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961.
Qing Wang Bo Liu Yangyang Xia Yonghui Zheng Ruru Huo Min Zhu Sannian Song Shilong Lv Yan Cheng Zhitang Song Songlin Feng 《固体物理学:研究快报》2015,9(8):470-474
Phase‐change memory (PCM) is regarded as one of the most promising candidates for the next‐generation nonvolatile memory. Its storage medium, phase‐change material, has attracted continuous exploration. Along the traditional GeTe–Sb2Te3 tie line, the binary compound Sb2Te3 is a high‐speed phase‐change material matrix. However, the low crystallization temperature prevents its practical application in PCM. Here, Cr is doped into Sb2Te3, called Cr–Sb2Te3 (CST), to improve the thermal stability. We find that, with increase of the Cr concentration, grains are obviously refined. However, all the CST films exhibit a single hexagonal phase as Sb2Te3 without phase separation. Also, the Cr helps to inhibit oxidation of Sb atoms. For the selected film CST_10.5, the resistance ratio between amorphous and crystalline states is more than two orders of magnitude; the temperature for 10‐year data retention is 120.8 °C, which indicates better thermal stability than GST and pure Sb2Te3. PCM cells based on CST_10.5 present small threshold current/voltage (4 μA/0.67 V). In addition, the cell can be operated by a low SET/RESET voltage pulse (1.1 V/2.4 V) with 50 ns width. Thus, Cr–Sb2Te3 with suitable composition is a promising novel phase‐change material used for PCM with high speed and good thermal stability performances. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
962.
Yan Guan Dayu Zhou Jin Xu Xiaohua Liu Fei Cao Xianlin Dong Johannes Müller Tony Schenk Uwe Schroeder 《固体物理学:研究快报》2015,9(10):589-593
A wealth of studies have confirmed that the low‐field hysteresis behaviour of ferroelectric bulk ceramics and thin films can be described using Rayleigh relations, and irreversible domain wall motion across the array of pining defects has been commonly accepted as the underlying micro‐mechanism. Recently, HfO2 thin films incorporated with various dopants were reported to show pronounced ferroelectricity, however, their microscopic domain structure remains unclear till now. In this work, the effects of the applied electric field amplitude, frequency and temperature on the sub‐coercive polarization reversal properties were investigated for 10 nm thick Si‐doped HfO2 thin films. The applicability of the Rayleigh law to ultra‐thin ferroelectric films was first confirmed, indicating the existence of a multi‐domain structure. Since the grain size is about 20–30 nm, a direct observation of domain walls within the grains is rather challenging and this indirect method is a feasible approach to resolve the domain structure. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
963.
Back contact–absorber interface modification by inserting carbon intermediate layer and conversion efficiency improvement in Cu2ZnSn(S,Se)4 solar cell 下载免费PDF全文
Fangqin Zeng Kaiwen Sun Li Gong Liangxing Jiang Fangyang Liu Yanqing Lai Jie Li 《固体物理学:研究快报》2015,9(12):687-691
Carbon layers have been employed as intermediate layers between Mo back contact and Cu2ZnSn(S1–xSex)4(CZTSSe) absorber film prepared by sol–gel and post‐selenization method. Carbon layers with appropriate thickness can significantly inhibit the formation of MoSe2 and voids at bottom region of the absorber, and therefore reduce the series resistance remarkably. The conversion efficiency can be boosted by the introducing of the carbon layer from 6.20% to 7.24% by enhancement in short current density, fill factor and open voltage in comparison to the reference sample without carbon layer. However, excess thickness of carbon layer will worse device performance due to the deteriorated absorber crystallinity. In addition, the time‐resolved photoluminescence analysis shows that inserting the carbon layer with suitable thickness does not introduce recombination and lower minority lifetime. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
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DFT study the interaction of β‐cyclodextrin with benzyl azide and phenyl acetylene in synthesis of 1,2,3‐triazoles 下载免费PDF全文
The phenyl acetylene and benzyl azide cycloaddition reaction in water in the presence of β‐cyclodextrin (β‐CD) as a phase transfer catalyst (PTC) can get a better yield in a shorter time. The interaction between β‐CD and phenyl acetylene or benzyl azide plays an important role in this reaction. This paper studies the complexes of β‐CD with phenyl acetylene and benzyl azide using density functional theory (DFT) method. In order to find out the orientations of guests in the cavity of β‐CD, binding energy and deformation energy are investigated, and the calculated results are confirmed by 1H nuclear magnetic resonance (1HNMR). The data from single point energy indicate that the inclusion complexes can improve the solubilities of phenyl acetylene and benzyl azide in water. The 13C and 15N spectra show that the most obvious variation concentrates on C6 and C8 of phenyl acetylene and N15 of benzyl azide in complexes. Mulliken charge and frontier orbital are employed for revealing the charge distribution. The effect of β‐CD is discussed in terms of the calculated parameters. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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Aiping Xi Zhongxin Xu Fengli Liu Yanli Xu Lijun Yu Jie Liu 《Russian Journal of Physical Chemistry B, Focus on Physics》2015,9(6):946-951
The aim of this present work is to investigate the interaction between doxorubicin and bovine serum albumin (BSA) in simulated physiological conditions by spectroscopic methods to reveal potential toxic effects of the drug. The results reflected that doxorubicin made the fluorescence quenching of BSA through a static quenching procedure. The binding constants at 293, 298, and 303 K were obtained as 2.53 × 105, 8.13 × 104, and 3.59 × 104 M–1, respectively. There may be one binding site of doxorubicin on BSA. The thermodynamic parameters indicated that the interaction between doxorubicin and BSA was driven mainly by hydrogen bonding and electrostatic forces. Synchronous fluorescence spectra and circular dichroism (CD) results showed doxorubicin binding slightly changed the conformation of BSA with secondary structural content changes. Förster resonance energy transfer (FRET) study revealed high possibility of energy transfer with doxorubicin-Trp-212 distance of 3.48 nm. The results of the present study may provide valuable information for studying the distribution, toxicological and pharmacological mechanisms of doxorubicin in vivo. 相似文献