甲基环己烷在9∽15.5 eV能量区的真空紫外光电离研究

利用具有同步辐射源的反射式飞行时间质谱仪,研究甲基环己烷的真空紫外光电离和光解离. 观测到母体离子C₇H₁₄⁺和碎片离子C₇H₁₃⁺,C₆H₁₁⁺,C₆H₁₀⁺,C₅H₁₀⁺,C₅H₉⁺,C₄H₈⁺,C₄H₇⁺和C₃H₅⁺的光电离效率曲线. 测定甲基环己烷的电离能为9.80±0.03 eV,通过光电离效率曲线确定其碎片离子的出现势. 在B3LYP/6-31G(d)水平上对过渡态、中间体和产物离子的优化结构进行表征,并使用G3B3方法计算其能量. 提出主要碎片离子的形成通道. 分子内氢迁移和碳开环是甲基环己烷裂解途径中最重要的过程.     

SF-环的内射性

研究了SF-环与P-内射环的关系,构造了SF-环成为P-内射环的一系列条件.证明了SF-环R只要满足其中之一:R的每个极大左理想是有限生成的;特殊右零化子的降链条件;对R的每个极大左理想M,l(M)在R中是本质的,那么R就是P-内射环.在此基础上,利用一定条件下SF-环的P-内射性,发展了SF-环的若干新结果,这些结果部分地拓展了有关文献中的结果.     

A broadband self-powered UV photodetector of aβ-Ga2O3/γ-CuI p–n junction

The symmetric Ti/Au bi-layer point electrodes have been successfully patterned on theβ-Ga;O;films which are prepared by metal–organic chemical vapor deposition(MOCVD)and theγ-Cu I films which are prepared by spin-coating.The fabricated heterojunction has a large open circuit voltage(Voc)of 0.69 V,desired for achieving self-powered operation of a photodetector.Irradiated by 254-nm ultraviolet(UV)light,when the bias voltage is-5 V,the dark current(Idark)of the device is 0.47 p A,the photocurrent(Iphoto)is-50.93 n A,and the photo-to-dark current ratio(Iphoto/Idark)reaches about 1.08×10;.The device has a stable and fast response speed in different wavelengths,the rise time(τr)and decay time(τd)are 0.762 s and 1.741 s under 254-nm UV light illumination,respectively.While theτr andτd are 10.709 s and7.241 s under 365-nm UV light illumination,respectively.The time-dependent(I–t)response(photocurrent in the order of10-10 A)can be clearly distinguished at a small light intensity of 1μW·cm;.The internal physical mechanism affecting the device performances is discussed by the band diagram and charge carrier transfer theory.     

气候对安徽中药材产业经济影响分析——基于经济气候模型

通过考虑气候和经济社会因素,将气候因素与函数综合考虑并进行分析,构建“经济气候”模型,分析并得出气候因素对安徽省中药材产业影响程度,利用所构建BP神经网络模型,分析数据,对气象因素对中药材产业的影响结果进行预测。通过分析安徽省气候变化的特点与方向,确定气候因素对中药材产业的影响程度,为中药材产业发展提供一定的数据分析支撑,为有针对性的管理中药材产业提供方法与数据基础,同时对降低严重气象灾害对中药材生产带来的负面作用具有一定的理论与实践意义。     

Scholte波与含泥沙两相流介质属性关系的分析及仿真验证

基于四种超声悬浮液模型Urick, Urick-Ament, HT, Mcclements分析了Scholte波在两相流体与多孔介质固体界面处的传播特性. 结合各模型的复波数表达式建立含泥沙流体-多孔介质固体界面波特征方程, 分析了Scholte波速与两相流体积含量、粒径等介质属性的关系. 通过仿真实验获得界面波信号, 运用时延估计获得Scholte波速与泥沙含量、粒径的关系, 发现所得的波速与Urick-Ament和HT理论有相对好的一致性. 关键词： Scholte波 两相流体 多孔介质 泥沙含量     

Reactive Compatibilization of Poly(Butylene Terephthalate)/Acrylonitrile-Styrene-Acrylate Blends by Epoxy Resin: Morphology and Mechanical Properties

