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71.
F. J. Martínez Crespo J. A. Palop Y. Sainz S. Narro V. Senador M. Gonzlez A. Lpez De Cerin A. Monge E. Hamilton A. J. Barker 《Journal of heterocyclic chemistry》1996,33(6):1671-1677
Several quinoxaline 1,4-di-N-oxides have been shown to be efficient and selective cytotoxins for hypoxic cells. We present now a series of 4-cyano-2-oxo-1,2,4-oxadiazolo[2,3-a]quinoxaline 5-N-oxides 2a-2k . They were prepared starting from 3-amino-2-quinoxalinecarbonitrile 1,4-di-N-oxides 1a-1k and 2-chloroethyl isocyanate in dry dioxane at 100–110°. A reaction mechanism is proposed. The treatment of 1a with phenyl isocyanate afforded 2a . Reaction of 2c with silica gel yielded 1c . Compounds 2a-2g were heated in the presence of ethanol and 2-propanol giving the corresponding carbamates 3a-3g and 4a-4g . Compound 2d was already obtained by heating a mixture of 1d and ethyl chloroformiate. Compound 2b was prepared when the carbamate 3b was heated at 150°. Quinoxalines were tested as cytotoxic agents both in oxic and hypoxic cells. The most interesting compounds were 3g and 4g . 相似文献
72.
Borja Vargas David Cuesta-Frau Paula Gonzlez-Lpez María-Jos Fernndez-Cotarelo
scar Vzquez-Gmez Ana Cols Manuel Varela 《Entropy (Basel, Switzerland)》2022,24(4)
Body temperature is usually employed in clinical practice by strict binary thresholding, aiming to classify patients as having fever or not. In the last years, other approaches based on the continuous analysis of body temperature time series have emerged. These are not only based on absolute thresholds but also on patterns and temporal dynamics of these time series, thus providing promising tools for early diagnosis. The present study applies three time series entropy calculation methods (Slope Entropy, Approximate Entropy, and Sample Entropy) to body temperature records of patients with bacterial infections and other causes of fever in search of possible differences that could be exploited for automatic classification. In the comparative analysis, Slope Entropy proved to be a stable and robust method that could bring higher sensitivity to the realm of entropy tools applied in this context of clinical thermometry. This method was able to find statistically significant differences between the two classes analyzed in all experiments, with sensitivity and specificity above 70% in most cases. 相似文献
73.
John de Jersey ZHENG Yuan-zhi FAN Hong-kuan Gary Schenk Luke Guddat Susan Hamilton 《高等学校化学研究》2006,22(2):263-264
Introduction Purpleacidphosphatases(PAPs)compriseofa familyofbinuclearmetal containinghydrolases,some membersofwhichhavebeenisolatedandcharacterized fromanimal,plantandfungalsources[1].PAPsnoton lycatalyzethehydrolysesofawiderangeofphosphate estersandanhy… 相似文献
74.
Kalin RM Hamilton JT Harper DB Miller LG Lamb C Kennedy JT Downey A McCauley S Goldstein AH 《Rapid communications in mass spectrometry : RCM》2001,15(5):357-363
Gas chromatography/mass spectrometry/isotope ratio mass spectrometry (GC/MS/IRMS) methods for delta(13)C measurement of the halomethanes CH(3)Cl, CH(3)Br, CH(3)I and methanethiol (CH(3)SH) during studies of their biological production, biological degradation, and abiotic reactions are presented. Optimisation of gas chromatographic parameters allowed the identification and quantification of CO(2), O(2), CH(3)Cl, CH(3)Br, CH(3)I and CH(3)SH from a single sample, and also the concurrent measurement of delta(13)C for each of the halomethanes and methanethiol. Precision of delta(13)C measurements for halomethane standards decreased (+/-0.3, +/-0.5 and +/-1.3 per thousand) with increasing mass (CH(3)Cl, CH(3)Br, CH(3)I, respectively). Given that carbon isotope effects during biological production, biological degradation and some chemical (abiotic) reactions can be as much as 100 per thousand, stable isotope analysis offers a precise method to study the global sources and sinks of these halogenated compounds that are of considerable importance to our understanding of stratospheric ozone destruction. 相似文献
75.
76.
