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41.
42.
The absorption spectrum of acetylene-d has been observed at high resolution between 6470 and 6630 cm−1 using an external cavity diode laser. Three cold bands have been observed: the strong 2ν1 band, the weaker ν1 + ν2 + 2ν5 band, and the (ν1 + ν3 + ν5)1 band, which gains its intensity through Coriolis resonance with 2ν1. Centers of unblended lines are determined with an accuracy of approximately 10 MHz. 相似文献
43.
K
β-to-K
α X-ray intensity ratios of Fe and Ni in pure metals and in Fe
x
Ni1−x
alloys (x=0.20, 0.50, 0.58) exhibiting similar crystalline structure have been measured following excitation by 59.54 keV γ-rays from a 241Am point source, to understand as to why the properties of permalloy Fe0.2Ni0.8 is distinct from other alloy compositions. It is observed that the valence electronic structure of Fe0.2Ni0.8 alloy is totally different from other alloys which may be attributed to its special magnetic properties. 相似文献
44.
45.
R.DeivaVenkatesh M.Grmela JamalChaouki 《中国颗粒学报》2005,3(3):165-169
Simulations of the gas fluidization of a cohesive powder were performed using the Stokesian Dynamics method and an agglomeration-deagglomeration model to investigate methods of improving the fluidizability of fine powders. Three techniques (a) high gas velocity (b) vibration-assisted fluidization and (c) tapered fluidizer were used in the simulations which provided detailed information on the bed microscopy such as the motion of 1 O0 particles in a fluidizing vessel along with the formation and destruction of cohesive bonds dudng collisions. While all three techniques were found to effectively improve the fluidizability of a strongly cohesive powder, we suggest a combination of high velocity fluidization assisted by extemal vibration of the fluidized bed to minimize entrainment of particles. 相似文献
46.
T. J. Hardwick 《国际化学动力学杂志》1969,1(3):325-337
The kinetics of the thermally and radiation initiated chain reaction between trichloroethylene and cyclopentane to produce 1,1-dichlorovinylcyclopentane and hydrogen chloride have been investigated in the temperature range 250–360°C at high pressure in the gas phase. The rate governing step in the chain is (k3 = 3.3 × 109 exp ?(4800/RT) cc mole?1 sec ?1). The rate of the unimolecular decomposition of trichloroethylene is 1.4 × 1014 exp ?(61,200/RT) sec?1. 相似文献
47.
Micol Santi Jakob Seitz Rossana Cicala Tomas Hardwick Dr. Nisar Ahmed Prof. Dr. Thomas Wirth 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(71):16230-16235
Amino acid derivatives undergo non-Kolbe electrolysis to afford enantiomerically enriched α-alkoxyamino derivatives through intermediate chiral carbenium ions. The products contain N,O-acetals which are important structural motifs found in bioactive natural products. The reaction is performed in a continuous flow electrochemical reactor coupled to a 2D-HPLC for immediate online analysis. This allowed a fast screening of temperature, electrode material, current, flow-rate and concentration in a DoE approach. The combination with online HPLC demonstrates that also stereoselective reactions can benefit from a hugely accelerated optimisation by combining flow electrochemistry with multidimensional analysis. 相似文献
48.
The Zeeman effect facilitates certain rotational assignments in bands of the electronic system of NO2. A partial analysis of two bands of this system is reported. 相似文献
49.
Laurence J. Hardwick Michael Holzapfel Alexander Wokaun Petr Novk 《Journal of Raman spectroscopy : JRS》2007,38(1):110-112
Raman spectroscopy was performed on various mixtures of the ionic liquid salt, 1‐ethyl‐3‐methylimidazolium‐bis(trifluoromethylsulfonyl)imide (EMI‐TFSI). When EMI‐TFSI is used in combination with a lithium salt, it could be a potential electrolyte for lithium‐ion or lithium metal batteries. The Raman spectra of EMI‐TFSI, EMI‐TFSI 0.5 M Li‐TFSI, EMI‐TFSI 0.5 M Li‐TFSI 2 M vinylene carbonate (VC) and EMI‐TFSI 0.5 Li‐TFSI 2 M ethylene carbonate (EC) were collected and compared. A comparison of the peak positions of the δs CF3 mode at 742 cm−1 demonstrates that when carbonate additives are present, the lithium ion is no longer interacting with the TFSI anion. Instead, it is coordinated with the carbon–oxygen double bond of the carbonates. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
50.
C. Daum L. Hertzberger W. Hoogland S. Peters P. Van Deurzen A. Berglund V. Chabaud A. Gonzalez-Arroyo B. Hyams H. Tiecke P. Weilhammer A. Dwurazny H. Palka G. Polok K. Rybicki M. Turala J. Turnau A. Zalewska H. Becker G. Blanar M. Cerrada H. Dietl J. Gallivan M. Glaubman R. Klanner E. Lorenz G. Lütjens G. Lutz W. Männer A. Pugl U. Stierlin J. Blakey M. Bowler R. Cashmore J. Loken J. Spalding G. Thompson B. Alper C. Damerell A. Gillman J. Hardwick F. Wickens Accmor Collaboration 《Zeitschrift fur Physik C Particles and Fields》1984,23(4):339-347