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131.
Natural biopolymers from plant sources contain many impurities (e.g., fat, protein, fiber, natural pigment and endogenous enzymes), therefore, an efficient purification process is recommended to minimize these impurities and consequently improve the functional properties of the biopolymer. The main objective of the present study was to investigate the effect of different purification techniques on the yield, protein content, solubility, water- and oil-holding capacity of a heteropolysaccharide-protein biopolymer obtained from durian seed. Four different purification methods using different chemicals and solvents (i.e., A (isopropanol and ethanol), B (isopropanol and acetone), C (saturated barium hydroxide), and D (Fehling solution)] to liberate the purified biopolymer from its crude form were compared. In most cases, the purification process significantly (p < 0.05) improved the physicochemical properties of heteropolysaccharide-protein biopolymer from durian fruit seed. The present work showed that the precipitation using isopropanol and acetone (Method B) resulted in the highest purification yield among all the tested purification techniques. The precipitation using saturated barium hydroxide (Method C) led to induce the highest solubility and relatively high capacity of water absorption. The current study reveals that the precipitation using Fehling solution (Method D) most efficiently eliminates the protein fraction, thus providing more pure biopolymer suitable for biological applications. 相似文献
132.
Synthesis of D-mannitol substituted ether-linked bis-1,2,3-triazoles as models of gemini surfactants
Adnan Ibrahim Mohammed Zaid Hassan AbboudAtheer Hamed Odda Alghanimi 《Tetrahedron letters》2012,53(38):5081-5083
Readily available and low cost D-mannitol was converted into 1,2,5,6-di-O-isopropylidene-D-mannitol (1) in the presence of acetone and zinc chloride. Williamson etherfication of 1 with propargyl bromide afforded the bisalkyne 2 in a very good yield. 1,3-Dipolar cycloaddition of 2 with four different alkyl azides using click conditions gave four novel bistriazoles 3a-d. Removal of the acetal groups of 3a-d afforded the deprotected bistriazoles 4a-d in excellent yields. Products 3 and 4 represent models of gemini surfactants. 相似文献
133.
Xinlai Cheng Hamed Alborzinia Karl-Heinz Merz Herbert Steinbeisser Ralf Mrowka Catharina Scholl Igor Kitanovic Gerhard Eisenbrand Stefan Wölfl 《Chemistry & biology》2012,19(11):1423-1436
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134.
Despite considerable presence of periodic multilayers with wavy architectures in nature and technology, little simulation data is available on their response. A recent investigation of wavy multilayers comprised of alternating elastic and elastic-perfectly plastic plies has revealed the important role that plasticity plays on their post-yield response relative to the corresponding flat configurations [Khatam, H., Pindera, M.-J., 2009b. Parametric finite-volume micromechanics of periodic materials with elastoplastic phases. Int. J. Plasticity 25 (7), 1386–1411]. Herein, we extend this investigation by considering the effect of elastic layer thickness on the post-yield response at several fixed elastic phase volume fractions using the parametric finite-volume direct averaging micromechanics (FVDAM) theory. The layer thickness is shown to have a substantial impact on the post-yield response whose extent depends on the loading mode and waviness amplitude, in contrast with the minimal impact on the homogenized elastic moduli. Decreasing the layer thickness at sufficiently high fixed volume fractions decreases the extent of strain hardening under transverse normal loading, as well as the maximum normal and shear stresses in the stiff layers, reducing the possibility of failure and thus potentially enhancing durability. The opposite holds under transverse shear loading for low waviness amplitudes. The presented results provide a framework for tailoring the elastoplastic response of multilayers with sinusoidally varying plies under different loading modes. 相似文献
135.
El-Sayed A. El-Sheikh Mahmoud M. Ramadan Ahmed E. El-Sobki Ali A. Shalaby Mark R. McCoy Ibrahim A. Hamed Mohamed-Bassem Ashour Bruce D. Hammock 《Molecules (Basel, Switzerland)》2022,27(22)
The use of pesticides leads to an increase in agricultural production but also causes harmful effects on human health when excessively used. For safe consumption, pesticide residues should be below the maximum residual limits (MRLs). In this study, the residual levels of pesticides in vegetables and fruits collected from farmers’ markets in Sharkia Governorate, Egypt were investigated using LC-MS/MS and GC-MS/MS. A total number of 40 pesticides were detected in the tested vegetable and fruit samples. Insecticides were the highest group in detection frequency with 85% and 69% appearance in vegetables and fruits, respectively. Cucumber and apple samples were found to have the highest number of pesticide residues. The mean residue levels ranged from 7 to 951 µg kg−1 (in vegetable samples) and from 8 to 775 µg kg−1 (in fruit samples). It was found that 35 (40.7%) out of 86 pesticide residues detected in vegetables and 35 (38.9%) out of 90 pesticide residues detected in fruits exceeded MRLs. Results for lambda-cyhalothrin, fipronil, dimothoate, and omethoate in spinach, zucchini, kaki, and strawberry, respectively, can cause acute or chronic risks when consumed at 0.1 and 0.2 kg day−1. Therefore, it is necessary for food safety and security to continuously monitor pesticide residues in fruits and vegetables in markets. 相似文献
136.
