MoO2/C共包覆Si/石墨复合锂离子电池负极材料的研究

采用溶胶-凝胶法, 用二氧化钼(MoO₂)和C共同包覆Si/石墨粒子制备了Si/石墨/MoO₂/C锂离子电池负极材料. 利用X射线衍射(XRD)、 扫描电子显微镜(SEM)、 透射电子显微镜(TEM)、 循环伏安(CV)和电化学阻抗(EIS)等分析了材料的形貌和性质. 结果表明, MoO₂/C的共包覆在缓解材料体积膨胀的同时提高了材料的电子和离子电导率, 进而提高了材料的电化学性能. 复合材料的首次充电比容量为2494 mA·h/g, 首次库仑效率为72%, 经过100次循环后比容量为636.6 mA·h/g.     

Temperature control of spin wave propagation over 100 μm distance in 100 nm-thick YIG film

The spin wave propagating along a film of 100 nm-thick yttrium iron garnet is studied with temperature control. Using a vector network analyzer, temperature dependence of spin wave transmission is measured. We observe a clear resonance frequency shift of 210 MHz with temperature change of 40 K. This can be explained by the dispersion variation of the temperature. These results enable a complete pass or forbidden spin wave propagation in a certain frequency window with temperature control which might lead to application of spin wave filters.     

基于不同HPLC法测定毛冬青植物不同部位各成分比较

采用ELSD-HPLC、UV-HPLC及薄层鉴别法,对毛冬青药材其根、茎、细枝、叶的成分进行对比研究。试验结果显示,毛冬青植物茎、细枝、叶脂溶性成分与根的相似度分别为100%、75%、75%;茎、细枝水溶性成分与根的相似度均为100%。因此认为从化学成分上看,毛冬青药用部位可以从根扩大至根茎或茎。更多还原     

光信息与光电子技术实验室建设的思考

本文简要介绍了天津工业大学光信息与光电子技术实验室的现状,并对实验室在"十一五"期间的建设思路与目标以及建设内容等进行了全面的介绍.     

Shaft runout inspection by a fiber optic displacement sensor

A reflective fiber optic displacement sensor has been developed and calibrated to gauge form and axis position of shafts during rotation. A technique has been implemented to determine the deviation of the actual shaft form from its nominal circular cross section (the off-round error) and the departure of the rotation axis from the geometric axis (the eccentric error). The sensor is simple, has acceptable accuracy for applications to mechanical engineering, is capable of monitoring shafts during rotation, and has potential for gauging parts on the production line.     

高效液相色谱法测定葛根芩连片中的葛根素

建立高效液相色谱测定葛根芩连片中葛根素含量的方法。以体积分数50%的甲醇为提取液对样品超声提取20 min,采用DiamonsilTMC18(250 mm×4.6 mm,5μm)色谱柱,以甲醇–乙腈–水(体积比8∶12∶80)为流动相,流速为1.0 mL/min,检测波长为250 nm,柱温为30.0℃,进样量体积10μL。在最佳实验条件下,葛根素与其它物质能完全分离,葛根素的质量浓度在5.43~543.2μg/mL范围内与色谱峰面积呈良好的线性,线性相关系数r=0.999 9,方法检出限为3.50μg/mL(S/N=3)。方法加标回收率为100.0%,测定结果的相对标准偏差为1.6%(n=6)。该方法简单、快速、重现性好,适用于葛根芩连片中葛根素的测定。     

Synthesis of beta- and gamma-carbolines by the palladium/copper-catalyzed coupling and cyclization of terminal acetylenes

A variety of 3-substituted beta- and gamma-carbolines have been synthesized from N-substituted 3-iodoindole-2-carboxaldehydes and 2-bromoindole-3-carboxaldehydes, respectively. The coupling of these aldehydes with various terminal acetylenes with PdCl(2)(PPh(3))(2)/CuI as the catalyst readily affords the corresponding alkynylindole carboxaldehydes, which have subsequently been converted to the corresponding tert-butylimines and cyclized to beta- and gamma-carbolines by either copper-catalyzed or thermal processes.     

Towards Unveiling the Exact Molecular Structure of Amorphous Red Phosphorus by Single‐Molecule Studies

Since the discovery of amorphous red phosphorus (a‐red P) in 1847, many possible structures have been proposed. However, the exact molecular structure has not yet been determined because of its amorphous nature. Herein several methods are used to investigate basic properties of a‐red P. Data from scanning tunneling microscopy (STM) and gel permeation chromatography (GPC) confirm that a‐red P is a linear inorganic polymer with a broad molecular weight distribution. The theoretical single‐molecule elasticities of the possible a‐red P structures are obtained by quantum mechanical (QM) calculations. The experimental single‐molecule elasticity of a‐red P measured by single‐molecule AFM matches with the theoretical result of the zig‐zag ladder structure, indicating that a‐red P may adopt this structure. Although this conclusion needs further validation, this fundamental study represents progress towards solving the structure of a‐red P. It is expected that the strategy utilized in this work can be applied to study other inorganic polymers.     

HAMILTON-JACOBI-BELLMAN方程的混合元方法

0　引　　言考虑下列随机微分方程 :ｄＸｔｄｔ =σ(Ｘｔ,αｔ) ζｔ+ｂ(Ｘｔ,αｔ)　ｔ≥ 0 ( 1 .1ａ)　　　　Ｘ0 =ｘ ∈ＲＮ ( 1 .1ｂ)　　此处 ,σ和ｂ分别是定义在ＲＮ×Ａ上的矩阵值和向量值函数 ,Ａ是给定的可分空间 ,αｔ值位于Ａ中的随机过程 更严格地 ,方程 ( 1 .1ａ)可写成下列形式 :Ｘｔ =ｘ + ∫ｔ0 σ(Ｘｓ,αｓ)ｄＢｓ+ ∫ｔ0 ｂ(Ｘｓ,αｓ)ｄｓ　ｔ≥ 0 ( 1 .2 )此外 ,Ｂｔ 是ｍ 维Ｂｒｏｗｎ运动 ,使得 :Ｅ(Ｂｔ) =0 ,Ｅ(Ｂ2 ｔ) =ｔ;∫ｔ0 σ(Ｘｓ,αｓ)ｄＢｓ 是随机积分 我们知道 ,σ ,ｂ若足够光滑 ,则保证了对每一…     

黏土中爆炸成坑地冲击耦合效应实验研究

为获得黏土中爆炸成坑体积与耦合地冲击能量的关系,采用10.5 g TNT厘米级球形炸药球作为爆炸源,在$varnothing $1500 mm×1490 mm分层式爆炸装置中开展了变埋深条件下的爆炸实验,利用3D扫描设备记录不同埋深下弹坑的真实体积,并通过动态土压力传感器测得地冲击传播衰减规律。实验结果表明：随埋深增大,耦合至黏土中的有效地冲击能量急剧增大,装药中心下方的有效弹坑体积与耦合至黏土中的有效地冲击能量基本呈正比关系,当装药比例埋深与封闭爆炸条件下爆炸空腔半径相当时,耦合至黏土中的有效地冲击能量基本达到饱和。结合实验结果给出了黏土中爆炸耦合地冲击能量分配随装药比例埋深的变化规律,建立了地下爆炸等效封闭当量计算方法,为地下工程抗爆设计提供了理论依据。