NMR Study on Polymer-Solvent Interactions during Temperature-Induced Phase Separation in Aqueous Polymer Solutions

Some possibilities of NMR spectroscopy (mainly spin-spin relaxation) in investigations of hydration and other polymer-solvent interactions during the temperature-induced phase separation in aqueous polymer solutions are described. A certain portion of water molecules bound in phase-separated mesoglobules was revealed. The residence time of the bound HDO for poly(vinyl methyl ether) (PVME)/D₂O solution (c = 6 wt%) is 1.2 ms. With time a slow release of originally bound water from the respective mesoglobules was observed. For highly concentrated PVME/D₂O solutions (c = 20–60 wt%), the residence time of bound HDO ≫ 2.7 ms and fractions of bound water unchanged even for 70 h were found. A similar behaviour as described above for water (HDO) was also found for EtOH molecules in PVME/D₂O/EtOH solutions.     

Invariant Mean—Value Property and M—Harmonicity in the Unit Ball of R^n

In 1993,Ahern,Flores and Rudin showed that,if f is integrable over the unit ball BC^n of C^n and satisfies∫BC^nfoφdv=f（φ（0)) for every φ∈Aut(BC^n),then f is M-harmonic if and only if n≤11.The present paper is about an analogous question in the context of the unit ball Bn of R^n as well as in the weighted setting.     

离子交换富集-导数火焰原子吸收法测定自来水中Cu,Fe和Zn

本文研究了用 2 0 1× 7阳离子交换树脂对自来水中的微量元素进行交换富集 ,采用微量脉冲进样 导数火焰原子吸收法测定富集后溶液中的Cu ,Fe和Zn ,该方法灵敏度分别为 0 2 9,0 5 9和 0 0 6 μg·L- 1 ,精密度分别为 4 2 8% ,1 95 %和 2 2 8% ,检测限分别为 1 2 8,5 85和 0 6 8μg·L- 1 ,回收率分别为 91 13% ,10 1 34%和99 84 % ,本方法大大减少了需样量 ,简便快速 ,灵敏度高。     

A study of Ga layers on Si(1 0 0)-(2 × 1) by SR-PES: Influence of adsorbed water

Results for deposition and thermal annealing of gallium on the Si(1 0 0)-(2 × 1) surface achieved by synchrotron radiation photoelectron spectroscopy (SR-PES) and low energy electron diffraction (LEED) are presented. In addition to deposition of Ga on a clean surface, the influence of water adsorption on the arrangement of gallium atoms was also studied. The results on Ga deposition at a higher temperature (490 °C) are consistent with a Ga ad-dimer model showing equivalent bond arrangement of all Ga atoms for coverages up to 0.5 ML. The deposition onto a surface with adsorbed water at room temperature led to a disordered gallium growth. In this case gallium atoms bind to silicon dimers already binding fragments of adsorbed water. A subsequent annealing of these layers leads to a surface structure similar to the Ga-(2 × 2), however, it is less ordered, probably due to the presence of silicon oxides formed from water fragments.     

A novel reconfigurable radio-over-fiber system based on flexible optical devices

In this paper, a reconfigurable Radio over Fiber system based on optical switches, optical multimode interference power splitter and tunable optical filters is designed, which can achieve quadrature phase shift keying wireless modulation in optical domain and switch carrier frequency between 30 and 60 GHz. The scheme can make good use of bandwidth resource and realize signal transmission in fiber within 10 km.     

Top介子在高能正负电子对撞机上的产生

在顶色辅助的人工色(TC2)模型框架下,研究了中性top介子和顶夸克的联合产生过程e+e–→ttπ0t.结果显示此过程的产生截面比标准模型和最小超对称标准模型中e+e–→ttH过程的产生截面都要大.在TC2模型合理的参数空间内,其产生截面可达20fb.通过此过程可在将来的对撞机上探测中性top介子.     

预测气吹精密播种机排种质量的一种简易方法

通过对气吹式精密播种机田间试验资料的相关分析，发现合格指数Ａ与｜Ｄ－Ｍ｜（重播指数与漏播指数之差的绝对值）之间里极显著负相关（ｒ＝－０．９３１２）。在对数据作进一步回归分析的基础上，本文建立了一套“由排种粒数预测排种质量”的方法。     

Numerical Analysis of Electromagnetic Fields in Multiscale Model

Modeling technique for electromagnetic fields excited by antennas is an important topic in computational electromagnetics, which is concerned with the numerical solution of Maxwell's equations. In this paper, a novel hybrid technique that combines method of moments(MoM) with finite-difference time-domain(FDTD) method is presented to handle the problem. This approach employed Huygen's principle to realize the hybridization of the two classical numerical algorithms. For wideband electromagnetic data, the interpolation scheme is used in the MoM based on the dyadic Green's function. On the other hand, with the help of equivalence principle, the scattered electric and magnetic fields on the Huygen's surface calculated by MoM are taken as the sources for FDTD. Therefore, the electromagnetic fields in the environment can be obtained by employing finite-difference time-domain method. Finally, numerical results show the validity of the proposed technique by analyzing two canonical samples.     

Charge injection and photooxidation of single conjugated polymer molecules

The complex, coupled mechanisms of charge transfer and oxidative damage in organic electronic devices (such as organic light-emitting diodes (OLED), solar cells, etc.) have been elucidated by a new technique that combines single-molecule spectroscopy with charge injection from a metal electrode. The experiments employed a sandwich device architecture (Au/TPD/MEH-PPV:PMMA/SiO2/ITO), essentially a modified OLED with a charge-blocking layer (SiO2) to suppress charge injection at the ITO electrode. The fluorescence (photoluminescence) of isolated MEH-PPV conjugated polymer molecules imbedded in the device was observed to exhibit diverse time- and electrical bias-dependent effects. These include: (i) fluorescence quenching due to interactions between MEH-PPV and holes in the TPD hole-transport layer; (ii) fluorescence quenching, or "photobleaching", due to chemical defects at MEH-PPV generated by photooxidation; and (iii) a novel process, reductive "repair" of the oxidative chemical defects by externally injected carriers. These results demonstrate a very different mechanism for photobleaching of organic conjugated materials than is generally assumed to operate and, furthermore, suggest an intimate relationship among photobleaching, charge transport, and persistent photoconductivity in organic materials.     

侧面预电离氟化氪激光器研制

采用侧面紫外火花隙自动预电离代替小极上小孔预电离，使放电泵浦氟化氪激光器的主放电均匀性大为改善。输出激光能量由１４０ｍＪ提高到２５０ｍＪ，增益区光能密度为２．３Ｊ／１，同时电极寿命和气体寿命也大为提高。