J. Galy D. J. Hamilton C. Normand 《The European physical journal. Special topics》2009,175(1):147-152
In the last decade or so, an evolution in experimental relativistic laser-plasma physics has led to highly sophisticated lasers
which are now capable of generating ultra-short pulses and can be focused to intensities in excess of 1021 W cm-2. The laser interaction with solid or gas targets can generate collimated beams of highly energetic electrons, protons and
ions. These high-intensity laser systems, therefore, turn out to be versatile and powerful sources of radiation and high-energy
particles, without recourse to large-scale facilities such as nuclear reactors or particle accelerators. The potential to
induce various kinds of nuclear reactions with laser-induced radiation fields has been demonstrated at several laboratories
in recent years. The present paper lays out a comprehensive overview of nuclear reactions induced by high-intensity laser
matter interactions. Mechanisms for electron, proton and ion acceleration, in addition to secondary bremsstrahlung, positron
and neutron production, are addressed, with a focus on the types of nuclear reactions that are possible and potential applications.
Discussion of the extrapolation of these processes and applications to the next generation of table-top lasers under construction
is also presented. 相似文献
77.
Maria Catarina Coutinho Varela da Silva João Luís Maia Figueirinhas 《Liquid crystals》2016,43(1):124-130
A number of polymer dispersed liquid crystal (PDLC) films based on dimethacrylate monomers were synthesised by polymer-induced phase separation (PIPS) using polyethylene glycol p-(1,1,3,3-tetramethylbutyl)-phenyl ether (TX-100) as an additive up to total solution weight of 10% aiming to modify the initial anchorage force of the liquid crystal (LC) molecules to the polymeric matrix. The effects of the addition of this additive to the PDLC films were studied resorting to electro-optical studies. Using a fitting model, several parameters were correlated such as the permanent memory effect (PME), the voltage required to achieve 90% of maximum transmittance (E90), the average elastic constant (K) and the rotational viscosity of the director (γ). The use of TX-100 results on an increase on the PME and γ, and decrease on the E90 and K. 相似文献
78.
J. H. Northern A. W. J. Thompson M. L. Hamilton P. Ewart 《Applied physics. B, Lasers and optics》2013,111(4):627-635
The detection of multiple species using a single laser and single detector employing multi-mode absorption spectroscopy (MUMAS) is reported. An in-house constructed, diode-pumped, Er:Yb:glass micro-laser operating at 1,565 nm with 10 modes separated by 18 GHz was used to record MUMAS signals in a gas mixture containing C2H2, N2O and CO. The components of the mixture were detected simultaneously by identifying multiple transitions in each of the species. By using temperature- and pressure-dependent modelled spectral fits to the data, partial pressures of each species in the mixture were determined with an uncertainty of ±2 %. 相似文献
79.
Dr. Carlos Cabezas Dr. Marcelino Varela Prof. José L. Alonso 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(23):6520-6525
Among the hundreds of peptide compounds for which conformations have been determined by using different spectroscopic techniques, the structure of the simplest dipeptide glycylglycine (Gly-Gly) is conspicuously absent. Herein, for the first time, solid samples of Gly-Gly have been vaporized by laser ablation and three different structures have been revealed in a supersonic expansion by Fourier transform microwave spectroscopy. The intramolecular hydrogen bonding interactions that stabilize the observed forms have been established based on the 14N nuclear quadrupole hyperfine structure. We have illustrated how conformer interconversion distorts the equilibrium conformational distribution, giving rise to missing conformers in the conformational landscape. 相似文献
80.
E.C. Paris M.F.C. Gurgel G.P. Casali T.M. Boschi J.A. Varela 《Journal of Physics and Chemistry of Solids》2010,71(1):12-17
Pb1−xSmxTiO3 (PST) powders with x varying from 0 to 0.1 were obtained by the polymeric precursor method, a soft chemical route. The vibrational properties relating tetragonal to pseudo-cubic phase transition were studied by Raman spectroscopy. The results obtained showed that the phase transition is extremely dependent upon the samarium content and presents a diffuse behavior. Monitoring of the oxygen 2p and titanium 3d orbitals was performed by the periodic mechanical quantum method, revealing the changes that occur with the distribution and contribution of the hybrid orbitals due to the samarium influence. 相似文献