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81.
82.
Sakamoto K Takashima Y Hamada N Ichida H Yamaguchi H Yamamoto H Harada A 《Organic letters》2011,13(4):672-675
An energy transfer process was investigated using cyclodextrin-oligothiophene rotaxanes (2T-[2]rotaxane). The excited energy of 2T-[2]rotaxane is transferred to the sexithiophene derivative which is included in the cavity of β-CD stoppers of 2T-[2]rotaxane. 相似文献
83.
Two stereoisomers of cis-[Ru(bpy)(pynp)(CO)Cl]PF6 (bpy = 2,2′-bipyridine, pynp = 2-(2-pyridyl)-1,8-naphthyridine) were selectively prepared. The pyridyl rings of the pynp ligand in [Ru(bpy)(pynp)(CO)Cl]+ are situated trans and cis, respectively, to the CO ligand. The corresponding CH3CN complex ([Ru(bpy)(pynp)(CO)(CH3CN)]2+) was also prepared by replacement reactions of the chlorido ligand in CH3CN. Using these complexes, ligand-centered redox behavior was studied by electrochemical and spectroelectrochemical techniques. The molecular structures of pynp-containing complexes (two stereoisomers of [Ru(bpy)(pynp)(CO)Cl]PF6 and [Ru(pynp)2(CO)Cl]PF6) were determined by X-ray structure analyses. 相似文献
84.
Some new heterocyclic compounds containing isoxazole, pyrazole and oxadiazole ring systems were prepared from various chalcones. The synthesized compounds have been characterized by elemental analysis and spectral methods. These compounds were screened for their antimicrobial activities. 相似文献
85.
Lattice dynamics and electron-phonon coupling are calculated for non-magnetic hcp iron at 100 GPa by a first-principles linear response full-potential LMTO method. Superconducting transition temperature is estimated to be less than 0.5 K. For ferromagnetic bcc iron lattice dynamical calculations are performed for 9.8 GPa as well as for ambient pressure. The results of calculation reproduce well the pressure dependence of phonon dispersion curves observed by neutron scattering measurements. 相似文献
86.
Hiroaki Koga Takeyuki Arai Taisuke Hamada Shigeyoshi Sakaki 《Journal of molecular catalysis. A, Chemical》2003,200(1-2):223-228
In the two-electron reduction of diphenylsulfoxide to diphenylsulfide, which is considered a model reaction of sulfite reduction catalyzed by sulfite reductase, methylviologen-pendent iron(III) porphyrin exhibits much higher catalytic activity than usual iron(III) and manganese(III) tetraphenylporphyrins, while cobalt(II) tetraphenylporphyrin exhibits much less catalytic activity than the others. Discussion about the active species and the reason of the acceleration by methylviologen-pendent is presented. 相似文献
87.
T. Ocho S. Kubo M. Ikeda T. Saito Y. Terumichi Y. Hamada S. Tanaka 《Physics letters. A》1980,77(5):318-320
When ohmic heating power is applied during the microwave discharge at the electron cyclotron resonance, the plasma current and density build-up become fast and the loop voltage required to start the tokamak discharge decreases. The micro-wave burst observed in the initial stage is reduced and the burst of hard X-rays, occurring at the quasi-steady stage of discharge in the case of no microwave injection, disappears, suggesting that the production of run-away electrons is suppressed strongly. 相似文献
88.
89.
Let nq(k, d) denote the smallest value of n for which there exists an [n, k, d; q]-code. It is known (cf. (J. Combin. Inform. Syst. Sci.18, 1993, 161–191)) that (1) n3(6, 195) {294, 295}, n3(6, 194) {293, 294}, n3(6, 193) {292, 293}, n3(6, 192) {290, 291}, n3(6, 191) {289, 290}, n3(6, 165) {250, 251} and (2) there is a one-to-one correspondence between the set of all nonequivalent [294, 6, 195; 3]-codes meeting the Griesmer bound and the set of all {v2 + 2v3 + v4, v1 + 2v2 + v3; 5, 3}-minihypers, where vi = (3i − 1)/(3 − 1) for any integer i ≥ 0. The purpose of this paper is to show that (1) n3(6, 195) = 294, n3(6, 194) = 293, n3(6, 193) = 292, n3(6, 192) = 290, n3(6, 191) = 289, n3(6, 165) = 250 and (2) a [294, 6, 195; 3]-code is unique up to equivalence using a characterization of the corresponding {v2 + 2v3 + v4, v1 + 2v2 + v3; 5, 3}-minihypers. 相似文献
90.