Ahmed I. M. Hamed Mostafa M. Aglan R. F. Aly M. I. 《Journal of Radioanalytical and Nuclear Chemistry》2019,319(1):39-49
Sulfonated ion irradiated (H+ and He2+) PEEK films were synthesized with a range of cross-linking density and a variety of sulfonation degrees. Batch adsorption experiments were carried out at an initial pH of 6.0 ± 0.2, initial concentrations of Pb2+ and 137Cs ions of 10.0 mg L−1 and 5500 Bq L−1, respectively. The maximum adsorption capacity was 60 mg g−1 for Pb2+, and the distribution coefficient reached 6200 cm3 g−1 for 137Cs. The results indicated that sulfonation could be used to recycle low cross-linked PEEK and prepare efficient adsorbents to remove toxic Pb2+ and 137Cs from polluted aqueous solutions.
相似文献137.
Nabil A. Younes Md. Mezanur Rahman Ahmed A. Wardany Mona F. A. Dawood Mohammad Golam Mostofa Sanjida Sultana Keya Arafat Abdel Hamed Abdel Latef Lam-Son Phan Tran 《Molecules (Basel, Switzerland)》2021,26(9)
The increasing culinary use of onion (Alium cepa) raises pressure on the current production rate, demanding sustainable approaches for increasing its productivity worldwide. Here, we aimed to investigate the beneficial effects of licorice (Glycyrrhiza glabra) root extract (LRE) in improving growth, yield, nutritional status, and antioxidant properties of two high-yielding onion cultivars, Shandaweel and Giza 20, growing under field conditions in two consecutive years. Our results revealed that pretreatments of both onion cultivars with LRE exhibited improved growth indices (plant height and number of leaves) and yield-related features (bulb length, bulb diameter, and bulb weight) in comparison with the corresponding LRE-devoid control plants. Pretreatments with LRE also improved the nutritional and antioxidant properties of bulbs of both cultivars, which was linked to improved mineral (e.g., K+ and Ca2+) acquisition, and heightened activities of enzymatic antioxidants (e.g., superoxide dismutase, catalase, ascorbate peroxidase, glutathione peroxidase, and glutathione S-transferase) and increased levels of non-enzymatic antioxidants (e.g., ascorbic acid, reduced glutathione, phenolics, and flavonoids). LRE also elevated the contents of proline, total free amino acids, total soluble carbohydrates, and water-soluble proteins in both onion bulbs. In general, both cultivars displayed positive responses to LRE pretreatments; however, the Shandaweel cultivar performed better than the Giza 20 cultivar in terms of yield and, to some extent, bulb quality. Collectively, our findings suggest that the application of LRE as biostimulant might be an effective strategy to enhance bulb quality and ultimately the productivity of onion cultivars under field conditions. 相似文献
138.
Ibrahim Muhammad Saeed Tareq Algehyne Ebrahem A. Alsulami Hamed Chu Yu-Ming 《Journal of Thermal Analysis and Calorimetry》2021,144(6):2449-2463
Journal of Thermal Analysis and Calorimetry - In this paper, the natural convection (NC) of the Al2O3–H2O nanofluids (NFs) in a cavity with a heat source in its center is numerically... 相似文献
139.
Eshgarf Hamed Kalbasi Rasool Maleki Akbar Shadloo Mostafa Safdari karimipour Arash 《Journal of Thermal Analysis and Calorimetry》2021,144(5):1959-1983
Journal of Thermal Analysis and Calorimetry - These days, the importance of energy consumption has led scientists to optimize thermal devices. One of the solutions proposed for this purpose is... 相似文献
140.
A planar polycrystalline copper target was bombarded normally by Ar+ ions with energies ranging from 60 to 300 eV. in the source of a mass spectrometer. The neutral particles sputtered normally from the target were post-ionized and analyzed in the mass spectrometer. A thermionically sustained, magnetically confined low pressure arc plasma was used to supply the bombarding ions, and for post-ionization of the neutral sputtered species. It was found that the relative yields of the sputtered neutral post-ionized Cu2 dimers are linearly proportional to S2, where S is the total sputtering yield for Ar+ -Cu. The results support the recombination model for the formation of neutral dimers in sputtering. 相似文献