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引言我们曾研究了金属镍,铜,钛,钨,铝,铁,银,铂,钼等和非金属硅与石墨及ⅢA—VA与ⅡB—ⅥA化合物晶体等的弛豫、重构和吸附表而的60多个表面结构。本文报道研究Ag(100)c(2×2)—C1表面的结果。Zanazzi和Jona观测了Ag(100)c(2×2)—C1表面结构的21束LEED谱,并采用层—KKR(Korring—Kohn—Rostocker)法,对清洁的Ag(100)表面吸附C1原子时假设了4种结构模型。经理论计算与观测值的比较,提出了C1原子的单层吸附和C1原子与Ag原子 相似文献
253.
Mixed-metal molybdenum(II)/rhodium(II) tetra(trifluoroacetate) of the composition [(MoRh)(O2CCF3)4] has been obtained from the gas-phase reaction between volatile carboxylates, [Mo2(O2CCF3)4] and [Rh2(O2CCF3)4]. This is an interesting system for which a single-crystal X-ray investigation fails to provide an unambiguous evidence of whether the product consists of the initial homometallic or newly formed heterometallic paddlewheel units. In the solid-state structure both metal atoms occupy the same crystallographic position, while the M-M and M-O distances are averaged with respect to the parent homometallic compounds. Nevertheless, the results of mass-spectrometric and magnetic measurements clearly indicate that the title bimetallic carboxylate contains a statistical mixture of homometallic dimolybdenum and dirhodium units. The product can be considered as a result of cocrystallization of isomorphous paddlewheel molecules. 相似文献
254.
Guo-Gui Liu Hua Zhao Yu-Bao Lan Bin Wu Xiao-Fei Huang Jian Chen Jing-Chao Tao Xing-Wang Wang 《Tetrahedron》2012,68(20):3843-3850
The asymmetric cross-aldol reaction of isatins with α,β-unsaturated ketones has been developed under catalysis by a Cinchona alkaloid-derivated bifunctional Brønsted acid–Brønsted base catalyst, affording the aldol adducts in moderate to good yields (18–98%) with moderate to good enantioselectivities (30–97%). The noncovalent organo-catalyzed asymmetric cross-aldol reaction displays a broad substrate scope and wide functional-group tolerability, albeit the electronic and steric properties of both reaction partners have considerable and regular effects on the reactivity and stereocontrol. 相似文献
255.
The direct Pd-catalyzed β-C(sp3) H activation and cyclization of aliphatic amides bearing a removable 2-pyridylmethyl directing group with gem-dibromoolefins is described for the first time to construct a variety of γ-lactams. 相似文献
256.
Chaojun Deng Haoyuan Wang Hongqiang Lan Boya Xu 《Journal of Dispersion Science and Technology》2018,39(11):1582-1587
The flow behavior in a three-phase separator with a bucket and weir was analyzed, and a theoretical equation for calculating the liquid-liquid interface level (HH) in gravity separation zone was derived. The analysis indicates that the HH increases as the flow rate and the density ratio of heavy to light liquid increase, and decreases linearly with increasing height difference between heavy and light liquid overflow weirs. The calculated HH under different operating conditions is in good agreement with the experimental. With the proposed equation, the thicknesses of heavy and light liquid layers can be calculated, and then the minimum lengths of two phase layers required for separation can be determined separately. From the minimum lengths it can be clearly indicated that the governing step of liquid-liquid separation is in heavy or light liquid layers, hence the sizing of the separator can be optimized. 相似文献
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Commensurate adsorption occurs when the number of molecules adsorbed per unit cell relates to the symmetry of the framework and its topology. While rare in zeolite materials, commensurate adsorption has been observed in several MOF materials. In some MOF materials, several molecules having dimensions within a limited size range show this effect. This paper describes the commensurate adsorption properties of three MOF materials and also two MOFs showing unusual combined structure-composition adsorption features. 相似文献
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