Manipulation of a single charge in a double quantum dot

We manipulate a single electron in a fully tunable double quantum dot using microwave excitation. Under resonant conditions, microwaves drive transitions between the (1,0) and (0,1) charge states of the double dot. Local quantum point contact charge detectors enable a direct measurement of the photon-induced change in occupancy of the charge states. From charge sensing measurements, we find T1 approximately 16 ns and a lower bound estimate for T*(2) of 400 ps for the charge two-level system.     

Measurement efficiency and n-shot readout of spin qubits

We consider electron spin qubits in quantum dots and define a measurement efficiency e to characterize reliable measurements via n-shot readouts. We propose various implementations based on a double dot and a quantum point contact (QPC) and show that the associated efficiencies e vary between 50% and 100%, allowing single-shot readout in the latter case. We model the readout microscopically and derive its time dynamics in terms of a generalized master equation, calculate the QPC current, and show that it allows spin readout under realistic conditions.     

Reversible repositioning of zinc atoms within single crystals of a zinc polycarboxylate with an open-framework structure

Upon dehydration at 220 degrees C under vacuum, an open-framework zinc tetrahydrofuran-2,3,4,5-tetracarboxylate undergoes reversible single crystal to single crystal conversion by some of the zinc atoms moving to different positions that are 3 A away. The reverse process occurs at room temperature by exposing dehydrated crystals to air.     

Neighbouring group participation in the allylic oxidation of a Δ5-steroid

The allylic oxidation of 3β-acetoxyandrost-5-en-17-one by bromine and silver acetate affords 4β-acetoxy-3β-hydroxyandrost-5-en-17-one rather than the 3β,4β-diacetate. Labelling studies show that this involves the migration of the 3β-acetoxyl group and an overall retention of configuration at C-4.     

Disproportionation of cyclohexadiene by Co(II) and Ni(II) based homogeneous ziegler catalysts

Homogeneous Ziegler catalysts prepared from Co(II) or Ni(II) alkanoates and aluminium alkyls are highly active for the disproportionation of 1,3- and 1,4-cyclohexadiene to benzene and cyclohexene.     

Noise control for rapid transit cars on elevated structures

Noise control treatments for the propulsion motor noise of rapid transit cars on concrete elevated structures and the noise reduction from barrier walls were investigated by using acoustical scale models and supplemented by field measurements of noise from trains operated by the Port Authority Transportation Corporation (PATCO) in New Jersey. The results show that vehicle skirts and undercar sound absorption can provide substantial cost-effective reductions in propulsion noise at the wayside of transit systems with concrete elevated guideways. The acoustical scale model noise reductions applied to PATCO vehicles on concrete elevated structures show reductions in the A-weighted noise levels of 5 dB for undercar sound absorption, 5 dB for vehicle skirts, and 10 dB for combined undercar absorption and vehicle skirts. Acoustical scale model results for sound barrier walls lined with absorptive treatment showed reductions from 7 dB to 12 dB of noise from vehicles in the far track, depending on the height of the wall, and reductions from 12 dB to 20 dB of noise from vehicles on the near track. Transit vehicles at high speeds where propulsion system noise dominates are 7 dB(A) noisier at 50 ft on concrete elevated structures than on at-grade on tie and ballast. Of this amount, 3 dB is due to loss of ground effect, and 4 dB is due to the absence of undercar absorption provided by ballast.     

Polymer coatings as stationary phases in high-performance liquid chromatography

Modern biochromatography demands highly sophisticated packing materials in terms of biocompatibility, (substrate-) selectivity and recovery. Polymers can be designed in a wide variety and therefore deliver solutions to specific chromatographic problems. Thus, tailor-made polymer coatings are an alternative to the classical chemically bonded stationary phases.