contains three binding sites (2 + 3 + 2-dentate) in a linear sequence. A series of thirteen complexes has been structurally characterised displaying a wide range of structural types. Bis-bidentate bridging ligands react with Ag(I) to give complexes in which Ag(I) is four-coordinate from two bidentate donors, but the complexes can take the form of one-dimensional coordination polymers, or dinuclear complexes (mesocate or helicate). A tris-bidentate triangular ligand forms a complicated two-dimensional coordination network with Ag(I) in which Ag...Ag contacts, as well as metal-ligand coordination bonds, play a significant role. Three dinuclear Hg(I) complexes were isolated which contain an {Hg2}2+ metal-metal bonded core bound to a single bis-bidentate ligand which can span both metal ions. Also characterised were a series of Hg(II) complexes comprising a simple mononuclear four-coordinate Hg(II) complex, a tetrahedral Hg(II)4 cage which incorporates a counter-ion in its central cavity, a trinuclear double helicate, and a trinuclear catenated structure in which two long ligands have spontaneously formed interlocked metallomacrocyclic rings thanks to cyclometallation of two of the Hg(II) centres. 相似文献
55.
Aldridge S Kays DL Al-Fawaz A Jones KM Horton PN Hursthouse MB Harrington RW Clegg W 《Chemical communications (Cambridge, England)》2006,(24):2578-2580
The reaction of (eta(5)-C5H5)Fe(CO)2B(C6F5)2 with CO has been shown to proceed via ligand substitution at the metal with accompanying transfer of the boryl fragment (via C-H insertion) to the Cp ring, thereby generating the zwitterion [eta(5)-C5H4B(C6F5)2H]Fe(CO)3 in quantitative yield. 相似文献
56.
57.
58.
59.
60.
Skabara PJ Pozo-Gonzalo C Lardiés Miazza N Laguna M Cerrada E Luquin A González B Coles SJ Hursthouse MB Harrington RW Clegg W 《Dalton transactions (Cambridge, England : 2003)》2008,(23):3070-3079
A series of new metal (M) dithiolene complexes bearing terthiophene (3, 12, M = Ni; 4, M = Pd; 5, 6, M = Au) and 2,5-bis(para-methoxyphenyl)thiophene units (14, M = Ni; 15, 16, M = Au; 17, M = Pd) have been synthesised in 38-99% yield. The electrochemical properties of the materials have been characterised by cyclic voltammetry and UV-vis spectroelectrochemistry. The nickel complexes possess low oxidation potentials (-0.12 to -0.25 V vs Ag/AgCl) due to the electron-rich dithiolene centres and all complexes display ligand-based redox activity. The terthiophene derivatives have been polymerised by electrochemical oxidation to give stable films with, in the case of poly(3), broad absorption characteristics. Charge transfer materials have been isolated from 14 and 16 with conductivities in the range 9 x 10(-6) to 7 x 10(-8) S cm(-1). 相似文献