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Sung‐Fu Hsu Tzong‐Ming Wu Chien‐Shiun Liao 《Journal of Polymer Science.Polymer Physics》2006,44(23):3337-3347
Poly(3‐hydroxybutyrate) (PHB)/layered double hydroxides (LDHs) nanocomposites were prepared by mixing PHB and poly(ethylene glycol) phosphonates (PEOPAs)‐modified LDH (PMLDH) in chloroform solution. Both X‐ray diffraction data and TEM micrographs of PHB/PMLDH nanocomposites indicate that the PMLDHs are randomly dispersed and exfoliated into the PHB matrix. In this study, the effect of PMLDH on the isothermal crystallization behavior of PHB was investigated using a differential scanning calorimeter (DSC) and polarized optical microscopy. Isothermal crystallization results of PHB/PMLDH nanocomposites show that the addition of 2 wt % PMLDH into PHB induced more heterogeneous nucleation in the crystallization significantly increasing the crystallization rate and reducing their activation energy. By adding more PMLDH into the PHB probably causes more steric hindrance of the diffusion of PHB, reducing the transportation ability of polymer chains during crystallization, thus increasing the activation energy. The correlation among crystallization kinetics, melting behavior and crystalline structure of PHB/PMLDH nanocomposites can also be discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3337–3347, 2006 相似文献
123.
L. A. Gil‐Alana 《商业与工业应用随机模型》2006,22(4):385-395
This article examines the length of the cycles in the gross domestic product (GDP) real per capita series of 15 countries by means of new statistical techniques based on unit root cycles. We propose tests for unit root cycles at each of the frequencies of the process. Using this approach, we are able to approximate the number of periods per cycle. The results show that the cycles have a periodicity of approximately six years when the disturbances are white noise. However, if we permit autocorrelation, they may also occur at smaller intervals of time. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
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This study analyzes the economics of transshipping biomass from truck to train in a North American setting. Transshipment
will only be economic when the cost per unit distance of a second transportation mode is less than the original mode. There
is an optimum number of transshipment terminals which is related to biomass yield. Transshipment incurs incremental fixed
costs, and hence there is a minimum shipping distance for rail transport above which lower costs/km offset the incremental
fixed costs. For transport by dedicated unit train with an optimum number of terminals, the minimum economic rail shipping
distance for straw is 170 km, and for boreal forest harvest residue wood chips is 145 km. The minimum economic shipping distance
for straw exceeds the biomass draw distance for economically sized centrally located power plants, and hence the prospects
for rail transport are limited to cases in which traffic congestion from truck transport would otherwise preclude project
development. Ideally, wood chip transport costs would be lowered by rail transshipment for an economically sized centrally
located power plant, but in a specific case in Alberta, Canada, the layout of existing rail lines precludes a centrally located
plant supplied by rail, whereas a more versatile road system enables it by truck. Hence for wood chips as well as straw the
economic incentive for rail transport to centrally located processing plants is limited. Rail transshipment may still be preferred
in cases in which road congestion precludes truck delivery, for example as result of community objections. 相似文献
126.
Jian‐guo Tang 《Mathematical Methods in the Applied Sciences》2006,29(11):1327-1338
An implicit iterative method is applied to solving linear ill‐posed problems with perturbed operators. It is proved that the optimal convergence rate can be obtained after choosing suitable number of iterations. A generalized Morozov's discrepancy principle is proposed for the problems, and then the optimal convergence rate can also be obtained by an a posteriori strategy. The convergence results show that the algorithm is a robust regularization method. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
127.
This paper is devoted to the proof of almost global existence results for Klein‐Gordon equations on Zoll manifolds (e.g., spheres of arbitrary dimension) with Hamiltonian nonlinearities, when the Cauchy data are smooth and small. The proof relies on Birkhoff normal form methods and on the specific distribution of eigenvalues of the Laplacian perturbed by a potential on Zoll manifolds. © 2007 Wiley Periodicals, Inc. 相似文献
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