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991.
以MCl2和配体L(L=1,10-菲罗啉-5,6-二酮)为原料,合成了标题配合物MLCl2,M=NiⅡ,CuⅡ,ZnⅡ,并经元素分析、热谱、IR和摩尔电导表征.三者均为四配位的电中性配合物,热稳定性高于500K,易溶于DMF、DMSO和吡啶,可溶于乙腈和水.它们在DMF中于350nm和315nm附近显示出强的M-L荷移跃迁 相似文献
992.
标题化合物二乙胺合三(5-甲基-2-苯并噻唑基)硼烷(C28H29BN4S3(Mr=527.57)的晶体属于三斜晶系,空间群为P1,晶胞参数a=0.397(8)nm,b=1.1742(6)nm,c=1.3100(2)nm,α=104.29(2)°,β=92.99(3)°,γ=98.58(5)°,V=1.3790nm3,Z=2,Dc=1.270g/cm3,μ(MoKα)=2.804cm-1.结构的偏离因子R=0.0648,Rw=0.0737.结构测定表明,甲基取代基的电子效应导致硼碳键键长的平均化,预示杂环对硼原子的π-电子反馈与胺基氮原子对硼原子的反馈有彼消此长的关系. 相似文献
993.
Let X(t) be an N parameter generalized Lévy sheet taking values in ℝd with a lower index α, ℜ = {(s, t] = ∏
i=1
N
(s
i, t
i], s
i < t
i}, E(x, Q) = {t ∈ Q: X(t) = x}, Q ∈ ℜ be the level set of X at x and X(Q) = {x: ∃t ∈ Q such that X(t) = x} be the image of X on Q. In this paper, the problems of the existence and increment size of the local times for X(t) are studied. In addition, the Hausdorff dimension of E(x, Q) and the upper bound of a uniform dimension for X(Q) are also established. 相似文献
994.
Arrays of NiO nanoparticles have been synthesized via thermal decomposition of nickel dimethylglyoximate precursor. The structure, morphology and properties of the products were characterized by XRD, TEM, SAED and UV-vis spectrophotometry. TEM reveals that one-dimensional arrays consist of NiO nanoparticles. XRD and SAED indicate that these NiO nanoparticles crystallize with a polycrystalline structure. The optical absorption band gap of NiO nanoparticles is 3.51 eV. 相似文献
995.
In this paper, we investigate strict stability of differential systems by variational Lyapunov function. We obtain some sufficient conditions and comparison theorems. 相似文献
996.
997.
框式约束凸二次规划问题的内点算法 总被引:4,自引:0,他引:4
张艺 《高等学校计算数学学报》2002,24(2):163-168
In this paper,a primal-dual interior point algorithm for convex quadratic progromming problem with box constrains is presented.It can be started at any primal-dual interior feasible point.If the initial point is close to the central path,it becomes a central path-following alogorithm and requires a total of O(√nL)number of iterations,where L is the input length. 相似文献
998.
999.
Zhishen Mo Lixiao Wang Hongfang Zhang Ping Han Baotong Huang 《Journal of Polymer Science.Polymer Physics》1987,25(9):1829-1837
Wide-angle X-ray scattering from presumed block copolymers of polypropylene (PP) and ethylene-propylene copolymer (EPR), i.e., PP-EPR and PP-EPR-PP, synthesized by sequential polymerization with δ-TiCl3? Et2AlCl, was examined and compared with WAXS of mechanical blends and chain-transfer mixtures of PP and EPR with comparable compositions. The peak at 2θ = 20° for both the copolymers and the mixtures was attributed to the γ modification of PP in EPR. A strong variation in the ratio of diffraction intensities I040/I110 of PP in block copolymers and mixtures was explained in terms of crystallite growth in different directions. Analysis of the patterns and calculation of crystallinity, crystallite size, and lattice parameters led to the conclusion that block structure existed in the prepared copolymers. 相似文献
1000.
Spatio temporal dynamics of the positive column of a dc neon glow discharge is studied and investigated experimentally and theoretically. Spatio temporal analysis by means of biorthogonal decomposition method (BOD) gives insights into the mechanism of irregularity and can be employed for characterization of spatio‐ temporal complexity. In the weak nonlinear region, the wave dynamics is approximated by an amplitude equation of the Ginzburg‐Landau equation (CGLE) with complex coefficients and an additional integral term based on a fluid model. In the present work we deal with irregular spatio‐temporal data. A comparison between the numerical analysis of the experimental data and simulation results are studied. A good agreement between the dynamical behaviour for experimental space‐time data and theoretical simulation space‐time results was obtained. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献