Optimized analysis of the critical behavior in polymer mixtures from Monte Carlo simulations

A complete outline is given for how to determine the critical properties of polymer mixtures with extrapolation methods similar to the Ferrenberg-Swendsen techniques recently devised for spin systems. By measuring not only averages but the whole distribution of the quantities of interest, it is possible to extrapolate the data obtained in only a few simulations nearT _c over the entire critical region, thereby saving at least 90% of the computer time normally needed to locate susceptibility peaks or cumulant intersections and still getting more precise results. A complete picture of the critical properties of polymer mixtures in the thermodynamic limit is then obtained with finite-size scaling functions. Since the amount of information extracted from a simulation in this way is drastically increased as compared to conventional methods, the investigation of mixtures with long chains or built-in asymmetries is now possible. As an example, the critical points, exponents, and amplitudes of dense, symmetric polymer mixtures with chain lengths ranging fromN=16 up toN=256 are determined within the framework of the 3D bond fluctuation model using grand canonical simulation techniques. As an example for an asymmetry, the generalization of the method to asymmetric monomer potentials is briefly discussed.     

Stabilization of linear systems by rotation

We introduce the concept of “stabilization by rotation” for deterministic linear systems with negative trace. This concept encompasses the well-known concept of “vibrational stabilization” introduced by Meerkov in the 1970s and is a deterministic version of ‘stabilization by noise’ for stochastic systems as introduced by Arnold and coworkers in the 1980s. It is shown that a linear system with negative trace can be stabilized by adding a skew-symmetric matrix, multiplied by a suitable scalar so-called “gain function” (possibly a constant) which is sufficiently large. To overcome the problem of what is “sufficiently large”, we also present a servo mechanism which tunes the gain function by learning from the trajectory until finally the trajectory tends to zero. This approach allows to show that one of Meerkov's assumptions for vibrational stabilization is superfluous. Moreover, while Meerkov as well as Arnold and coworkers assume that a stabilizing periodic function or the noise has sufficiently large frequency and amplitude, we also provide a servo mechanism to determine this function dynamically in a deterministic setup.     

Polygermoxanes suitable for biochemical purposes. Part I. Digermoxanes (low-viscosity oils)

In order to replace silicones in some of their biomedical applications, e.g. syringe lubrication, implants ets., a series of digermoxanes (R¹R²R³Ge)₂O (R = n–alkyl, aryl) were synthesized. These compounds are thermally stable oils; their viscosities, depending on the nature of substituents, lie in the range 1–72 cPo (mPa s) at 20°C.