全文获取类型
收费全文 | 16401篇 |
免费 | 3169篇 |
国内免费 | 2063篇 |
专业分类
化学 | 12153篇 |
晶体学 | 232篇 |
力学 | 917篇 |
综合类 | 133篇 |
数学 | 1737篇 |
物理学 | 6461篇 |
出版年
2024年 | 76篇 |
2023年 | 463篇 |
2022年 | 757篇 |
2021年 | 857篇 |
2020年 | 890篇 |
2019年 | 840篇 |
2018年 | 689篇 |
2017年 | 647篇 |
2016年 | 899篇 |
2015年 | 1000篇 |
2014年 | 1105篇 |
2013年 | 1308篇 |
2012年 | 1603篇 |
2011年 | 1576篇 |
2010年 | 1052篇 |
2009年 | 1087篇 |
2008年 | 1117篇 |
2007年 | 959篇 |
2006年 | 844篇 |
2005年 | 690篇 |
2004年 | 497篇 |
2003年 | 392篇 |
2002年 | 361篇 |
2001年 | 263篇 |
2000年 | 236篇 |
1999年 | 225篇 |
1998年 | 188篇 |
1997年 | 159篇 |
1996年 | 145篇 |
1995年 | 115篇 |
1994年 | 98篇 |
1993年 | 89篇 |
1992年 | 91篇 |
1991年 | 55篇 |
1990年 | 46篇 |
1989年 | 47篇 |
1988年 | 32篇 |
1987年 | 28篇 |
1986年 | 27篇 |
1985年 | 26篇 |
1984年 | 15篇 |
1983年 | 6篇 |
1982年 | 8篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 3篇 |
1976年 | 2篇 |
1971年 | 2篇 |
1966年 | 2篇 |
1957年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
62.
Hu H Qiao M Xie F Fan K Lei H Tan D Bao X Lin H Zong B Zhang X 《The journal of physical chemistry. B》2005,109(11):5186-5192
The desulfurization of thiophene on Raney Ni and rapidly quenched skeletal Ni (RQ Ni) has been studied in ultrahigh vacuum (UHV) by X-ray photoelectron spectroscopy (XPS). The Raney Ni or RQ Ni can be approximated as a hydrogen-preadsorbed polycrystalline Ni-alumina composite. It is found that thiophene molecularly adsorbs on Raney Ni or RQ Ni at 103 K. At 173 K, thiophene on alumina is desorbed, while thiophene in direct contact with the metallic Ni in Raney Ni undergoes C-S bond scission, leading to carbonaceous species most probably in the metallocycle-like configuration and atomic sulfur. On RQ Ni, the temperature for thiophene dissociation is about 100 K higher than that on Raney Ni. The lower reactivity of RQ Ni toward thiophene is tentatively attributed to lattice expansion of Ni crystallites in RQ Ni due to rapid quenching. The existence of alumina and hydrogen may block the further cracking of the metallocycle-like species on Raney Ni and RQ Ni at higher temperatures, which has been the dominant reaction pathway on Ni single crystals. By 473 K, the C 1s peak has disappeared, leaving nickel sulfide on the surface. 相似文献
63.
The anodic polymerization of 3-aminophthalhydrazide (luminol) and iron(II) tris 5-aminophenanthroline (Fe(phen-NH2)3(2+)) has been reported in this paper. A bilayer electrode was developed based on these polymers and the ITO conductive glass (denoted ITO[Fe(phen-NH2)3(2+)]luminol electrode). This electrode emitted light (lambdaem: 430 nm) as it was brought into contact with H2O2. At pH 10, the resulting electrochemiluminescence (ECL) showed a linear relationship with the concentration of H2O2 in the range of 10 microM(-1) mM. This bilayer electrode also showed an application potential for the detection of glucose after being further modified with glucose oxidase (denoted ITO[Fe(phen-NH2)3(2+)]luminol]GOx electrode). Although the resulting ECL decayed more rapidly in concentrated glucose solutions (e.g., I M) because of the consumption of luminol during use, the decay became less severe in diluted glucose solutions (e.g., 10 mM). According to the flow injection analysis, a linear relationship existed between the ECL and the concentration of glucose from 10(-5)-10(-3) M at pH 9. The detection limit could reach a level of 5 x 10(-5) M at this pH. 相似文献
64.
ZHU Jun ZHANG Yun CHEN Hao CHE Yun-Xia ZHENG Ji-Min ② 《结构化学》2006,25(8):1011-1013
1 INTRODUCTION Nonlinear optics (NLO) is at the forefront of cur- rent researches because of its importance in provi- ding the key functions of frequency shifting, optical modulation, optical switching, optical logic and op- tical memory for the emerging … 相似文献
65.
Yong Li Xiao-Bing Cui Ji-Qing Xu Ke-Chang Li Guang-Hua Li Qing-Xin Yang 《Journal of solid state chemistry》2005,178(1):363-369
Both the homometal cluster [P(ph4)]2[Mo2O2(μ-S)2(S2)2] (1) and [Mo2O2(μ-S)2(Et2dtc)2] (2) (Et2dtc=diethyl-dithiocarbamate) were successfully synthesized by low-temperature solid-state reactions. X-ray single-crystal diffraction studies suggest that compound (1) is a dinuclear anion cluster, and compound (2) is a dinuclear neutral cluster. The two compounds were characterized by elemental analyses, IR spectra and UV-Vis spectra. The third-order non-linear optical (NLO) properties of the clusters were also investigated and all exhibited nice non-linear absorption and self-defocusing performance with moduli of the hyperpolarizabilities 5.145×10−30 esu for (1) and 5.428×10−30 esu for (2). 相似文献
66.
67.
钇对Ti-1100高温钛合金热稳定性和蠕变行为的影响 总被引:3,自引:1,他引:3
量了Ti1100和Ti1100/01%Y(质量分数)高温钛合金在600℃/100h空气中暴露后的拉伸性能及在600℃/150MPa/100h条件下的蠕变性能,利用透射电镜观察了合金室温及蠕变后的组织。结果表明,Ti1100合金加入01%的Y后,由于原始β晶粒得到细化,明显改善了其热稳定性;固溶在基体中的硅原子阻碍位错滑移和攀移,使蠕变中的回复过程难于实现;稀土还抑制α2相的长大,所形成的氧化物也阻碍位错的运动。这些均有利于提高Ti1100合金的抗蠕变性能。 相似文献
68.
69.
70.
Determination of tripolyphosphate in frozen cod and scallop adductor by ion chromatography 总被引:4,自引:0,他引:4
We introduce a method for the determination of tripolyphosphate in frozen cod and scallop adductor by using ion chromatography. The tripolyphosphate was extracted from minced cod and scallop adductor with deionized water by ultrasonic leaching, and then the proteins soluble in water were precipitated with trichloroacetic acid and removed by filtering. An ion chromatograph with an ionpac AS11-HC anion-exchange column, an ASRS (Anion Self Regenerating Suppression), a conductivity detector and a gradient pump (sodium hydroxide gradient) was used. The detection limit was below 5 mg tripolyphosphate/kg cod or scallop adductor. This method is applicable to the determination of polyphosphates in aquatic products and the procedures are easy to implement. 相似文献