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81.
Farid Taherkhani Hadi Abroshan Hamed Akbarzadeh Alessandro Fortunelli 《Phase Transitions》2013,86(7):613-623
We investigate a one-dimensional (1-D) Ising model for finite-site systems. The finite-site free energy and the surface free energy are calculated via the transfer matrix method. We show that, at high magnetic fields, the surface free energy has an asymptotic limit. The absolute surface energy increases when the value of f (the ratio of magnetic field to nearest-neighbor interactions) increases, and for f?≥?10 approaches a constant value. For the values of f?≥?0.2, the finite-site free energy also increases, but slowly. The thermodynamic limit in which physical properties approach the bulk value is also explored. 相似文献
82.
Salah Abd El Wanees Sabry Hamed Seda 《Journal of Dispersion Science and Technology》2013,34(12):1813-1826
AbstractThe kinetics of H2 production during Zn corrosion in 0.5?M HCl without and with various additives of N,N'-bis-(1-hydroxyphenylimine)-2,5-thiophenedicarboxaldehyde (HPTD) was studied using gasometry and electrochemical techniques. The surface of the corroded Zn samples was investigated using SEM and Optical Profilometry. The rate of H2 production (RHP) increased with the immersion time and temperature. Presence of HPTD mitigated RHP due to an adsorption process. The electrochemical impedance spectroscopy showed that HPTD had a good inhibitive effect. Polarization data proved that HPTD acted as a surface-active mixed-type inhibitor. Some thermodynamic parameters were deduced and discussed. Theoretical calculations were also conducted to corroborate the capability of HPTD to protect Zn surface from corrosion process. 相似文献
83.
This paper presents a simulation and an analytical modeling of the machine interference problem in manufacturing cells. Each machine experiences two types of stoppage which are to be served by a robot. Several combinations of the distributions of the stoppages, service distributions, and service disciplines are studied. We determine the optimal number of machines assigned to the robot under different operating conditions such that the expected total cost of the manufacturing cell is minimized.This research is based on Mr. Norton's M.S. thesis, which was conducted at Rutgers. 相似文献
84.
Decisions concerning a project’s expedition, traditionally involved considerations regarding time and cost tradeoff. It was recently suggested that the quality of a project should also be taken into considerations. In this paper, we propose a meta-heuristic solution procedure for the discrete time, cost and quality tradeoff problem. This problem involves the scheduling of project activities in order to minimize the total cost of the project while maximizing the quality of the project and also meeting a given deadline. We apply a so called electromagnetic scatter search to solve this problem. In this process, we initially generate a population of feasible solutions. In so doing, we use frequency memory to well sample the feasible region. A number of these solutions are then selected and improved locally. The improved solutions are then combined to generate new set of solutions. The combination process utilizes attraction–repulsion mechanisms borrowed from the electromagnetism theory. The whole process is stopped when no significant improvement in the set of solutions are observed. The validity of the proposed solution procedure is demonstrated, and its applicability is tested on a randomly generated large and complex problem having 19,900 activities. 相似文献
85.
Alberto Plaza Ciro Balestrieri Giuseppe Bifulco Arafa Hamed Sonia Piacente 《Tetrahedron》2005,61(31):7470-7480
Eight new 14,15-secopregnane glycosides, namely argelosides C-J, possessing two ketal functions involved in three five-membered rings, have been isolated from the hairy seeds of Solenostemma argel. Their structures have been established by MS and NMR experiments, combined with quantum mechanical calculations of the 13C chemical shifts for the interpretation of the experimental data. On the basis of the obtained results, the structures of argelosides A and B have been revised. Additionally, the effect of these compounds on the VEGF-induced in Kaposi's sarcoma cell proliferation was evaluated. Results indicated that all the compounds reduced the cell proliferation in a dose-dependent manner. 相似文献
86.
