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171.
ABSTRACT A new catalytic kinetic fluorescent quenching method for the determination of trace gold(III) was investigated. The method was based on the catalytic effect of gold on oxidation of 3-(3′-methylphenyl)-5- (2′-arsenoxylphenylazo) rhodanine by hydrogen peroxide in potassium hydrogen phthalate–hydrochloric acid (pH = 3.4). Under the optimum conditions, the great decrease of fluorescence intensity has a linear relationship against the concentration of gold in the range of 0 to 12.0 µg·L?1 with a detection limit of 6.0 × 10?10g·L?1. The coexistent metal ions can be separated, and gold can be enriched by TBP resin of solid-phase extraction, which greatly improves the selectivity and sensitivity of the system. The method can be used to determine trace amounts of gold in ore samples successfully with satisfactory results. 相似文献
172.
A theoretical investigation is reported of the fine structure levels and the spin-singlet contributions to zero-field-splitting (ZFS) parameters for Cr2+ ion in CdGa2S4 crystals. Firstly, the complete energy matrix including all spin states for a 3d 4 ion in tetrahedral D 2d symmetry is constructed according the double-group chain in the strong-field scheme. Then, by diagonalizing the complete energy of electron–electron interactions, the crystal field and the spin–orbit coupling for the Cr2+ (3d 4) ion in CdGa2S4 crystal, the fine structure levels and the spin-singlet contributions to ZFS parameters a, D and F are calculated. The results show that the spin-singlet contribution to D is negligible, but the contributions to a and F are very important. So, to obtain more accurate ZFS parameters for 3d 4 ions in the tetrahedral crystals, all spin states should be considered. 相似文献
173.
Fuzzy半群中的Fuzzy理想 总被引:4,自引:4,他引:4
本文先引入Fuzzy半群中Fuzzy理想的概念,进而讨论它们的一些代数性质,推广了前人的一些结果。 相似文献
174.
Theoretical analysis of the velocity field, stress field and vortex sheet of generalized second order fluid with fractional anomalous diffusion 总被引:1,自引:0,他引:1
The velocity field of generalized second order fluid with fractional anomalous diiusion caused by a plate moving impulsively
in its own plane is investigated and the anomalous diffusion problems of the stress field and vortex sheet caused by this
process are studied. Many previous and classical results can be considered as particular cases of this paper, such as the
solutions of the fractional diffusion equations obtained by Wyss; the classical Rayleigh’s time-space similarity solution;
the relationship between stress field and velocity field obtained by Bagley and co-worker and Podlubny’s results on the fractional
motion equation of a plate. In addition, a lot of significant results also are obtained. For example, the necessary condition
for causing the vortex sheet is that the time fractional diffusion index β must be greater than that of generalized second
order fluid α; the establiihment of the vorticity distribution function depends on the time history of the velocity profile
at a given point, and the time history can be described by the fractional calculus. 相似文献
175.
建立一个描述低能电子在多元多层介质中散射的物理模型,运用MonteCarlo方法模拟低能电子在靶体胶衬底中的复杂散射过程,在此基础上通过大量计算研究入射束能、胶层厚度、衬底材料等不同曝光条件对抗蚀剂沉积能密度分布的影响,获得沉积能分布规律:适量的低束能、薄胶层、低原子序数衬底可以使前散射电子对胶中沉积能密度分布的贡献增大、背散射电子的贡献减小,从而提高曝光分辨率.
关键词:
电子束曝光
MonteCarlo方法
低能电子散射
能量沉积 相似文献
176.
177.
Sheng-Li Tan 《Proceedings of the American Mathematical Society》2001,129(9):2553-2562
In this paper, we compute the integral closure of a cubic extension over a Noetherian unique factorization domain. We also present some applications to triple coverings and to rank two reflexive sheaves over an algebraic variety.
178.
熔融侧面泵浦耦合器光纤夹角对耦合效率的影响 总被引:1,自引:0,他引:1
泵浦耦合器是高功率光纤激光器的关键无源光器件,其制作工艺是采用泵浦光纤和主光纤侧面熔融的方法,该方法可以保持主光纤中信号光的低插入损耗,但泵浦光纤和主光纤之间的夹角对耦合效率影响较大。为解决这一问题,根据熔融侧面泵浦耦合器的结构特点,建立了物理模型,推导出各光纤中光功率与夹角关系的方程组,进行了数值仿真和实验论证,结果是随着泵浦光纤和主光纤之间夹角的减小,耦合效率会逐渐增大,但存在临界值,NA值小的泵浦光纤耦合效率高且临界角大,NA为0.22的泵浦光纤,夹角小于9.7时耦合效率最大值为96.9%,NA为0.15的泵浦光纤,夹角小于11.5时耦合效率最大值为97.8%。 相似文献
179.
Hao Huang Cuicui Du Hongyan Shi Xun Feng Jin Li Yanlei Tan Wenbo Song 《Particle & Particle Systems Characterization》2015,32(1):72-79
Uniform water‐soluble monolayer MoS2 quantum dots (MQDs) with lateral sizes of ≈2.1 nm, a clearly zigzag‐terminated edge, and a hexagonal lattice structure are achieved using ammonium molybdate, thiourea, and N‐acetyl‐l ‐cysteine (NAC) as precursors and the capping reagent in a facile one‐pot hydrothermal approach. MQDs have good dispersity and high stability in aqueous suspension and exhibit a significantly larger direct bandgap (3.96 eV) compared to monolayer MoS2 nanosheets (1.89 eV). Pronounced blue‐shifts in the wavelengths of both the excitonic absorption and intrinsic state emission with activated strong luminescence at room temperature beyond monolayer MoS2 nanosheets is demonstrated. Unusual upconversion photoluminescence is also observed and is caused by two successive transfers of energy from the near‐infrared (NIR) absorption generated by the NAC capping reagent to the hexagonal structure of MQDs. Additional optical properties of MQDs may provide numerous exciting technological applications. Here, MQDs are demonstrated as a highly selective fluorescent reagent for detecting tetracycline hydrochloride under UV and NIR irradiation. 相似文献
180.