Grenzflächen Lösung/Luft. II. Adsorption von oberflächenaktiven Substanzen in verdünnten wäßrigen Lösungen. Anomale Schwingungsstrahl-Erscheinungen

Colloid and Polymer Science -     

Activity interference and noise annoyance

Debate continues over differences in the dose-response functions used to predict the annoyance at different sources of transportation noise. This debate reflects the lack of an accepted model of noise annoyance in residential communities. In this paper a model is proposed which is focussed on activity interference as a central component mediating the relationship between noise exposure and annoyance. This model represents a departure from earlier models in two important respects. First, single event noise levels (e.g., maximum levels, sound exposure level) constitute the noise exposure variables in place of long-term energy equivalent measures (e.g., 24-hour L_eq or L_dn). Second, the relationships within the model are expressed as probabilistic rather than deterministic equations. The model has been tested by using acoustical and social survey data collected at 57 sites in the Toronto region exposed to aircraft, road traffic or train noise. Logit analysis was used to estimate two sets of equations. The first predicts the probability of activity interference as a function of event noise level. Four types of interference are included: indoor speech, outdoor speech, difficulty getting to sleep and awakening. The second set predicts the probability of annoyance as a function of the combination of activity interferences. From the first set of equations, it was possible to estimate a function for indoor speech interference only. In this case, the maximum event level was the strongest predictor. The lack of significant results for the other types of interference is explained by the limitations of the data. The same function predicts indoor speech interference for all three sources—road, rail and aircraft noise. The results for the second set of equations show strong relationships between activity interference and the probability of annoyance. Again, the parameters of the logit equations are similar for the three sources. A trial application of the model predicts a higher probability of annoyance for aircraft than for road traffic situations with the same 24-hour L_eq. This result suggests that the model may account for previously reported source differences in annoyance.     

Ion-pair high-performance liquid chromatographic separation of a multicomponent anticholinergic drug formulation

N,N'-Trimethylene-bis-(pyridinium-4-aldoxime)dibromide, 4-pyridine aldoxime, atropine sulfate, benactyzine hydrochloride, methyl paraben and propyl paraben are separated by ion-pair high-performance liquid chromatography. The method is specific for detecting and quantifying each compound in a complex mixture without solvent extraction or pretreatment. Levels as low as 1 ng on column are quantifiable by the procedure. All components are eluted within 9 min subsequent to the initial injection. Because of the simplicity of the method, the procedure is suitable for routinely monitoring the stability of the various compounds in the formulation during storage.     

Intensity convolutions of CARS spectra

A derivation of the convolution integral for finite bandwidth pump and Stokes sources in CARS is given. The resulting “partially coherent” convolution confirms previously published results, and is compared to the widely used incoherent treatment. The effect of intensity convolution choice on multiplex CARS thermometry is evaluated by reducing N₂ data taken in an ethylene-air diffusion flame. N₂ CARS thermometry using multimode pumps is ordinarily not very sensitive to convolution.     

Mapping of the cerebral response to acetazolamide using graded asymmetric spin echo EPI

Cerebral vascular reactivity in different regions of the rat brain was quantitatively characterized by spatial and temporal measurements of blood oxygenation level-dependent (BOLD)-fMRI signals following intravenous administration of the carbonic anhydrase inhibitor acetazolamide: this causes cerebral vasodilatation through a cerebral extracellular acidosis that spares neuronal metabolism and vascular smooth muscle function, thus separating vascular and cerebral metabolic events. An asymmetric spin echo-echo planar imaging (ASE-EPI) pulse sequence sensitised images selectively to oxygenation changes in the microvasculature; use of a surface coil receiver enhanced image signal-to-noise ratios (SNRs). Image SNRs and hardware integrity were verified by incorporating quality assurance procedures; cardiorespiratory stability in the physiological preparations were monitored and maintained through the duration of the experiments. These conditions made it possible to apply BOLD contrast fMRI to map regional changes in cerebral perfusion in response to acetazolamide administration. Thus, fMRI findings demonstrated cerebral responses to acetazolamide that directly paralleled the known physiological actions of acetazolamide and whose time courses were similar through all regions of interest, consistent with acetazolamide's initial distribution in brain plasma, where it affects cerebral haemodynamics by acting at cerebral capillary endothelial cells. However, marked variations in the magnitude of the responses suggested relative perfusion deficits in the hippocampus and white matter regions correlating well with their relatively low vascularity and the known vulnerability of the hippocampus to ischaemic damage.     

Simple and compact 1-Hz laser system via an improved mounting configuration of a reference cavity

We report an improved mounting configuration for a passive optical cavity used for laser frequency stabilization. The associated reduction of the vibration sensitivity of the effective cavity length has led to a simple and compact reference cavity system for laser stabilization at the level of 1 Hz linewidth.     

Observation of laser driven supercritical radiative shock precursors

We present a supercritical radiative shock experiment performed with the LULI nanosecond laser facility. Using targets filled with xenon gas at low pressure, the propagation of a strong shock with a radiative precursor is evidenced. The main measured shock quantities (electronic density and propagation velocity) are shown to be in good agreement with theory and numerical simulations.     

Measurement of the total active 8B solar neutrino flux at the Sudbury Neutrino Observatory with enhanced neutral current sensitivity

The Sudbury Neutrino Observatory has precisely determined the total active (nu(x)) 8B solar neutrino flux without assumptions about the energy dependence of the nu(e) survival probability. The measurements were made with dissolved NaCl in heavy water to enhance the sensitivity and signature for neutral-current interactions. The flux is found to be 5.21 +/- 0.27(stat)+/-0.38(syst) x 10(6) cm(-2) s(-1), in agreement with previous measurements and standard solar models. A global analysis of these and other solar and reactor neutrino results yields Deltam(2)=7.1(+1.2)(-0.6) x 10(-5) eV(2) and theta=32.5(+2.4)(-2.3) degrees. Maximal mixing is rejected at the equivalent of 5.4 standard deviations.