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291.
Gulzar Bhat Akbar Masood Bashir A. Ganai Baseerat Hamza Showkat Ganie Tasfi Shafi 《Natural product research》2016,30(20):2291-2298
The methanolic extract of the Tanacetum gracile afforded the isolation of new sesquiterpene lactone, named gracilone (1) along with four known compounds as 14α-taraxeran-3-one (2), 14α-taraxeran-3-ol (3), apigenin (4) and β-sitosterol (5). The structure of compound 1 was elucidated on the basis of 1D, 2D NMR and MS spectroscopic analysis. Antimicrobial, antioxidant and anticancer activities of all compounds were evaluated, from which gracilone (1) showed a moderate antibacterial activity, while apigenin (4) showed comparatively more antibacterial activity against both grampositive and gramnegative tested strains. 相似文献
292.
Stirling A Hamza A Rokob TA Pápai I 《Chemical communications (Cambridge, England)》2008,(27):3148-3150
A computational approach reveals cooperative action of the preorganized acidic and basic centers of the frustrated P(t-Bu)(3)/B(C(6)F(5))(3) Lewis pair on olefinic bonds as the key to the observed regioselective addition reaction. 相似文献
293.
Deuterium content of natural waters has been estimated with a mass spectromete using different methods of reduction of water samples. The optimum conditions for isotopic analysis are found, and the different parameters of the instrument are obtained. The accuracy was within ± 3ppm. 相似文献
294.
We revisit old conjectures of Fermat and Euler regarding the representation of integers by binary quadratic form x 2+5y 2. Making use of Ramanujan’s 1 ψ 1 summation formula, we establish a new Lambert series identity for $\sum_{n,m=-\infty }^{\infty}q^{n^{2}+5m^{2}}We revisit old conjectures of Fermat and Euler regarding the representation of integers by binary quadratic form x
2+5y
2. Making use of Ramanujan’s 1
ψ
1 summation formula, we establish a new Lambert series identity for
?n,m=-¥¥qn2+5m2\sum_{n,m=-\infty }^{\infty}q^{n^{2}+5m^{2}}
. Conjectures of Fermat and Euler are shown to follow easily from this new formula. But we do not stop there. Employing various
formulas found in Ramanujan’s notebooks and using a bit of ingenuity, we obtain a collection of new Lambert series for certain
infinite products associated with quadratic forms such as x
2+6y
2, 2x
2+3y
2, x
2+15y
2, 3x
2+5y
2, x
2+27y
2, x
2+5(y
2+z
2+w
2), 5x
2+y
2+z
2+w
2. In the process, we find many new multiplicative eta-quotients and determine their coefficients. 相似文献
295.
Two new phytochemical compounds, Tetranins A and B, 1-(3,5'-dihydroxy-4'-méthoxyphenyl)-2-phenylethanol 1 and 5,2'-dihydroxy-5'-methoxy-6,7-methylenedioxy-isoflavone 2, were isolated from the EtOAc extract of Salsola tetrandra roots. They exhibited a significant antioxidant effect in 1,1-diphenyl-2-picrylhydrazyl (DPPH) free radical and 2,2'-azinobis (3-ethylbenzothiazoline-6-sulphonic acid (ABTS) assays. Their structures were elucidated by extensive spectroscopic methods including 1-D-((1)H and (13)C) and 2-D-NMR experiments (CHcorr, HMBC, (1)H-(1)H COSY and NOESY) as well as high-resolution ES-MS and they were found to be quite active as antioxidants in the DPPH and ABTS assays. 相似文献
296.
We investigate dispersive properties of two dimensional photonic crystal (PC) called star-shaped PC (STAR-PC) in order to succeed super-collimation over a broad bandwidth. Both time- and frequency-domain numerical methods are conducted. Due to introduced low-symmetry in the primitive cell, flat contours are observed at the fifth band for transverse magnetic mode. The proposed structure supports a super-collimation effect over a broad wavelength range between 1443 nm and 1701 nm with a bandwidth of Δω = 16.42%. The intrinsic characteristic of STAR-PC provides in-plane beam propagation with a limited diffraction length of 120a, where a is the lattice constant. By means of STAR-PC, one may realize super-collimation based single-mode optical devices with a low insertion loss, reduced dispersion and wide bandwidth. 相似文献
297.
298.
Possible inhibitors preventing human immunodeficiency virus type 1 (HIV-1) entry into the cells are recognized as hopeful next-generation anti-HIV-1 drugs. It is highly desirable to develop a potent inhibitor blocking binding of glycoprotein CD4 of the cell with glycoprotein gp120 of HIV-1, because the gp120-CD4 binding is the initial step of HIV-1 entry into the cells. It has been recently reported that (-)-epigallocatechin gallate (EGCG) from green tea is an inhibitor blocking gp120-CD4 binding. But the inhibitory mechanism remains unknown. For understanding the inhibitory mechanism, extensive molecular docking, molecular dynamics simulations, and binding free-energy calculations have been performed in this study to predict the most favorable structures of CD4-EGCG, gp120-CD4, and gp120-CD4-EGCG binding complexes in water. The results reveal that EGCG binds with CD4 in such a way that the calculated binding affinity of gp120 with the CD4-EGCG complex is negligible. So, the favorable binding of EGCG with CD4 can effectively block gp120-CD4 binding. The calculated CD4-EGCG binding affinity (DeltaG(bind) = -5.5 kcal/mol, K(d) = 94 microM) is in excellent agreement with available experimental data suggesting IC(50) approximately 100 microM for EGCG-blocking CD4-gp120 binding. These results and insights provide a rational basis for future design of novel, more potent inhibitors to block gp120-CD4 binding. 相似文献
299.
M. H. Annaby A. E. Hamza K. A. Aldwoah 《Journal of Optimization Theory and Applications》2012,154(1):133-153
This paper is devoted for a rigorous investigation of Hahn’s difference operator and the associated calculus. Hahn’s difference operator generalizes both the difference operator and Jackson’s q-difference operator. Unlike these two operators, the calculus associated with Hahn’s difference operator receives no attention. In particular, its right inverse has not been constructed before. We aim to establish a calculus of differences based on Hahn’s difference operator. We construct a right inverse of Hahn’s operator and study some of its properties. This inverse also generalizes both Nörlund sums and the Jackson q-integrals. We also define families of corresponding exponential and trigonometric functions which satisfy first and second order difference equations, respectively. 相似文献
300.
We say that a quantum spin system is dynamically localized if the time-evolution of local observables satisfies a zero-velocity Lieb-Robinson bound. In terms of this definition we have the following main results: First, for general systems with short range interactions, dynamical localization implies exponential decay of ground state correlations, up to an explicit correction. Second, the dynamical localization of random xy spin chains can be reduced to dynamical localization of an effective one-particle Hamiltonian. In particular, the isotropic xy chain in random exterior magnetic field is dynamically localized. 相似文献