chemie und ortografie

The German-speaking countries decided last year to reform their spelling in an extremely restrictive manner, resulting in nearly invisible changes in daily writing. German chemists have actively promoted new orthography rules. R. Pauli, in 1904, edited a journal with a progressive writing, far ahead of the recently adopted new spelling rules.     

Calculations of electromagnetic nucleon form factors and electroexcitation amplitudes of isobars

In this paper, we present numerical results for electroproduction amplitudes of proton resonances and electromagnetic nucleon form factors calculated in a relativized quark model. Interactions with both transversely and longitudinally polarized virtual photons were considered. Contributions of the different effects included in our approach have been analysed through a sample comparison with the available data. We also discuss the validity of the usual single-quark transition ansatz and possible parametrizations of the potential acting between the constituent quarks of the baryon. Impressive agreement is obtained with the nucleon form factor data up to squared momentum transfers of 2.5 GeV², but still some problems remain with the Δ(1232) and higher resonances.     

Unitarity bounds for 4-fermion contact interactions

In this paper we consider the effect of unitarity bounds s_bs(E₁+E₂) _cms ² for the recently proposed types of nonderivative 4-fermion contact interactions. To this purpose we decompose the helicity amplitudes at c.m.s. into partial waves. The bounds are defined to hold for all reaction channels due to the same type of contact interaction. We find s_b=4/. Here is the coupling constant. The factor depends on the type of coupling and on the different cases to identify the fermions. It ranges from 1/3 to 4.     

Novel cationic carotenoid lipids as delivery vectors of antisense oligonucleotides for exon skipping in Duchenne muscular dystrophy

Duchenne Muscular Dystrophy (DMD) is a common, inherited, incurable, fatal muscle wasting disease caused by deletions that disrupt the reading frame of the DMD gene such that no functional dystrophin protein is produced. Antisense oligonucleotide (AO)-directed exon skipping restores the reading frame of the DMD gene, and truncated, yet functional dystrophin protein is expressed. The aim of this study was to assess the efficiency of two novel rigid, cationic carotenoid lipids, C30-20 and C20-20, in the delivery of a phosphorodiamidate morpholino (PMO) AO, specifically designed for the targeted skipping of exon 45 of DMD mRNA in normal human skeletal muscle primary cells (hSkMCs). The cationic carotenoid lipid/PMO-AO lipoplexes yielded significant exon 45 skipping relative to a known commercial lipid, 1,2-dimyristoyl-sn-glycero-3-ethylphosphocholine (EPC).     

A relativized quark model for radiative baryon transitions

In this paper we investigate the electromagnetic form factors of baryons and their resonances using the framework of a relativized constituent quark model. Beyond the usual single-quark transition ansatz, we incorporate relativistic corrections which are welldetermined by the intrinsic interaction and confinement forces between the quarks. Furthermore we separate off for the compound three-quark system the relativistic center-of-mass motion by an approximately Lorentz-invariant approach. In this way for the first time recoil effects could be explicity studied. Using the harmonic oscillator wavefunctions with the configuration mixing as derived in the Isgur-Karl model, after restoring gauge invariance our relativized interaction hamiltonian can be used to calculate the transversely and longitudinally polarized photon transition form factors of the baryons.     

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Pyrolysis craters produced by laser pulse irradiation on propellant solids

The appearance of craters is discussed, which are observed at the surface of propellant solids after laser pulse heating. The discussion is based on the three-dimensional heat flow equation and an infinitesimal short heat source. The experimental crater dimensions are correlated with the laser pulseenergy and the pyrolysis temperature of the solids.