Spectroscopic study of plasmons in ion-irradiated single-walled carbon nanotubes

The electronic structure of single-walled carbon nanotubes was experimentally investigated using x-ray photoelectron spectroscopy, reflection electron energy-loss spectroscopy, and Auger electron spectroscopy. A shake-up satellite structure observed near the C 1s core-level lines in the x-ray photoelectron spectra at high binding energies in the range 284–330 eV due to excitation of π and π + σ plasmons was studied. The effect of irradiation by 1-keV argon ions on the shape of the spectra was analyzed. The shape of the C 1s satellite spectra was found to be sensitive to Ar⁺ irradiation in the electron energy loss range 10–40 eV corresponding to excitation of π + σ plasmons. Auger spectroscopy revealed the presence of argon on the surface of ion-irradiated samples. The argon content increased to ～4 at. % with increasing irradiation dose. An analysis of the results obtained and their comparison with the data available in the literature led to a qualitative conclusion that the bond angles of the carbon atoms making up the walls of single-walled carbon nanotubes are distorted at sites exposed to Ar⁺ irradiation.     

On the role of mechanical effects during dynamic fatigue of PbTiO3 single crystals

The details of the mechanical effects (twinning and microcracking) are clarified at various stages of dynamic fatigue of PbTiO₃ crystals using a polarization microscope and selective etching.     

Micromagnetic analysis of transition noise for high-density perpendicular recording

In this paper, specific issues related to high-density perpendicular magnetic recording processes, such as transition noise properties and cross-track correlation lengths, were investigated with the help of micromagnetic analysis. The effects of media parameters were taken into consideration, including intergranular exchange coupling, and exchange distribution, irregular grain shapes, magnetization saturation distribution, and anisotropy distribution. The micromagnetic simulation results showed that the effect of anisotropy distribution on transition noise is more significant than magnetization saturation distribution, and it is crucial to reduce this effect to achieve a high signal-to-noise ratio. Additionally, a new method to further estimate the partial erasure threshold was proposed to approximate the partial erasure effects, and the relation between the microtrack jitter and total track jitter was investigated.     

Properties of Josephson junctions in the inhomogeneous magnetic field of a system of ferromagnetic particles

The effect of an array of ferromagnetic nanoparticles on the field-dependent critical current of the short overlap Josephson junction is experimentally studied. Large reversible variations of the maximum critical current are observed depending on the magnetic state of the particles. The pronounced commensurability effects are detected which are proved by the additional peaks of magnetic field induced diffraction pattern.     

Hydrolytic degradation and thermal stability of poly(naphthylimides) based on naphthalene-1,4,5,8-tetracarboxylic dianhydride and bis(naphthalic anhydrides)

The molecular properties of a number of new poly(naphthylimides) derived from naphthalene-1,4,5,8-tetracarboxylic dianhydride and bis(naphthalic anhydrides) have been studied. On the basis of hydrodynamic studies of the polymers at various stages of their thermal degradation in 96% H₂SO₄ and thermogravimetric measurements, the hydrolytic stability and thermooxidative resistance of the polymers have been compared. A correlation between the experimental data and the chemical structure of molecular chains has been established.     

Monotone additive matrix transformations

We investigate additive transformations on the space of real or complex matrices that are monotone with respect to any admissible partial order relation. A complete characterization of these transformations is obtained. In the real case, we show that such transformations are linear and that all nonzero monotone transformations are bijective. As a corollary, we characterize all additive transformations that are monotone with respect to certain classical matrix order relations, in particular, with respect to the Drazin order, left and right *-orders, and the diamond order.     

Studying high-spin ferric heme proteins by pulsed EPR spectroscopy: Analysis of the ferric form of the E7Q mutant of human neuroglobin

In this work, the high-spin ferric form of the E7Q mutant of human neuroglobin (E7Q-NGB) is studied by X-band continuous-wave electron paramagnetic resonance (CW EPR) and hyperfine sublevel correlation (HYSCORE) spectroscopy. It is shown that the use of matched pulses in the HYSCORE experiment is essential to observe the nitrogen spectral contributions. The validity of approximating the high-spin Fe(III) system (S=5/2) as an effectiveS=1/2 system is tested and the consequences for the HYSCORE simulations are highlighted. Comparative HYSCORE experiments combined with deuterium exchange experiments for aquometmyoglobin and ferric E7Q-NGB clearly show that the heme iron of the latter protein is pentacoordinated, lacking the distal water. Furthermore, CW EPR experiments show that, at high pH, the E10K residue is coordinating to the heme iron in this globin. These observations are corroborated by resonance Raman experiments and could also be reproduced for other E7 mutants of human and mouse neuroglobin. Finally, the proton and nitrogen hyperfine and nuclear quadrupole parameters obtained for ferric E7Q-NGB are discussed in detail.     

Binding energy of impurity states in an inverse parabolic quantum well under magnetic field

 We have investigated the effects of the magnetic field which is directed perpendicular to the well on the binding energy of the hydrogenic impurities in an inverse parabolic quantum well (IPQW) with different widths as well as different Al concentrations at the well center. The Al concentration at the barriers was always x_max=0.3. The calculations were performed within the effective mass approximation, using a variational method. We observe that IPQW structure turns into parabolic quantum well with the inversion effect of the magnetic field and donor impurity binding energy in IPQW strongly depends on the magnetic field, Al concentration at the well center and well dimensions.