全文获取类型
收费全文 | 694篇 |
免费 | 0篇 |
国内免费 | 2篇 |
专业分类
化学 | 621篇 |
晶体学 | 1篇 |
力学 | 1篇 |
数学 | 42篇 |
物理学 | 31篇 |
出版年
2023年 | 6篇 |
2021年 | 13篇 |
2020年 | 13篇 |
2019年 | 8篇 |
2016年 | 4篇 |
2014年 | 5篇 |
2013年 | 15篇 |
2012年 | 16篇 |
2011年 | 13篇 |
2010年 | 7篇 |
2009年 | 3篇 |
2008年 | 14篇 |
2007年 | 9篇 |
2006年 | 14篇 |
2005年 | 22篇 |
2004年 | 14篇 |
2003年 | 14篇 |
2002年 | 10篇 |
2001年 | 5篇 |
2000年 | 5篇 |
1999年 | 14篇 |
1998年 | 13篇 |
1997年 | 11篇 |
1996年 | 28篇 |
1995年 | 22篇 |
1994年 | 16篇 |
1993年 | 19篇 |
1992年 | 21篇 |
1991年 | 20篇 |
1990年 | 27篇 |
1989年 | 20篇 |
1988年 | 20篇 |
1987年 | 19篇 |
1986年 | 28篇 |
1985年 | 23篇 |
1984年 | 25篇 |
1983年 | 23篇 |
1982年 | 20篇 |
1981年 | 16篇 |
1980年 | 11篇 |
1979年 | 9篇 |
1978年 | 8篇 |
1977年 | 6篇 |
1976年 | 10篇 |
1975年 | 11篇 |
1974年 | 6篇 |
1973年 | 6篇 |
1972年 | 5篇 |
1971年 | 7篇 |
1970年 | 3篇 |
排序方式: 共有696条查询结果,搜索用时 0 毫秒
691.
Formation of Organosilicon Compounds. 95. Crystal Structure of a Hexadecamethyloctasila-dispiro [5.1.5.1]tetradecane, Si8C22H56 1,1,3,3,5,5,7,7,9,9,11,11,13,13,14,14-Hexadecamethyl-1,3,5,7,9,11,13,14-octasila-dispiro[5.1.5.1]tetradecane crystallizes monoclinically in the space group P21/n (No. 14) with a = 1352.4 pm, b = 1215.5 pm, c = 1001.2 pm, β = 92.11° and Z = 2 molecules per unit cell. The dispiro system is formed by a central disilacyclobutane and two C-spiro connected trisilacyclohexane rings. The symmetry of the molecule is 2/m, with flattened six membered rings in chair conformation. The Si? C bonds are enlarged (192 pm) at the strained spiro region whereas the Si? C bonds are distinctly shortened (186 pm) at the opposite Si atoms in the six membered rings. 相似文献
692.
Wiesaw Wojnowski Maria Wojnowski Hans Georg von Schnering Mathias Noltemeyer 《无机化学与普通化学杂志》1985,531(12):153-157
Contributions to the Chemistry of Silicon-Sulfur Compounds. XXXVI. Mercury(II)-bis-tri-tert-butoxysilanethiolate Mercury(II)bis-tri-tert-butoxysilanethiolate was obtained in reaction of HgO with (t-C4H9O)3SiSH. This compound forms colourless triclinic plates. The central S? Hg? S bond element is linear, with Hg? S bond distance of 231.6 pm. The Hg atom is coordinated by two oxygens of the two butoxy groups, with Hg? O distance of 287.8 pm. The mean bond angle at the two-bonded sulfur is 95.6°. (Space group P1 ; a = 930.8, b = 944.0, c = 1204.8 pm, α = 100.34, β = 97,64, γ = 116.50°; Z = 1; R = 0.035; 3390 reflections hkl). 相似文献
693.
TiOBr was prepared by reaction of Ti with TiO2 and Br2. The compound forms fiat reddish-brown needles and shows a temperature independent weak paramagnetism. It crystallises in the orthorhombic system (Pmmn; a = 3.787, b = 3.487, c = 8.529 Å) with the FeOCl type of structure. The interatomic distances are Ti?O = 1.952; 2.245 Å (2X) and Ti?Br = 2.544 Å (2X). 相似文献
694.
695.
A robust method for routine quality control of corky off-flavour compounds in wine and cork soak matrices has been established. Based on an automated headspace solid phase microextraction (HS-SPME), the method needs only marginal sample preparation and achieves low (sub-ng L−1) trace level detection limits (LODs) for the most relevant off-flavour compounds, such as 2,4,6-trichloroanisole (TCA), 2,3,4,6-tetrachloroanisole (TeCA) and 2,4,6-tribromoanisole (TBA). Particularly for wine matrix, reliable trace level quantification had only been achieved after applying heart-cutting multidimensional gas chromatography (MDGC). Using a halogen-sensitive electron capture detector (ECD) and quantification with a stable isotope dilution assay (SIDA), LODs of 0.1 ng L−1 for TCA, TeCA and TBA could be obtained. Since a SIDA based quantification method is used with a non-mass spectrometric detector, the necessary chromatographic resolution of internal standard and target analyte peaks resulted from the use of highly deuterated [2H5]-isotopologues. 相似文献
696.
The polarized absorption spectra of derivatives of 3,4,9-perylenetricarboxylic acid and of 3,4,9,10-perylenetetracarboxylic acid dissolved in the nematic liquid crystal mixture ZLI 1695 have been recorded as a function of temperature. On the basis of these spectra, the directions of the absorption transition moments with respect to the principle axes of the order tensor, and the order parameters S * and D * for perylene derivatives have been determined assuming a C s or C 2 point symmetry group for the dyes molecules. From a generalized equation describing properties of anisotropic phases, the conditions necessary to determine a complete set of the order parameters and the pieces of possible information that can be obtained from the polarized optical spectroscopy are discussed. 相似文献