首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   23902篇
  免费   4321篇
  国内免费   2705篇
化学   17729篇
晶体学   352篇
力学   1373篇
综合类   184篇
数学   2788篇
物理学   8502篇
  2024年   63篇
  2023年   574篇
  2022年   880篇
  2021年   1062篇
  2020年   1218篇
  2019年   1095篇
  2018年   935篇
  2017年   815篇
  2016年   1209篇
  2015年   1339篇
  2014年   1427篇
  2013年   1890篇
  2012年   2201篇
  2011年   2186篇
  2010年   1461篇
  2009年   1502篇
  2008年   1679篇
  2007年   1405篇
  2006年   1266篇
  2005年   1107篇
  2004年   809篇
  2003年   637篇
  2002年   619篇
  2001年   476篇
  2000年   436篇
  1999年   407篇
  1998年   290篇
  1997年   223篇
  1996年   260篇
  1995年   210篇
  1994年   177篇
  1993年   165篇
  1992年   135篇
  1991年   104篇
  1990年   110篇
  1989年   87篇
  1988年   77篇
  1987年   65篇
  1986年   59篇
  1985年   57篇
  1984年   47篇
  1983年   20篇
  1982年   18篇
  1981年   22篇
  1980年   13篇
  1979年   10篇
  1976年   12篇
  1975年   11篇
  1971年   9篇
  1957年   5篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
Given an n ‐vertex pseudorandom graph G and an n ‐vertex graph H with maximum degree at most two, we wish to find a copy of H in G , that is, an embedding φ : V ( H ) V ( G ) so that φ ( u ) φ ( v ) E ( G ) for all u v E ( H ) . Particular instances of this problem include finding a triangle‐factor and finding a Hamilton cycle in G . Here, we provide a deterministic polynomial time algorithm that finds a given H in any suitably pseudorandom graph G . The pseudorandom graphs we consider are ( p , λ ) ‐bijumbled graphs of minimum degree which is a constant proportion of the average degree, that is, Ω ( p n ) . A ( p , λ ) ‐bijumbled graph is characterised through the discrepancy property: | e ( A , B ) ? p | A | | B | | < λ | A | | B | for any two sets of vertices A and B . Our condition λ = O ( p 2 n / log n ) on bijumbledness is within a log factor from being tight and provides a positive answer to a recent question of Nenadov. We combine novel variants of the absorption‐reservoir method, a powerful tool from extremal graph theory and random graphs. Our approach builds on our previous work, incorporating the work of Nenadov, together with additional ideas and simplifications.  相似文献   
22.
Ding  Hao  Wang  Jin-Ting  Lu  Li-Qiao  Pan  Jian-Wen 《Nonlinear dynamics》2021,104(4):3365-3384
Nonlinear Dynamics - Conventional tuned liquid column dampers (TLCDs) are deficient in multidirectionality. In contrast, toroidal TLCDs are designed to extend the application to multidirectional...  相似文献   
23.
The Pd‐catalyzed polycondensation of 4‐octylaniline with various dibromoarylenes was carried out under microwave heating. Microwave heating led to a decrease in the reaction time and an increase in the molecular weight of the polymers as compared to conventional heating. Microwave heating also allowed the catalyst loading to be reduced to 1 mol %, yielding polymerization results that were comparable to those under conventional heating and 5 mol % catalyst. Investigations regarding field‐effect transistors and organic photovoltaic cells using the obtained poly(arylamine) with azobenzene units revealed that increasing the molecular weight of the polymer led to improved device performance, including hole mobility and power conversion efficiency. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 536–542  相似文献   
24.
Defects play a central role in controlling the electronic properties of two-dimensional (2D) materials and realizing the industrialization of 2D electronics. However, the evaluation of charged defects in 2D materials within first-principles calculation is very challenging and has triggered a recent development of the WLZ (Wang, Li, Zhang) extrapolation method. This method lays the foundation of the theoretical evaluation of energies of charged defects in 2D materials within the first-principles framework. Herein, the vital role of defects for advancing 2D electronics is discussed, followed by an introduction of the fundamentals of the WLZ extrapolation method. The ionization energies (IEs) obtained by this method for defects in various 2D semiconductors are then reviewed and summarized. Finally, the unique defect physics in 2D dimensions including the dielectric environment effects, defect ionization process, and carrier transport mechanism captured with the WLZ extrapolation method are presented. As an efficient and reasonable evaluation of charged defects in 2D materials for nanoelectronics and other emerging applications, this work can be of benefit to the community.  相似文献   
25.
Chen  Wei  Han  Qi  Liu  Jingbo 《Aequationes Mathematicae》2019,93(2):425-432
Aequationes mathematicae - We discuss equivalence conditions for the non-existence of non-trivial meromorphic solutions to the Fermat Diophantine equation $$f^m(z)+g^n(z)=1$$ with integers $$m,n\ge...  相似文献   
26.
27.
28.
A photo-switchable hetero-complementary quadruple H-bonding array, which consists of an azobenzene-derived ureidopyrimidinone (UPy) module ( Azo-UPy ) and a nonphotoactive diamidonaphthyridine (DAN) derivative ( Napy-1 ), is constructed based on a reversible photo-locking approach. Upon UV (390 nm)/Vis (460 nm) light irradiations, photo-switchable quadruple H-bonded dimerization between Azo-UPy and Napy-1 can be achieved with exhibiting 4.8×104-fold differences in binding strength (ON/OFF ratios). Furthermore, smart polymeric gels with unique photo-controlled macroscopic self-assembly behavior can be fabricated by introducing such quadruple H-bonding array as photo-regulable noncovalent interfacial connections.  相似文献   
29.
30.
The modulation of electron density is an effective option for efficient alternative electrocatalysts. Here, p‐n junctions are constructed in 3D free‐standing FeNi‐LDH/CoP/carbon cloth (CC) electrode (LDH=layered double hydroxide). The positively charged FeNi‐LDH in the space‐charge region can significantly boost oxygen evolution reaction. Therefore, the j at 1.485 V (vs. RHE) of FeNi‐LDH/CoP/CC achieves ca. 10‐fold and ca. 100‐fold increases compared to those of FeNi‐LDH/CC and CoP/CC, respectively. Density functional theory calculation reveals OH? has a stronger trend to adsorb on the surface of FeNi‐LDH side in the p‐n junction compared to individual FeNi‐LDH further verifying the synergistic effect in the p‐n junction. Additionally, it represents excellent activity toward water splitting. The utilization of heterojunctions would open up an entirely new possibility to purposefully regulate the electronic structure of active sites and promote their catalytic activities.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号