ZnO/ZnSe复合纳米结构的制备及可见光光催化性能

通过热水解法, 以氧化锌为模板, 成功制备出形貌均一的ZnO/ZnSe复合纳米结构. 为了对比不同O/Se比对光催化性能的影响, 保持其它反应参数不变, 调节还原剂水合肼的用量, 得到不同硒化程度的ZnO/ZnSe复合纳米结构. 采用场发射扫描电子显微镜、 X射线衍射仪和透射电子显微镜对样品的形貌及结构进行了表征, 通过测试该复合结构对亚甲基蓝的可见光催化降解评估了其光催化效率. 结果表明, 与纯ZnO比, ZnO/ZnSe复合结构在可见光区域和紫外光区域的光吸收范围变宽, 显示出较高的光催化效率. 原因在于ZnSe导带上的电子在扩散势能的作用下迁移到ZnO的导带上, 而空穴仍保留在ZnSe价带, 这样有助于光生电子和空穴对的分离, 降低其复合机率, 从而提高ZnO的光催化效率.     

基于角系数跟踪反射能量研究太空中空心圆柱体温度分布

利用角系数跟踪反射能量求得辐射传递因子,探讨太空中太阳入射下、热控涂层对空心圆柱体温度分布的影响.使用有限差分法离散圆柱坐标系下三维稳态导热方程,考虑辐射-导热边界条件,用Patankar线性化方法将边界条件线性化,用点迭代法来求解名义上的线性化方程组从而得到空心圆柱体的温度分布.热控涂层表面的辐射特性用一组矩形谱带来近似.本文的研究方法对太空航天器件温度分布的精确数值求解具有参考价值.     

Novel 5‐Methyl‐2‐[(un)substituted phenyl]‐4‐{4,5‐dihydro‐ 3‐[(un)substituted phenyl]‐5‐(1,2,3,4‐tetrahydroisoquinoline‐2‐yl)pyrazol‐1‐yl}‐oxazole Derivatives: Synthesis and Anticancer Activity

Eleven novel 5‐methyl‐2‐[(un)substituted phenyl]‐4‐{4,5‐dihydro‐3‐[(un)substituted phenyl]‐5‐(1,2,3,4‐tetrahydroisoquinoline‐2‐yl)pyrazol‐1‐yl}‐oxazole derivatives were synthesized and characterized by elemental analysis, ESI‐MS, ¹H NMR and ¹³C NMR. All of the compounds have been screened for their antiproliferative activities against PC‐3 cell (human prostate cancer) and A431 cell (human epidermoid carcinoma cancer) lines in vitro. The results revealed that compounds 4g , 4j and 4k exhibited the strong inhibitory activities against the PC‐3 cell lines (with IC₅₀ values of 2.8±0.11, 3.1±0.10 and 3.0±0.06 μg/mL, respectively).     

Synthesis, crystal structure and in vitro antibacterial activity of two novel silver(I) complexes

Two silver(I) complexes [Ag₂(dppm)₂(L¹)₂(CH₂Cl₂)₂] (1) and [Ag₄(dppm)₂(L²)₂(NO₃)₂] (2) have been prepared by the reactions of [Ag₂(dppm)₂(NO₃)₂] with HL¹ and HL² [dppm = bis(diphenylphosphino)methane, HL¹ = 2-(9H-carbazol-9-yl) acetic acid and HL² = (E)-3-(4-(9H-carbazole-9-yl) phenyl) acrylic acid], respectively. Both complexes have been structurally characterized by X-ray crystallography, confirming that 1 is a binuclear complex whereas 2 is a tetranuclear one. Both complexes were assayed for antibacterial activity against two Gram-positive bacterial strains (Bacillus subtilis ATCC 6633 and Staphylococcus aureus ATCC 6538) and two Gram-negative bacterial strains (Pseudomonas aeruginosa ATCC 13525 and Escherichia coli ATCC 35218) by MTT method. Complex 2 exhibited powerful antibacterial activities against B. subtilis ATCC 6633 with MIC of 0.78 μg/mL, which was superior to the positive controls penicillin G. On the basis of the biological results, structure-activity relationships were discussed.     

A novel sandwiched membrane as polymer electrolyte for application in lithium-ion battery

A novel kind of sandwiched polymer membrane was prepared, which consists of two outer layers of electrospun poly(vinyl difluoride) (PVDF) fibrous films and one inner layer of poly(methyl methacrylate) (PMMA) film. Its characteristics were investigated by scanning electron microscopy and X-ray diffraction. The membrane can easily absorb non-aqueous electrolyte to form gelled polymer electrolytes (GPEs). The resulting gelled polymer electrolytes had a high ionic conductivity up to 1.93 × 10⁻³ S cm⁻¹ at room temperature, and exhibited a high electrochemical stability potential of 4.5 V (vs. Li/Li⁺). It is of great potential application in polymer lithium-ion batteries.     

