Higgs boson searches at the Tevatron

This article reviews the Higgs searches at the Tevatron, as presented over the summer of 2012; both standard model (SM) and beyond the standard model (BSM) results are discussed as detailed (arXiv: 1207.0449; Phys. Rev. Lett., 2012, 109: 071804; Phys. Rev. D, 2012, 85: 032005). We discuss the combination of searches by the CDF and D0 Collaborations for the standard model Higgs boson in the mass range 100–200 GeV/c ² produced in the the gg → H, WH, ZH, t{ie27-1}H, and vector boson fusion production modes, and decaying in the H → b{ie27-2}, H → W ⁺ W ^?, H → ZZ, H → τ ⁺ τ ^?, and H → γγ modes. The data, collected at the Fermilab Tevatron collider in p{ie27-3} collisions at {ie27-4} TeV, correspond to integrated luminosities of up to 10 fb^?1. In the absence of signal, we expect to exclude the regions 100<m _H < 120 GeV/c ² and 139<m _H < 184 GeV/c ². We exclude, at the 95% C.L., two regions: 100<m _H < 103 GeV/c ², and 147<m _H < 180 GeV/c ². We observe a significant excess of events in the mass range between 115 and 140 GeV/c ². The local significance corresponds to 3.0 standard deviations at m _H = 120 GeV/c ²; the global significance (incorporating the look-elsewhere effect) for such an excess anywhere in the full mass range investigated is approximately 2.5 standard deviations. Furthermore, we separately combine searches for H → b{ie27-5}, H → W+W ^? and H → γγ. We find that the excess is concentrated in the H → b{ie27-6} channel, appearing in the searches over a broad range of m _H ; the maximum local significance of 3.3 standard deviations corresponds to a global significance of approximately 3.1 standard deviations. The observed signal strengths in all channels are consistent with the expectation for a standard model Higgs boson at m _H = 125 GeV/c ². The production of neutral Higgs bosons in association with b-quarks can be significantly enhanced in various beyond the standard model scenarios, including Supersymmetry. The recent combination of such searches from the two collaborations is discussed.     

A mild and highly convenient chemoselective alkylation of thiols using Cs2CO3-TBAI

A mild and improved method for the synthesis of thioethers has been developed. In the presence of cesium carbonate, tetrabutylammonium iodide, and DMF, various alkyl and aryl thiols underwent S-alkylation to afford structurally diverse sulfides in high yield. Unprotected mercaptoalcohols and thioamines reacted chemoselectively at the sulfur moiety exclusively. An example of a one-pot, solid-phase synthesis of a thioether is also described.     

Synthesis and characterization of 7-(CH3)3N-4- {2,4-(NO2)2C6H3S}-nido-7-CB10H11 and its Biodistribution in C57B16 Mice Bearing B16 Melanoma

7-(CH₃)₃N-4-{2,4-(NO₂)₂C₆H₃S}-nido-7-CB₁₀H₁₁ has been synthesized through a Friedel-Crafts substitution reaction on 7-(CH₃)3N-nido-7- CB₁₀H₁₂. A biodistribution study in mice with implanted B16 melanoma indicates that the compound locates in neoplastic tissue at concentrations which suggest that its use in ¹⁰B neutron capture therapy may be feasible.     

Fine structure splitting of high 2D states of 39K

The technique of Doppler free two photon absorption is used to measure the fine structure interval in the ²D states of potassium for principal quantum numbers from 8 to 19.     

Isolement et identification de composés phénoliques et monoterpéniques de la mousse de chêne (Evernia prunastri (L.) Ach.)

The composition of different oakmoss extracts was investigated by combined gas chromatography/mass spectrometry. A series of 38 compounds – especially phenol derivatives and monoterpenes – was identified, 22 of which have not yet been reported as constituents of oakmoss.     

Nuclear magnetic resonance diagnosis of an anaplastic astrocytoma

A patient presented with an 8-month history of a progressive left homonymous visual field deficit, left hemiparesis, and a left thalamocortical sensory deficit that was not detectable by repeated conventional neurodiagnostic evaluations. Proton nuclear magnetic resonance (NMR) imaging revealed a right parietal lesion characterized by a prolonged T₂ (spin-spin relaxation time). At surgery, the mass proved to be an anaplastic astrocytoma. NMR appears to be more sensitive than x-ray computerized tomography scanning in some patients with malignant gliomas and offers the clinician an additional probe with which to evaluate these patients.     

He I and He II spectra of 2-halopyridines

The He I and He II ultraviolet photoelectron spectra of 2-fluoro-, 2-chloro-, 2-bromo-, and 2-iodopyridine have been recorded and interpreted in terms of a composite-molecule model. The sequence of the four lowest ionization energies for 2-fluoro- and 2-chloropyridine is: π₃ (1a₂) > n_N (11a₁) > π₂ (2b₁) > π_pyr (7b₂), whereas for 2-bromo- and 2-iodopyridine the assignment is: π₃ (1a₂) - π_X > n_N (11a₁) > π_X > π₂ (2b₁), where X represents a bromine and iodine lone-pair. Comparison of the He I and He II band intensities confirmed this assignment. However, ab initio calculations at the STO-3G*/STO-3G* and 6–31G**/STO-3G* levels did not agree with the sequence predicted by either the composite-molecule model, simple correlations and the He I/He II cross-section ratios. For the 2-fluoropyridine, a comparison using the HAM/3 model was found to be in agreement with this assignment.     

Diborane: High resolution infrared rovibration studies of 11B2H6 and 11B2D6

Ground state rotation and quartic distortion constants were obtained for ¹¹B₂D₆ from the analysis of high resolution (～0.05 cm^?1) Fourier transform infrared spectra. The bands studied comprised the ν₁₇, ν₁₈ type A, and ν₁₄, ν₉ + ν₁₅ type C bands of ¹¹B₂H₆ and the ν₁₆, ν₁₇, ν₁₈ type A, ν₈ type B, and ν₁₄ type C bands of ¹¹B₂D₆. In the case of ¹¹B₂H₆, the authors' ground state data were combined with those of Lafferty et al. obtained from a previous study (J. Mol. Spectrosc.33, 345–367 (1970)) at comparable resolution of the ν₁₆ type A and ν₈ type B fundamentals. Information on the ground state rotational energy manifold of ¹¹B₂H₆ was accumulated up to J = 23, K_a = 18, and of ¹¹B₂D₆ up to J = 32, K_a = 22. This permitted rather precise determination of the distortion constants Δ_J⁰, Δ_JK⁰, Δ_K⁰, although δ_J⁰ and δ_K⁰ proved to be too small (< 10^?7 cm^?1) and were constrained to values calculated from the force field. Sets of upper state parameters were determined for all vibrational levels studied. Although these appear to be essentially unperturbed globally, several localized perturbations were observed and identified.