全文获取类型
收费全文 | 230篇 |
免费 | 31篇 |
国内免费 | 30篇 |
专业分类
化学 | 138篇 |
晶体学 | 6篇 |
力学 | 15篇 |
综合类 | 1篇 |
数学 | 69篇 |
物理学 | 62篇 |
出版年
2023年 | 5篇 |
2022年 | 4篇 |
2021年 | 9篇 |
2020年 | 13篇 |
2019年 | 10篇 |
2018年 | 8篇 |
2017年 | 9篇 |
2016年 | 10篇 |
2015年 | 9篇 |
2014年 | 10篇 |
2013年 | 15篇 |
2012年 | 35篇 |
2011年 | 31篇 |
2010年 | 28篇 |
2009年 | 23篇 |
2008年 | 10篇 |
2007年 | 6篇 |
2006年 | 10篇 |
2005年 | 10篇 |
2004年 | 1篇 |
2003年 | 8篇 |
2002年 | 4篇 |
2001年 | 2篇 |
2000年 | 3篇 |
1999年 | 3篇 |
1998年 | 4篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1994年 | 1篇 |
1992年 | 1篇 |
1990年 | 2篇 |
排序方式: 共有291条查询结果,搜索用时 31 毫秒
71.
Ultrasmall reduced graphene oxide with high near-infrared absorbance for photothermal therapy 总被引:2,自引:0,他引:2
Robinson JT Tabakman SM Liang Y Wang H Casalongue HS Vinh D Dai H 《Journal of the American Chemical Society》2011,133(17):6825-6831
We developed nanosized, reduced graphene oxide (nano-rGO) sheets with high near-infrared (NIR) light absorbance and biocompatibility for potential photothermal therapy. The single-layered nano-rGO sheets were ~20 nm in average lateral dimension, functionalized noncovalently by amphiphilic PEGylated polymer chains to render stability in biological solutions and exhibited 6-fold higher NIR absorption than nonreduced, covalently PEGylated nano-GO. Attaching a targeting peptide bearing the Arg-Gly-Asp (RGD) motif to nano-rGO afforded selective cellular uptake in U87MG cancer cells and highly effective photoablation of cells in vitro. In the absence of any NIR irradiation, nano-rGO exhibited little toxicity in vitro at concentrations well above the doses needed for photothermal heating. This work established nano-rGO as a novel photothermal agent due to its small size, high photothermal efficiency, and low cost as compared to other NIR photothermal agents including gold nanomaterials and carbon nanotubes. 相似文献
72.
Li Y Wang H Xie L Liang Y Hong G Dai H 《Journal of the American Chemical Society》2011,133(19):7296-7299
Advanced materials for electrocatalytic and photoelectrochemical water splitting are central to the area of renewable energy. In this work, we developed a selective solvothermal synthesis of MoS(2) nanoparticles on reduced graphene oxide (RGO) sheets suspended in solution. The resulting MoS(2)/RGO hybrid material possessed nanoscopic few-layer MoS(2) structures with an abundance of exposed edges stacked onto graphene, in strong contrast to large aggregated MoS(2) particles grown freely in solution without GO. The MoS(2)/RGO hybrid exhibited superior electrocatalytic activity in the hydrogen evolution reaction (HER) relative to other MoS(2) catalysts. A Tafel slope of ~41 mV/decade was measured for MoS(2) catalysts in the HER for the first time; this exceeds by far the activity of previous MoS(2) catalysts and results from the abundance of catalytic edge sites on the MoS(2) nanoparticles and the excellent electrical coupling to the underlying graphene network. The ~41 mV/decade Tafel slope suggested the Volmer-Heyrovsky mechanism for the MoS(2)-catalyzed HER, with electrochemical desorption of hydrogen as the rate-limiting step. 相似文献
73.
74.
75.
A novel amphotropic polymer which could exhibit liquid-crystalline behavior both in the solvent and in the heating process was synthesized through azo polymers grafting from cellulose nanocrystals (CNCs). The CNCs, prepared by acid hydrolysis of filter paper, were characterized by Atomic Force Microscopy (AFM). Poly{6-[4-(4-methoxyphenylazo)phenoxy] hexyl methacrylate}(PMMAZO), which was a liquid-crystalline polymers (LCP), was successfully to graft from CNC via Atom transfer radical polymerization (ATRP). The structure and thermal properties of the PMMAZO-grafted CNC were investigated using Fourier transform infrared spectroscopy (FT-IR) and thermogravimetric analyses (TGA). Its phase structures and transitions were studied by differential scanning calorimetry (DSC) and polarized optical microscopy (POM). The experimental results showed that the PMMAZO-grafted CNC exhibited both types of liquid crystal formation, thermotropic and lyotropic. 相似文献
76.
77.
78.
Yiren Zhong Dr. Yujun Xie Dr. Sooyeon Hwang Qian Wang Prof. Dr. Judy J. Cha Dr. Dong Su Prof. Dr. Hailiang Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(33):14107-14112
The energetic chemical reaction between Zn(NO3)2 and Li is used to create a solid-state interface between Li metal and Li6.4La3Zr1.4Ta0.6O12 (LLZTO) electrolyte. This interlayer, composed of Zn, ZnLix alloy, Li3N, Li2O, and other species, possesses strong affinities with both Li metal and LLZTO and affords highly efficient conductive pathways for Li+ transport through the interface. The unique structure and properties of the interlayer lead to Li metal anodes with longer cycle life, higher efficiency, and better safety compared to the current best Li metal electrodes operating in liquid electrolytes while retaining comparable capacity, rate, and overpotential. All-solid-state Li||Li cells can operate at very demanding current–capacity conditions of 4 mA cm−2–8 mAh cm−2. Thousands of hours of continuous cycling are achieved at Coulombic efficiency >99.5 % without dendrite formation or side reactions with the electrolyte. 相似文献
79.
80.
High sensitivity plasmonic temperature sensor based on a side-polished photonic crystal fiber 下载免费PDF全文
A high sensitivity plasmonic temperature sensor based on a side-polished photonic crystal fiber is proposed in this work.In order to achieve high sensitivity and high stability,the gold layer is coated on the side-polished photonic crystal fiber to support surface plasmon resonance.The mixture of ethanol and chloroform is used as the thermosensitive liquid.The performances of the proposed temperature sensor were investigated by the finite element method(FEM).Simulation results indicate that the sensitivity of the temperature sensor is as high as 7.82 nm/℃.It has good linearity(R;=0.99803),the resolution of 1.1×10;℃,and the amplitude sensitivity of 0.1008℃;.In addition,the sizes of the small air hole and polishing depth have little influence on the sensitivity.Therefore,the proposed sensor shows a high structure tolerance.The excellent performance and high structure tolerance of the sensor make it an appropriate choice for temperature measurement. 相似文献