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681.
A Brønsted acidic ionic liquid-[Hmim]HSO4 promoted unexpected reaction of Baylis-Hillman alcohols and diarylmethanols with p-toluenesulfonylmethyl isocyanide (TosMIC) affording the corresponding sulfone derivatives instead of N-tosylmethyl amides is reported. After isolation of the product, the ionic liquid [Hmim]HSO4 was easily recycled for further use. 相似文献
682.
Manju Sharma Rohit Soni Asiya Nazir Harinder Singh Oberoi Bhupinder Singh Chadha 《Applied biochemistry and biotechnology》2011,163(5):577-591
A thermotolerant Aspergillus fumigatus strain isolated from composting pile of mixed industrial waste was found to produce a spectrum of cellulase and hemicellulases
when cultured on rice straw solidified substrate. The two-dimensional electrophoresis (2DE) resolved the secretome into 57
distinct protein spots. The zymograms developed against 2DE gels identified the presence of three β-glucosidases and five
CBHI/EGI isoforms in the secretome. The peptide mass fingerprinting of 17 protein spots by liquid chromatography mass spectrometry
characterized the secretome into different glycosyl hydrolase families. The enzyme cocktail produced by A. fumigatus was capable of efficient hydrolysis of alkali pretreated rice straw (at 7% and 10% w/v) resulting in 95% and 91% saccharification, respectively. 相似文献
683.
A careful methodological study revealed a true Click catalytic system based on commercially available [CuBr(PPh(3))(3)]. This system is active at room temperature, with 0.5 mol % [Cu] (or less), in the absence of any additive, and it does not require any purification step to isolate pure triazoles. 相似文献
684.
A steady state thermodynamic model for an air—cooled finned—tube condenser, used in a typical deep freezer vapour compression
system, operating with pure and refrigerant mixtures has been developed using finite difference method. The heat transfer
aspects in the condenser are treated uniquely for superheated, two—phase and subcooled regimes and studied for various heat
load, pressure, temperature, and mass flow rate. The condensation heat transfer coefficient, the tube length required for
condensation, the degree of subcooling, and the temperature glide for different ambient temperatures are estimated. The simulation
and the experimental results are in good agreement. 相似文献
685.
Ratan Lal 《Physica C: Superconductivity and its Applications》2010,470(4):281-284
The critical current density Jc of some of the superconducting samples, calculated on the basis of the Bean’s model, shows negative curvature for low magnetic field with a downward bending near H = 0. To avoid this problem Kim’s expression of the critical current density, Jc = k/(H0 + H), where Jc has positive curvature for all H, has been employed by connecting the positive constants k and H0 with the features of the hysteresis loop of a superconductor. A relation between the full penetration field Hp and the magnetic field Hmin, at which the magnetization is minimum, is obtained from the Kim’s theory. Taking the value of Jc at H = Hp according to the actual loop width, as in the Bean’s theory, and at H = 0 according to an enhanced loop width due to the local internal field, values of k and H0 are obtained in terms of the magnetization values M+(?Hmin), M?(Hmin), M+(Hp) and M?(Hp). The resulting method of estimating Jc from the hysteresis loop turns out to be as simple as the Bean’s method. 相似文献
686.
Arshad Iqbal Ayaz Ali Sher Naveed Muhammad Syed Lal Badshah Abdul-Hamid Emwas Mariusz Jaremko 《Molecules (Basel, Switzerland)》2022,27(13)
Chrozophora tinctoria is an annual plant of the family Euphorbiaceae, traditionally used as a laxative, a cathartic and an emetic. A methanolic extract of Chrozophora tinctoria (MEC) whole plant and an n-butanol fraction of Chrozophora tinctoria (NBFC) were analyzed by gas chromatography–mass spectrometry (GC-MS) to detect the phytochemicals. MEC and NBFC were tested for in vitro anti acetylcholinesterase (AChE) potential. The effect of both samples on intestinal propulsive movement and spasmolytic activity in the gastrointestinal tract (GIT) was also studied. About twelve compounds in MEC and three compounds in NBFC were tentatively identified through GC-MS. Some of them are compounds with known therapeutic activity, such as toluene; imipramine; undecane; 14-methyl-pentadecanoic acid methyl ester; and hexadecanoic acid. Both NBFC and MEC samples were checked for acute toxicity and were found to be highly toxic in a dose-dependent manner, causing diarrhea and emesis at 1 g/kg concentration in pigeons, with the highest lethargy and mortality above 3 g/kg. Both the samples of Chrozophora tinctoria revealed significant (p ≤ 0.01) laxative activity against metronidazole (7 mg/kg) and loperamide hydrochloride (4 mg/kg)-induced constipation. NBFC (81.18 ± 2.5%) and MEC (68.28 ± 2.4%) significantly increased charcoal meal intestinal transit compared to distal water (41.15 ± 4.3%). NBFC exhibited a significant relaxant effect (EC50 = 3.40 ± 0.20 mg/mL) in spontaneous rabbit jejunum as compared to MEC (EC50 = 4.34 ± 0.68 mg/kg). Similarly, the impact of NBFC on KCl-induced contraction was more significant than that of MEC (EC50 values of 7.22 ± 0.06 mg/mL and 7.47 ± 0.57 mg/mL, respectively). The present study scientifically validates the folk use of Chrozophora tinctoria in the management of gastrointestinal diseases such as constipation. Further work is needed to isolate the phytochemicals that act as diarrheal agents in Chrozophora tinctoria. 相似文献
687.
688.
Manik Lal Maity Samyadeb Mahato Prof. Dr. Subhajit Bandyopadhyay 《Angewandte Chemie (International ed. in English)》2023,62(45):e202311551
The chalcone-flavylium photochromic system switches in aqueous media. However, the chalcone→flavylium conversion requires detrimental ultra-violet (UV) light for the switching which deters their applications in the biological domain. To address this issue, we have synthesized strategically modified chalcone scaffolds that can be reversibly switched to the flavylium forms with visible light ranging from 456 nm (blue) to 640 nm (red). 相似文献
689.