Ordered mesoporous SBA‐15/PrSO3Pd and SBA‐15/PrSO3PdNP as active,reusable and selective phosphine‐free catalysts in CX activation Heck coupling process

The incorporation of sulfonate into mesoporous SBA‐15 molecular sieves as ligands for palladium ions was used. Then SBA‐15/PrSO₃Pd and SBA‐15/PrSO₃Pd_NP were prepared and applied for the Heck arylation reaction of conjugate alkenes with aryl halides, to afford corresponding cross‐coupling products under phosphine‐free aerobic conditions with good to excellent yields. These supported palladium pre‐catalysts could be separated easily from reaction products and reused several times, showing superiority over homogeneous catalysts for industrial and chemical applications. Copyright © 2015 John Wiley & Sons, Ltd.     

Ultrafast GaN/AlN modulator based on quantum dot for terabit all-optical communication

An ultrafast all-optical modulator based on spherical quantum dot using electromagnetically induced transparency (EIT) technique in GaN/AlN structure, associated with inter-sublevel transitions, is proposed and analyzed. The aim of this paper is to modify and enhance the main parameters of an all-optical modulator such as, power consumption, modulation depth, maximum bit-rate and band-width. To realize these points, we have proposed a suitable quantum dot structure based on EIT in a strained GaN/AlN, with an internal barrier. Simulations show this barrier enhances the dot optical properties, such as dipole matrix element, linear susceptibility, and hence absorption coefficient, reducing the power consumption and increasing the modulation depth. Furthermore, using control signal in EIT process, carriers are driven from an upper state to a lower state from where they rapidly decay to the ground state increasing the modulation bit-rate and band-width.     

The Potential Role of Apigenin in Cancer Prevention and Treatment

Cancer is the leading cause of death worldwide. In spite of advances in the treatment of cancer, currently used treatment modules including chemotherapy, hormone therapy, radiation therapy and targeted therapy causes adverse effects and kills the normal cells. Therefore, the goal of more effective and less side effects-based cancer treatment approaches is still at the primary position of present research. Medicinal plants or their bioactive ingredients act as dynamic sources of drugs due to their having less side effects and also shows the role in reduction of resistance against cancer therapy. Apigenin is an edible plant-derived flavonoid that has received significant scientific consideration for its health-promoting potential through modulation of inflammation, oxidative stress and various other biological activities. Moreover, the anti-cancer potential of apigenin is confirmed through its ability to modulate various cell signalling pathways, including tumor suppressor genes, angiogenesis, apoptosis, cell cycle, inflammation, apoptosis, PI3K/AKT, NF-κB, MAPK/ERK and STAT3 pathways. The current review mainly emphases the potential role of apigenin in different types of cancer through the modulation of various cell signaling pathways. Further studies based on clinical trials are needed to explore the role of apigenin in cancer management and explain the possible potential mechanisms of action in this vista.