R. H. Abu-Eittah M. M. Hamed M. M. Abdou 《International journal of quantum chemistry》1987,31(6):855-869
The electronic absorption spectra of some phenylethylamine drugs, namely, d-pseudoepherine, l-pseudoephedrine, l-ephedrine, dl-ephedrine dl-norephedrine, phenylethylamine, methoxyphenamine, and l-noradrenaline were investigated in polar and nonpolar solvents. The observed transitions were interpreted, and the role of σ-π interaction was explored. Molecular orbital calculations were performed on representatives of the above group of compounds, namely, d-pseudoephedrine, l-ephedrine, and l-noradrenaline using the INDO procedures and adopting the best conformer of the molecule. The transition energy, band intensity, and dipole moments were calculated and corresponded satisfactorily with the experimental values. 相似文献
87.
Magda F. Mohamed Mervat S. Mohamed Samia A. Shouman Mohamed M. Fathi Ismail Abdelshafy Abdelhamid 《Applied biochemistry and biotechnology》2012,168(5):1153-1162
A newly synthesized series of chalcone derivatives containing pyrazole rings were synthesized and evaluated for their cytotoxic activities in vitro against several human cancer cell lines. Most of the prepared compounds showed potential cytotoxicity against human breast cancer cell lines MCF-7, HEPG-2, and HCT-116. Also the compounds were evaluated as antimicrobial agents. The three compounds 3, 4, and 5 were proved to be better anticancer agents than the positive standard doxorubicin with IC50 values (4.7, 4.4, and 3.9???g/ml) against the same human cancer cell lines, whereas compounds 5 and 6 showed the most active antimicrobial compounds in comparison to the other chalcones. 相似文献
88.
C‐Coumarinoyl‐N‐arylformohydrazonoyl bromides ( 3 ) were synthesized by reaction of N‐nitrosoarylacetamides with an appropriate sulfonium bromide in ethanol at room temperature. The reactions of potassium thiocyanate, potassium selenocyanate, thiourea, methyl phenylthiocarbomate, and methyl phenylhydrazinedithioate with hydrazonoyl bromide 3a were examined. © 1999 John Wiley & Sons, Inc. Heteroatom Chem 10: 355–362, 1999 相似文献
89.
Hanna Mouaziz Sebastian Braconnot Frédéric Ginot Abdelhamid Elaissari 《Colloid and polymer science》2009,287(3):287-297
Aminodextran containing submicron magnetic latex particles were prepared in two steps: (a) transformation of oil-in-water
magnetic emulsion into structured magnetic latex particles via combination of seed and miniemulsion-like polymerization process
and (b) immobilization (adsorption and chemical grafting) of prepared aminodextran onto negatively charged seed magnetic latex
particles. The elaborated magnetic latex particles were characterized in terms of particle size, size distribution, morphology,
surface charge density, chemical composition, magnetic properties, and also colloidal stability. The results showed that the
morphology of the prepared seed magnetic latex is core–shell like and the cationic latex particles are hydrophilic and of
high colloidal stability, irrespective of the aminodextran immobilization process. 相似文献
90.
Abbas Afkhami Farzaneh Soltani-Felehgari Tayyebeh Madrakian Hamed Ghaedi Majid Rezaeivala 《Analytica chimica acta》2013
A new chemically modified carbon paste electrode was constructed and used for rapid, simple, accurate, selective and highly sensitive simultaneous determination of cadmium, copper and mercury using square wave anodic stripping voltammetry (SWASV). The carbon paste electrode was modified by N,N′-bis(3-(2-thenylidenimino)propyl)piperazine coated silica nanoparticles. Compared with carbon paste electrode, the stripping peak currents had a significant increase at the modified electrode. Under the optimized conditions (deposition potential, −1.100 V vs. Ag/AgCl; deposition time, 60 s; resting time, 10 s; SW frequency, 25 Hz; pulse amplitude, 0.15 V; dc voltage step height, 4.4 mV), the detection limit was 0.3, 0.1 and 0.05 ng mL−1 for the determination of Cd2+, Cu2+ and Hg2+, respectively. The complexation reaction of the ligand with several metal cations in methanol was studied and the stability constants of the complexes were obtained. The effects of different cations and anions on the simultaneous determination of metal ions were studied and it was found that the electrode is highly selective for the simultaneous determination of Cd2+, Cu2+ and Hg2+. Furthermore, the present method was applied to the determination of Cd2+, Cu2+ and Hg2+ in water and some foodstuff samples. 相似文献