全文获取类型
收费全文 | 1026篇 |
免费 | 59篇 |
国内免费 | 8篇 |
专业分类
化学 | 829篇 |
晶体学 | 14篇 |
力学 | 8篇 |
数学 | 85篇 |
物理学 | 157篇 |
出版年
2023年 | 10篇 |
2022年 | 7篇 |
2021年 | 10篇 |
2020年 | 24篇 |
2019年 | 27篇 |
2018年 | 12篇 |
2017年 | 13篇 |
2016年 | 36篇 |
2015年 | 28篇 |
2014年 | 22篇 |
2013年 | 57篇 |
2012年 | 50篇 |
2011年 | 62篇 |
2010年 | 36篇 |
2009年 | 45篇 |
2008年 | 78篇 |
2007年 | 63篇 |
2006年 | 69篇 |
2005年 | 66篇 |
2004年 | 53篇 |
2003年 | 46篇 |
2002年 | 42篇 |
2001年 | 15篇 |
2000年 | 13篇 |
1999年 | 9篇 |
1998年 | 11篇 |
1997年 | 4篇 |
1996年 | 8篇 |
1995年 | 12篇 |
1994年 | 5篇 |
1993年 | 9篇 |
1992年 | 7篇 |
1991年 | 9篇 |
1990年 | 6篇 |
1988年 | 10篇 |
1987年 | 7篇 |
1986年 | 4篇 |
1985年 | 8篇 |
1984年 | 15篇 |
1983年 | 8篇 |
1982年 | 15篇 |
1981年 | 17篇 |
1980年 | 6篇 |
1979年 | 4篇 |
1978年 | 5篇 |
1977年 | 4篇 |
1974年 | 3篇 |
1973年 | 5篇 |
1972年 | 4篇 |
1969年 | 3篇 |
排序方式: 共有1093条查询结果,搜索用时 15 毫秒
91.
Doppler-broadened atomic and molecular spectra were observed with a one octave tunable, continuous-wave, doubly resonant, monolithic optical parametric oscillator (OPO) using 5% MgO-doped LiNbO3 as a non-linear crystal with a birefringent phase-matching configuration. By tuning the frequency of a pump laser, longitudinal mode selection over 20 successive modes, corresponding to a 60 GHz span, was possible, owing to the simple structure of the monolithic OPO. Continuous frequency tuning was achieved using an external waveguide-type electrooptic phase modulator (EOM). By changing the modulation frequency of the EOM, frequency tuning of the optical sidebands over 12 GHz was possible, which is larger than the one free spectral range of the monolithic cavity of 3 GHz. We could observe the Cs-D1 (894 nm), Cs-D2 (852 nm), Rb-D1 (795 nm), acetylene R9 (1520 nm) and P9 (1530 nm) transitions with the single monolithic OPO. 相似文献
92.
93.
Toshiaki Shirakawa Hajime Ichimura Isao Ikemoto 《Molecular Crystals and Liquid Crystals》2013,570(1-4):101-107
Pressure-volume isotherms for 4-(trans-4-butylcylohexyl)benzonitrile were measured by means of piston-cylinder method. This substance has a monotropic nematic phase at atmospheric pressure. But over a pressure, the nature of isotropic to nematic phase transition changed from monotropic to enantiotropic phase transition. It is the first observation in P-V-T experiments that the monotropic isotropic-nematic transition changes enantiotropic under pressure. 相似文献
94.
Hajime Kameo Yumiko Nakajima Hiroharu Suzuki 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2008,120(52):10313-10316
95.
96.
Koji Nuida Satoshi Fujitsu Manabu Hagiwara Takashi Kitagawa Hajime Watanabe Kazuto Ogawa Hideki Imai 《Designs, Codes and Cryptography》2009,52(3):339-362
It has been proven that the code lengths of Tardos’s collusion-secure fingerprinting codes are of theoretically minimal order
with respect to the number of adversarial users (pirates). However, the code lengths can be further reduced as some preceding
studies have revealed. In this article we improve a recent discrete variant of Tardos’s codes, and give a security proof of
our codes under an assumption weaker than the original Marking Assumption. Our analysis shows that our codes have significantly
shorter lengths than Tardos’s codes. For example, when c = 8, our code length is about 4.94% of Tardos’s code in a practical setting and about 4.62% in a certain limit case. Our
code lengths for large c are asymptotically about 5.35% of Tardos’s codes.
A part of this work was presented at 17th Applied Algebra, Algebraic Algorithms, and Error Correcting Codes (AAECC-17), Bangalore,
India, December 16–20, 2007. 相似文献
97.
98.
Aubert T Ledneva AY Grasset F Kimoto K Naumov NG Molard Y Saito N Haneda H Cordier S 《Langmuir : the ACS journal of surfaces and colloids》2010,26(23):18512-18518
Metal atom clusters constitute very promising candidates as luminophores for applications in biotechnology because they are nanosized entities offering robust luminescence in the near-infrared field (NIR). However, they cannot be used as prepared for biological applications because of potential toxic effects and quenching of the clusters' luminescence in aqueous media, and they therefore need to be dispersed in a biocompatible matrix. We describe herein the encapsulation of octahedral rhenium clusters, denoted as A(4)[Re(6)Q(8)L(6)] (A = Cs or K, Q = S or Se, and L = OH or CN), in silica nanoparticles by a water-in-oil microemulsion process, paying particular attention to the clusters' stability. The obtained A(4)[Re(6)Q(8)L(6)]@SiO(2) nanoparticles are 30 nm in size with good monodispersity and a perfectly spherical shape, as shown by scanning electron microscopy (SEM). The presence of cluster units inside the silica matrix was evidenced by scanning transmission electron microscopy in annular dark-field mode (ADF-STEM). From the point of view of their optical properties, the A(4)[Re(6)Q(8)L(6)]@SiO(2) nanoparticles show red and NIR emission under UV excitation, even when dispersed in water. The evolution of the structural and luminescence properties of clusters before and after encapsulation was followed by Raman and photoluminescence spectroscopy. 相似文献
99.
Diastereoselectivity in the photoallylation and photoreduction of 1,1-dicyano-2-methyl-3-phenyl-1-butene by allyltrimethylsilane
in the presence of phenanthrene was dependent on the structures and stoichiometry of the added carboxylic acids. Diastereoselectivity
increased up to 72% by the addition of equimolar amount of l-lactic acid based on the alkene. 相似文献
100.
Cyclic enaminones were synthesized in high yields from amino acids in two steps via Wolff rearrangement. The cyclization represents a rare 6-exo-dig cyclization involving a ketene as an electrophile. No racemization was observed during this reaction. 相似文献