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71.
[structure: see text] C-1,2-alternate tetrahomodioxacalix[4]arene pyreneamides were synthesized. Pb(2+) coordination gave a quenched monomer and excimer fluorescence emission, while upon Ca(2+) ion binding, the receptor provides an enhanced excimer and declined monomer emission with ratiometric response. The excimer emission spectra changes are rationalized by frontier molecular orbitals that the effective Py-Py interaction induces emission intensity increases upon Ca(2+) ion complexation, whereas there is no such interaction observed upon Pb(2+) binding. 相似文献
72.
[reaction: see text] Potassium bromo- and iodomethyltrifluoroborates have been prepared via in situ reaction of n-BuLi with dibromo- and diiodomethane, respectively, in the presence of trialkyl borates, followed by treatment with KHF(2). Moreover, a new synthetic method for the preparation of potassium organotrifluoroborates through nucleophilic substitution of the halide in these potassium halomethyltrifluoroborates is described. 相似文献
73.
74.
Jung Sook Ham 《Journal of Mathematical Analysis and Applications》2003,286(1):116-124
Let α≡{αn}n=0∞ be a weight sequence and let Wα denote the associated unilateral weighted shift on . In this paper we prove that if α is eventually increasing, then Wα is M-hyponormal and that if α has exactly two subsequential limits such that the larger one is different from the spectral radius of Wα then Wα is not M-hyponormal. 相似文献
75.
76.
We have discovered a novel, spontaneous model oxidation that leads to a powerful base capable of carrying out a carbon-carbon bond forming condensation reaction analogous to that observed in the vitamin K-mediated carboxylation of glutamate. The model sequence incorporates a novel base-strength enhancement sequence and it implicates molecular oxygen as the initiating factor in the vitamin K-dependent carboxylation. When the oxygenation is carried out under an atmosphere of (18)O2, two atoms of (18)O are incorporated into the vitamin K oxide product. Selective (18)O labelling defines the carbonyl group next to methyl as the active site of the vitamin K. 相似文献
77.
2,3-Disubstituted indoles were synthesized by solid-phase reaction using the Fischer indole synthesis. A "traceless" silicon linker was employed with the silicon-carbon bonding being cleaved with TFA. An oxygen atom was placed into the middle of the spacer/linker so as to enhance solid-phase synthesis by better solvation. 相似文献
78.
79.
A microscopic site binding model to treat binding of several metal ions to multi-center receptors is proposed. The model introduces the appropriate parameterization in terms of microscopic complexation constants and metal-metal pair interaction energies. The model is solved with statistical mechanical techniques, including direct enumeration or transfer matrices. We obtain microscopic and macroscopic complexation constants, microstate probabilities, and binding isotherms for chain-like receptors, including the long-chain limit. Various examples to illustrate the usefulness of the model are given. 相似文献
80.
YoonMee Ham & Sang sup Yum 《偏微分方程(英文版)》1995,8(3):211-218
We consider a free boundary problem in a parabolic partial differential equation with multiple interfacial curves which is reduced to a reaction-diffusion equation. The forcing term of this problem is not continuously differentiable and thus we use Green's function to make a regular one. The existence, uniqueness and dependence. on initial conditions will be shown in this paper. 相似文献