The n-loop expansion of the Reggeon calculus

We apply the technique known in solid state physics as the n-loop expansion to calculate the critical indices of the φ³ Gribov Reggeon calculus directly in two transverse dimensions. Infrared pathologies of the massless theory require the calculation to be done in the infinite momentum limit of the massive theory. For n = 1 the results are close to those of the ε-expansion in O(ε). For n = 2 the β function has no zero, analogously to the case in solid state physics. Use of a Padé approximant for β yields σ_tot ≈ (1n s)^0.27 at infinity, close to the O(ε²) result.     

Study of pp and ΛΛ production in π±p reactions at 18.5 GeV/c

Studies have been made of the rare reactions $\text{π}{}^{\mathrm{+}}\text{p}\text{→ π}{}^{\mathrm{+}}\text{pp}\text{p}$ and $\text{Λ +}\text{Λ}\text{+}\text{anything}$, and of $\text{π}{}^{\mathrm{?}}\text{p}\text{→ π}{}^{\mathrm{?}}\text{pp}\text{p}$ and $\text{Λ +}\text{Λ}\text{+}\text{anything}$, with cross sections of 18.5 ± 5.5, 10.7 ± 3.0, 12.0 ± 5.0, and 19.7 ± 4.8 μb, respectively. Production characteristics of these reactions are examined and effective-mass spectra are presented. There is no significant evidence in the data for production of Ψ(3095) in the baryon-antibaryon system, or for any other high-mass resonances.     

Test of correlation expansions for inelastic scattering of protons from 16O and 40Ca in Glauber theory

Two different versions of a correlation expansion for the A-body nuclear transition density required to evaluate the Glauber amplitude for inelastic proton-nucleus scattering are tested. Antisymmetrized oscillator wave functions, containing only Pauli correlations, are used to calculate the “exact” amplitude as well as various terms in the correlation expansions for the excitation of the 3^? (6.13 MeV) state of ¹⁶O and the 5^? (4.49 MeV) state of ⁴⁰Ca. The leading term in both expansions, which ignores all correlations and corresponds to the Glauber theory version of the DWIA, leads to errors which are larger than present experimental errors, especially at large momentum transfers. In one version of the correlation expansion, due to Alkhazov et al., the first-order correction contains both elastic and inelastic two-body correlations and leads to satisfactory results. In the other version, used by Abgrall et al., the first-order correction contains only inelastic two-body correlations. In this case the first- and second-order corrections are needed to obtain accuracy comparable to that of the latest experiments.     

Amino-functionalised diarylphosphide complexes of the alkali metals and lanthanum

The secondary phosphines Ar(C6H4-2-CH2NMe2)PH [Ar = mes (3), Tripp (4)] may be isolated in good yields from reactions between Li(C6H4-2-CH2NMe2) and the respective dichlorophosphine, followed by reduction with LiAlH4 [mes = 2,4,6-Me3C6H2, Tripp = 2,4,6-Pri3C6H2]. Metalation of either 3 or 4 with BunLi gives the corresponding lithium compound; the lithium derivative of 3 was isolated as the separated ion pair complex [Li(12-crown-4)2][(mes)(C6H4-2-CH2NMe2)P].THF (5). The lithium complexes Ar(C6H4-2-CH2NMe2)PLi undergo metathesis reactions with either NaOBut or KOBut to give the heavier alkali metal phosphides {Ar(C6H4-2-CH2NMe2)P}M.1/2OEt2 [Ar = mes, M = Na (8), K (9); Ar = Tripp, M = K (10)]. Metathesis reactions between 9 and LaI3(THF)4 give only intractable products; in contrast, a metathesis reaction between 10 and LaI3(THF)4 yields the heteroleptic complex {(Tripp)(C6H4-2-CH2NMe2)P}2LaI (11). Compound 11 reacts cleanly with K{N(SiMe3)2} to give {(Tripp)(C6H4-2-CH2NMe2)P}2La{N(SiMe3)2} (14). Compounds 3-5, 8-11 and 14 have been characterised by multi-element NMR spectroscopy; in addition, compounds 5, 11 and 14 have been studied by X-ray crystallography.     

Complexes of Ag(I), Hg(I) and Hg(II) with multidentate pyrazolyl-pyridine ligands: From mononuclear complexes to coordination polymers via helicates, a mesocate, a cage and a catenate

The coordination chemistry of a series of di- and tri-nucleating ligands with Ag(I), Hg(I) and Hg(II) has been investigated. Most of the ligands contain two or three N,N'-bidentate chelating pyrazolyl-pyridine units pendant from a central aromatic spacer; one contains three binding sites (2 + 3 + 2-dentate) in a linear sequence. A series of thirteen complexes has been structurally characterised displaying a wide range of structural types. Bis-bidentate bridging ligands react with Ag(I) to give complexes in which Ag(I) is four-coordinate from two bidentate donors, but the complexes can take the form of one-dimensional coordination polymers, or dinuclear complexes (mesocate or helicate). A tris-bidentate triangular ligand forms a complicated two-dimensional coordination network with Ag(I) in which Ag...Ag contacts, as well as metal-ligand coordination bonds, play a significant role. Three dinuclear Hg(I) complexes were isolated which contain an {Hg2}2+ metal-metal bonded core bound to a single bis-bidentate ligand which can span both metal ions. Also characterised were a series of Hg(II) complexes comprising a simple mononuclear four-coordinate Hg(II) complex, a tetrahedral Hg(II)4 cage which incorporates a counter-ion in its central cavity, a trinuclear double helicate, and a trinuclear catenated structure in which two long ligands have spontaneously formed interlocked metallomacrocyclic rings thanks to cyclometallation of two of the Hg(II) centres.     

Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment

The reaction of (eta(5)-C5H5)Fe(CO)2B(C6F5)2 with CO has been shown to proceed via ligand substitution at the metal with accompanying transfer of the boryl fragment (via C-H insertion) to the Cp ring, thereby generating the zwitterion [eta(5)-C5H4B(C6F5)2H]Fe(CO)3 in quantitative yield.