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991.
992.
Hans J. Queisser 《Annalen der Physik》1990,502(6):461-466
An alternative interpretation is offered to explain a photoconductivity, rising exponentially with time under constant illumination, which has been detected in semiinsulating GaAs. Spatial inhomogeneities, caused by nonuniform defect density, present potential barriers to current flow. Illumination neutralizes the space charge, thus reduces these barriers, hence increases current at constant bias. Local electric fields consequently vary in time, which may establish polarization effects and lifetime discontinuities via exciton dissociation. 相似文献
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Lucas Montero De Espinosa Juan C. Ronda Marina Galià Virginia Cádiz Michael A.R. Meier 《Journal of polymer science. Part A, Polymer chemistry》2009,47(21):5760-5771
The acyclic diene metathesis (ADMET) polymerization of a phosphorus‐containing α,ω‐diene prepared from a plant oil derived building block is reported. Different ruthenium based metathesis catalysts and conditions were tested to optimize the ADMET polymerization of this monomer. Undecylenyl undecenoate was used as fully renewable comonomer to obtain polyesters with different phosphorus contents and to increase the renewable content of the final polymers. Copolymerization caused marked variations in the molecular weights leading to polyesters from 6 to 38 KDa. The effect of the ADMET polymerization temperature in the thermal properties of the copolymers was studied and their thermal degradation and flame retardant properties were evaluated. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 5760–5771, 2009 相似文献
999.
Sebastian Mendrek Aleksandra Mendrek Hans‐Juergen Adler Andrzej Dworak Dirk Kuckling 《Journal of polymer science. Part A, Polymer chemistry》2009,47(7):1782-1794
Block copolymers of poly(glycidol)‐b‐poly(4‐vinylpyridine) were obtained by ATRP of 4‐vinylpyridine initiated by ω‐(2‐chloropropionyl) poly(glycidol) macroinitiators. By changing the monomer/macroinitiator ratio in the synthesis polymers with varied P4VP/PGl molar ratio were obtained. The obtained block copolymers showed pH sensitive solubility. It was found that the linkage of a hydrophilic poly(glycidol) block to a P4VP influenced the pKa value of P4VP. DLS measurements showed the formation of fully collapsed aggregates exceeding pH 4.7. Above this pH values the collapsed P4VP core of the aggregates was stabilized by a surrounding hydrophilic poly(glycidol) corona. The size of the aggregates depended significantly upon the composition of the block copolymers. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 1782–1794, 2009 相似文献
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C. Frick H. Engemann L. Kürthy Hans Müller G. J. Hough Heßling 《Analytical and bioanalytical chemistry》1930,80(9-10):387-391