含羧酸配体的鼓形有机锡氧簇合物：六聚苯基锡氧3-吲哚丁酸酯的合成及晶体结构

利用Ph3SnOH和3-吲哚丁酸以1：1摩尔比反应，合成了新型含羧酸配体的鼓形 有机锡氧簇合物：六聚苯基锡氧3-吲哚西酸酯。通过元素分析、红外光谱和X射线 单晶衍射对其结构进行了表征。测试结果表明：该化合物为三斜晶系，空间群P1， a=1.1722(6),b=1.5694（8）nm，c=1.7227(9)nm，α=116.251（8）°，β=100. 854（10）°，γ=95.606（9）°，Z=1，V=2.732(3)nm^3，Dc=1.554g·cm^-3，μ =1.420mm^-1，F(000)=1276，R=0.0630，ωR=0.0762。晶体结构中，六配位的锡原 子呈畸变的八面体构型。     

乙醇对超临界CO2中乙酰乙酸乙酯异构化平衡的影响

超临界流体（SCF）是物质所处的温度和压力同时高于其临界值时的流体．在超临界体系中存在特殊的分子间相互作用，从而使其具有诸如高压缩性、高扩散系数、强溶剂化力等许多独特的性质.在超临界流体研究领域引起人们普遍关注的问题之一是共溶剂效应（cosolventeffect），即在超     

Determination of Biodegradation Process of Benzene, Toluene, Ethylbenzene and Xylenes in Seabed Sediment by Purge and Trap Gas Chromatography

Benzene, toluene, ethylbenzene, and xylenes (BTEX) are commonly found in crude oil and are used in geochemical investigations as direct indicators of the presence of oil and gas. BTEX are easily volatile and can be degraded by microorganisms, which affect their precise measurement seriously. A method for determining the biodegradation process of BTEX in seabed sediment using dynamic headspace (purge and trap) gas chromatography with a photoionization detector (PID) was developed, which had a detection limit of 7.3–13.2 ng L^?1 and a recovery rate of 91.6–95.0%. The decrease in the concentration of BTEX components was monitored in seabed sediment samples, which was caused by microorganism biodegradation. The results of BTEX biodegradation process were of great significance in the collection, transportation, preservation, and measurement of seabed sediment samples in the geochemical investigations of oil and gas.     

The finite steps of convergence of the fast thresholding algorithms with f-feedbacks in compressed sensing

Numerical Algorithms - Iterative algorithms based on thresholding, feedback, and null space tuning (NST+HT+FB) for sparse signal recovery are exceedingly effective and efficient, particularly for...     

Rearrangement Free Method for Hardy-Littlewood-Sobolev Inequalities on $\mathbb{S}^n$

For conformal Hardy-Littlewood-Sobolev(HLS) inequalities [22] and reversed conformal HLS inequalities [8] on $\mathbb{S}^n,$ a new proof is given for the attainability of their sharp constants. Classical methods used in [22] and [8] depends on rearrangement inequalities. Here, we use the subcritical approach to construct the extremal sequence and circumvent the blow-up phenomenon by renormalization method. The merit of the method is that it does not rely on rearrangement inequalities.     

Weighted composition operators on the Fock space

In this paper,we study weighted composition operators on theFock space F².We prove that each bounded composition operator on F² is complex symmetric.This is in sharp contrast with the phenomenon on the Hardy space H²(D).We characterize Hermitian weighted composition operators and algebraic weighted composition operators with degree less than or equal to two on F².In addition,we investigate cyclicity and hypercyclicity of complex symmetric weighted composition operators.We also characterize those weighted compositionoperators that preserveframes,tight frames or normalized tight frames on F².Finally,we study mean ergodicity and uniformly mean ergodicity of weighted composition operators.