Beam search (BS) is used as a heuristic to solve various combinatorial optimization problems, ranging from scheduling to assembly line balancing. In this paper, we develop a backtracking and an exchange-of-information (EOI) procedure to enhance the traditional beam search method. The backtracking enables us to return to previous solution states in the search process with the expectation of obtaining better solutions. The EOI is used to transfer information accumulated in a beam to other beams to yield improved solutions. 相似文献
A series of seven-membered ditopic ring-expanded N-heterocyclic carbene (dre-NHC) precursors, bearing sterically demanding and electron-rich aryl groups, were synthesised in moderate yields via the reaction of 1,2,4,5-tetrakis(bromomethyl)benzene with the corresponding N,N′-diarylformamidines in the presence of K2CO3 in acetonitrile under an air atmosphere. All new compounds were characterised by HRMS, NMR spectroscopy, and microanalysis, as well as X-ray crystallography for compound 1c. The development of an efficient catalytic system for the Suzuki-Miyaura coupling reaction of aryl chlorides with various boronic acids was also investigated using the in situ generated dre-NHC ligands. 相似文献
Thin film CdIn2Te4/CdS solar cells were deposited onto the ITO-coated glass substrate by electron beam evaporation (e-beam) technique, and the the effect of annealing on their structural properties is studied. The annealing was performed under nitrogen atmosphere for 1 h. The manufactured solar cells were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray (EDAX) analysis. Crystallite size (D), inter-planer distance (d) and lattice constant (a) values were calculated for the thin film solar cell from XRD data. Annealed samples display well defined XRD patterns with three diffraction peaks. We observed increased peak intensity in the annealed films. EDAX analysis showed that only CdIn2Te4 is present in absorber layer and CdS is found in the window layer, but no impurity atoms are present the structure. It is observed that surface roughness of the annealed films incresed, according to SEM images. The I–V characteristics show that the current is increased for annealed thin films solar cells.
Oxalic acid adsorption from aqueous solution is studied in this work. Multi-walled carbon nanotubes (MWCNT) were used as an adsorbent. The investigated adsorption variables are equilibrium time, initial acid concentration, and temperature. The experimental results were presented using equilibrium isotherm and kinetic models. The used equilibrium models are Langmuir, Freundlich, and Temkin adsorption isotherms. And the kinetic models are Elovich, Lagergren pseudo-first-order and pseudo-second-order kinetic models. The thermodynamics studies were carried out at three different temperatures: 278, 298, and 318 K. Langmuir isotherm was the best fitted equilibrium model for the experimental data. The all applied kinetic models fitted the data suitably. 相似文献
Furo[3,2‐c]pyran‐4‐ones, which possess a natural‐product skeleton, are synthesized via a simple, one‐pot, three‐component reaction of furan‐2,3‐diones with dialkyl acetylenedicarboxylates and Ph3P. 相似文献
The synthesis of new polyfluorinated dendrimeric metallophthalocyanines (M = Zn, Ni, Co) bearing 3,5-bis(2′,3′,4′,5′,6′-pentafluorobenzyloxy)benzyloxy moieties (2–4) was achieved by cyclotetramerization of phthalonitrile derivative 1 in the presence of zinc, nickel or cobalt salts in DMF. All the target phthalocyanines were separated by column chromatography and their spectroscopic, fluorescence and energy transfer properties, and aggregation behavior were investigated in different solvents and at different concentrations in chloroform. The compounds were characterized by Fourier transform-infrared, fluorine, proton and carbon nuclear magnetic resonance, mass, ultraviolet–visible and fluorescence spectral data. The phthalocyanines (2–4) were extremely soluble in various organic solvents, such as tetrahydrofuran, acetone and dichloromethane. 相似文献
Tannic acid, a naturally occurring plant polyphenol, is composed of a central glucose molecule derivatized at its hydroxyl groups with one or more galloyl residues. In the present paper, we examines the in vitro radical scavenging and antioxidant capacity of tannic acid by using different in vitro analytical methodologies such as 1,1-diphenyl-2-picryl-hydrazyl free radical (DPPH) scavenging, 2,2′-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid) (ABTS) radical scavenging activity, total antioxidant activity determination by ferric thiocyanate, total reducing ability determination using by Fe3+–Fe2+ transformation method, superoxide anion radical scavenging by riboflavin–methionine-illuminate system, hydrogen peroxide scavenging and ferrous ions (Fe2+) chelating activities. Also, butylated hydroxyanisole (BHA), butylated hydroxytoluene (BHT), α-tocopherol and trolox, a water-soluble analogue of tocopherol, were used as the reference antioxidant radical scavenger compounds.Tannic acid inhibited 97.7% lipid peroxidation of linoleic acid emulsion at 15 μg/mL concentration. On the other hand, the above mentioned standard antioxidants indicated an inhibition of 92.2%, 99.6%, 84.6% and 95.6% on peroxidation of linoleic acid emulsion at 45 μg/mL concentration, respectively. In addition, tannic acid had an effective DPPH scavenging, ABTS+ radical scavenging, superoxide anion radical scavenging, hydrogen peroxide scavenging, Fe3+ reducing power and metal chelating on ferrous ions activities. Also, those various antioxidant activities were compared to BHA, BHT, α-tocopherol and trolox as references antioxidant compounds. The present study shows that tannic acid is the effective natural antioxidant component that can be used as food preservative agents or nutraceuticals. 相似文献
We propose the real time optical reconstruction of a three-dimensional (3D) object from a digitally recorded hologram. Phase distribution of the recorded hologram is numerically calculated by 1-dimensional Continuous Wavelet Transform (1D-CWT) for digital reconstruction with phase only information. Also, the phase distribution of 1D-CWT transferred to the spatial light modulator (SLM) is used to obtain optically reconstructed image. It is observed that an efficient real-time analysis can be achieved, if phase of 1D-CWT is used. In the same time, optically reconstructed 3D objects obtained by only phase information are about three times brighter than bleached hologram intensity's. So the minimum power loss can be obtained. Numerical and experimental results are presented. 相似文献