感应电压叠加器驱动阳极杆箍缩二极管型脉冲X射线源

 介绍了自行研制的用于闪光照相且基于感应电压叠加器和阳极杆箍缩二极管的X射线源的组成、结构和主要参数。输出电压3 MV的Marx发生器给阻抗7.8 Ω水介质脉冲形成线充电,产生脉宽约70 ns,电压约1 MV的高功率脉冲,经过峰化开关和预脉冲开关后分成3路馈入三级感应电压叠加器感应腔进行电压叠加,感应电压叠加器次级采用真空绝缘传输线,阻抗从40 Ω变成60 Ω,驱动阳极杆箍缩二极管,二极管阴极为石墨,阳极为直径1.2 mm的钨杆,石墨阴极产生的电子束在电流自磁场作用下发生箍缩,轰击阳极,产生小焦斑脉冲Ｘ射线。该装置在Marx充电电压为±35 kV时,二极管电压约2.0 MV,二极管电流约为50 kA,半高宽约80 ns;X射线半高宽约为40 ns,剂量约为28 mGy,焦斑约为0.95 mm。利用该X射线源拍摄到了炸药爆炸产生的层裂碎片不同飞行时间的图像。     

强脉冲γ射线能谱测量仪研制

研制出了一种用于强脉冲γ射线能谱测量的能谱仪,在感应电压叠加器实验平台上,测量了阳极杆箍缩二极管产生的强脉冲γ射线能谱。选择适合强脉冲γ射线测量的Si-PIN探测器阵列和铅过滤片作为测量系统,通过在能谱仪的前部放置不同厚度的铅衰减片,测量了感应电压叠加器的强脉冲γ射线的强度。理论计算了不同能量的光子经过不同厚度的铅衰减片以后在探测器阵列上的能量沉积,得到了探测器的灵敏度曲线。利用探测器上的理论计算的电荷量和实验波形的对应关系,求解了该加速器的能谱。光子的最高能量约为1.44 MeV,平均能量为0.68 MeV,其中能量在0.4~0.8 MeV范围内的光子数最多,占74.3%。     

Nickel‐Catalyzed 1,1‐Alkylboration of Electronically Unbiased Terminal Alkenes

An unprecedented nickel‐catalyzed 1,1‐alkylboration of electronically unbiased alkenes has been developed, providing straightforward access to secondary aliphatic boronic esters from readily available materials under very mild reaction conditions. The regioselectivity of this reaction is governed by a unique pyridyl carboxamide ligated catalyst, rather than the substrates. Moreover, this transformation shows excellent chemo‐ and regio‐selectivity and remarkably good functional‐group tolerance. We also demonstrate that under balloon pressure, ethylene can also be utilized as a substrate. Additionally, competence experiments indicate that selective bond formation is favored at the α‐position of boron and preliminary mechanistic studies indicate that the key step in this three‐component reaction involves a 1,2‐nickel migration.     

Design of a 1,8-naphthalimide-based OFF-ON type bioorthogonal reagent for fluorescent imaging in live cells

A novel 1,8-naphthalimide-based OFF-ON type fluorogenic sydnone (Naph-Syd) is designed as bioorthogonal probe for imaging. Sydnone moiety efficiently quenches the native fluorescence of 1,8-naphthalimide, which can be restored with the enhancement of about 300-fold, after reacting with strained cyclooctynes to form pyrazole products (Naph-Pyr). The second-order rate constant of this bioorthogonal cycloaddition can be up to 2.5 L mol^?1 s^?1, which benefits imaging of biomolecules at low concentrations in cellular environment.     

单轴双向加载分离式霍普金森压杆的数据处理方法

本文中提出单轴双向加载分离式霍普金森压杆（bidirectional-load split Hopkinson compression bar,BSHCB）,即在传统的分离式霍普金森压杆（split Hopkinson pressure bar,SHPB）的基础上增加另一个对称的入射波,两边的入射波同时且对称地对试样进行动态加载。根据一维应力波传播理论,推导出单轴双向加载分离式霍普金森杆的数据处理公式。通过数值模拟分析发现,所推导的数据处理公式可以用于计算单轴双向加载实验中试样的工程应力、工程应变和工程应变率。此外,单轴双向对称加载不仅可缩短试样内部应力均匀化的过程,而且可以提高试样应变率。