全文获取类型
收费全文 | 195篇 |
免费 | 14篇 |
专业分类
化学 | 142篇 |
力学 | 8篇 |
数学 | 32篇 |
物理学 | 27篇 |
出版年
2024年 | 1篇 |
2023年 | 1篇 |
2022年 | 6篇 |
2021年 | 6篇 |
2020年 | 3篇 |
2019年 | 4篇 |
2018年 | 5篇 |
2017年 | 4篇 |
2016年 | 14篇 |
2015年 | 5篇 |
2014年 | 14篇 |
2013年 | 19篇 |
2012年 | 18篇 |
2011年 | 10篇 |
2010年 | 12篇 |
2009年 | 5篇 |
2008年 | 11篇 |
2007年 | 10篇 |
2006年 | 10篇 |
2005年 | 4篇 |
2004年 | 6篇 |
2003年 | 4篇 |
2002年 | 4篇 |
2001年 | 4篇 |
1999年 | 3篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1995年 | 1篇 |
1993年 | 3篇 |
1987年 | 6篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有209条查询结果,搜索用时 78 毫秒
51.
Mustafa M. El‐Abadelah Salim S. Sabri Monther A. Khanfar Hani A. Yasin Wolfgang Voelter 《Journal of heterocyclic chemistry》2002,39(5):1055-1059
The synthesis and spectral properties (ir, ms, nmr) of a substituted 2‐methyl‐2H‐pyrazolo[4,3‐d]‐pyrimidin‐7‐one ( 3 ), an isomer of Viagra®, are described. The key synthon, 4‐amino‐1‐methyl‐5‐propyl‐3‐pyrazolecarboxamide ( 7 ), is prepared via the reaction of ethyl 2,4‐dioxoheptanoate with methylhydrazine, followed by cyclization, nitration, amidation, and nitro group reduction. Interaction of 7 with 2‐ethoxyben‐zoyl chloride yielded the respective bis‐amide ( 8 ) which was cyclized in polyphosphoric acid to the corresponding pyrazolo[4,3‐d]pyrimidin‐7‐one derivative 9 . Chlorosulfonylation of 9 , and subsequent treatment with 1‐methylpiperazine furnished iso Viagra ( 3 ). 相似文献
52.
Di--butylketene reacts with alkyllithiums to give enolate intermediates which can be captured by silylation or alkylation. 相似文献
53.
One-way conversion of the racemic (±)-5,6-dicarba-nido-decaborane (12) to its laevorotatory enantiomer by (+)-N-methylcamphidine is reported. 相似文献
54.
Madhuchandra Kenchegowda Mohamed Rahamathulla Umme Hani Mohammed Y. Begum Sagar Guruswamy Riyaz Ali M. Osmani Mysore P. Gowrav Sultan Alshehri Mohammed M. Ghoneim Areej Alshlowi Devegowda V. Gowda 《Molecules (Basel, Switzerland)》2022,27(1)
Cancer is a group of disorders characterized by uncontrolled cell growth that affects around 11 million people each year globally. Nanocarrier-based systems are extensively used in cancer imaging, diagnostics as well as therapeutics; owing to their promising features and potential to augment therapeutic efficacy. The focal point of research remains to develop new-fangled smart nanocarriers that can selectively respond to cancer-specific conditions and deliver medications to target cells efficiently. Nanocarriers deliver loaded therapeutic cargos to the tumour site either in a passive or active mode, with the least drug elimination from the drug delivery systems. This review chiefly focuses on current advances allied to smart nanocarriers such as dendrimers, liposomes, mesoporous silica nanoparticles, quantum dots, micelles, superparamagnetic iron-oxide nanoparticles, gold nanoparticles and carbon nanotubes, to list a few. Exhaustive discussion on crucial topics like drug targeting, surface decorated smart-nanocarriers and stimuli-responsive cancer nanotherapeutics responding to temperature, enzyme, pH and redox stimuli have been covered. 相似文献
55.
A new τ_method is presented for the two dimensional linear boundary value problems. Theoretical and numerical analyses are presented. These results indicate that our method works nicely and efficiently. 相似文献
56.
57.
Room temperature deformable shape memory composite with fine‐tuned crystallization induced via nanoclay particles
下载免费PDF全文
![点击此处可从《Journal of Polymer Science.Polymer Physics》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Yu‐Chen Sun Shenyang Cai Jie Ren Hani E. Naguib 《Journal of Polymer Science.Polymer Physics》2017,55(16):1197-1206
It is known that particular types of semi‐crystalline/elastomer polymer blends exhibit shape memory effects (SME) due to the dispersion of two immiscible phases. In this study, the crystal structure of polylactic acid (PLA)/ thermoplastic polyurethane (TPU) based shape memory polymer (SMP) is altered by incorporating small amounts of montmorillonite (MMT) nanoclay. The results indicate the incorporation of MMT can improve the compatibility of the two different polymers. Moreover, the presence of MMT affects the total crystallinity of the SMP and improves mechanical properties. Lastly, uniaxial stretching deformation can be applied to the SMP at room temperature conditions while maintaining its shape memory properties. With 1 wt % MMT particles, the recovery ratio (Rr) was nearly 95%, which indicated a strong recovery effect. The shape‐fixing ratio (Rf) remained above 95% for all composites due to plastic deformation applied at room temperature. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 1197–1206 相似文献
58.
59.
60.
Design of thermal hybrid composites based on liquid crystal polymer and hexagonal boron nitride fiber network in polylactide matrix
下载免费PDF全文
![点击此处可从《Journal of Polymer Science.Polymer Physics》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Shahriar Ghaffari Mosanenzadeh Min Wen Liu Hugo G. Palhares Hani E. Naguib 《Journal of Polymer Science.Polymer Physics》2016,54(4):457-464
Development of high thermally conductive and electrically insulative composites is of interest for electronic packaging industry. Advancements in smaller and more compact electronic devices required improvements in packing materials, including their weight, thermal conductivity, and electrical resistivity. In addition, with the increasing environmental awareness, the usage of green (bio‐based) alternatives was equally important. In the present study a hybrid based on fibers of highly concentrated hexagonal boron nitride (hBN) in liquid crystal polymer (LCP) matrix were fabricated. These hybrids were formed by arranging hBN platelets into LCP fiber form to reach high filler concentration and then randomly mix it in polylactide (PLA) matrix. With appropriate filler interaction within the hybrid, thermal conductivity similar to that of pure fiber could be achieved. Filler interaction may be tailored by optimizing the fibers aspect ratio. This study demonstrated the effect of random fillers in fibers shape in increasing the overall thermal conductivity of PLA polymeric hybrid using hBN and LCP fibers. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 457–464 相似文献