The effect on the notched Izod impact strength of poly(butylene terephthalate) (PBT) by blending it with acrylonitrile-styrene-acrylate (ASA) was examined. Epoxy resin (ER) was demonstrated to be an efficient compatibilizer for the partially compatible blends of PBT/ASA. It requires only a very small amount of ER to improve the toughness of the PBT/ASA blends drastically. Furthermore, there exists an optimum proportion of ER added to achieve maximum notched Izod impact strength. Transmission electron microscopy (TEM) observation suggests that the ER in the PBT/ASA/ER blends suppressing the tendency of coalescence of ASA, leading to better dispersion of the ASA particles. Field emission scanning electron microscopy (FESEM) shows that ER enhances the phase dispersion and the interfacial adhesion between the PBT and ASA phases, it improves the compatibility between PBT and ASA. The compositions in the interphase was continuous, which results in multiphase composites with a graded interphase. It is suggested that enhanced interphase adhesion was necessary to obtain improved dispersion, fine phase morphology, and better toughness.     

生物矿化法制备HgS/聚氨酯复合薄膜及其对Ba2+的传感性能

通过生物矿化法制备出HgS/聚氨酯纳米复合材料并用FTIR、SEM等对材料进行了表征. 研究发现聚氨酯分子可以控制HgS的成核和晶体生长. 聚氨酯的量子限域效应已通过紫外-可见光谱证实,在约291 nm处有明显的特征吸收峰. 荧光性能研究结果表明HgS/聚氨酯纳米粒子复合薄膜对Ba²⁺的存在十分敏感,少量的Ba²⁺会使荧光强度明显上升,水中常见离子几乎对此没有影响.     

钙钛矿结构中的简谐子软模

利用复合空间型方法,在自由边界条件下解出了钙钛矿结构有限尺寸晶体的简谐振动方程.计算结果给出了收敛的简谐子谱分布,并发现了许多简谐子软模.用这些软模花样说明了钛酸钡晶体冷却时发生具有a畴和c畴结构的铁电相变.理论表明铁电相变过程涉及屏蔽电荷的激发及其在界面的缓慢扩散,以最后得出各个电畴内部的均匀自发极化 关键词： 晶格动力学 简谐子 软模 钛酸钡     

A novel acoustic emission beamforming method with two uniform linear arrays on plate-like structures

A novel acoustic emission (AE) source localization approach based on beamforming with two uniform linear arrays is proposed, which can localize acoustic sources without accurate velocity, and is particularly suited for plate-like structures. Two uniform line arrays are distributed in the x-axis direction and y-axis direction. The accurate x and y coordinates of AE source are determined by the two arrays respectively. To verify the location accuracy and effectiveness of the proposed approach, the simulation of AE wave propagation in a steel plate based on the finite element method and the pencil-lead-broken experiment are conducted, and the AE signals obtained from the simulations and experiments are analyzed using the proposed method. Moreover, to study the ability of the proposed method more comprehensive, a plate of carbon fiber reinforced plastics is taken for the pencil-lead-broken test, and the AE source localization is also realized. The results indicate that the two uniform linear arrays can localize different sources accurately in two directions even though the localizing velocity is deviated from the real velocity, which demonstrates the effectiveness of the proposed method in AE source localization for plate-like structures.     

Upgrade of beamline BL08B at Taiwan Light Source from a photon‐BPM to a double‐grating SGM beamline

During the last 20 years, beamline BL08B has been upgraded step by step from a photon beam‐position monitor (BPM) to a testing beamline and a single‐grating beamline that enables experiments to record X‐ray photo‐emission spectra (XPS) and X‐ray absorption spectra (XAS) for research in solar physics, organic semiconductor materials and spinel oxides, with soft X‐ray photon energies in the range 300–1000 eV. Demands for photon energy to extend to the extreme ultraviolet region for applications in nano‐fabrication and topological thin films are increasing. The basic spherical‐grating monochromator beamline was again upgraded by adding a second grating that delivers photons of energy from 80 to 420 eV. Four end‐stations were designed for experiments with XPS, XAS, interstellar photoprocess systems (IPS) and extreme‐ultraviolet lithography (EUVL) in the scheduled beam time. The data from these experiments show a large count rate in core levels probed and excellent statistics on background normalization in the L‐edge adsorption spectrum.