基于碳纳米管和导电聚合物电刺激释放地塞米松导电生物膜的制备

为了降低植入式神经电极引起的炎性组织反应,通过层叠法构建可电刺激释放抗炎药物地塞米松的碳纳米管与聚吡咯双层导电生物膜(MWCNTs/Dex@PPy/Dex).并采用场发射扫描电镜(FESEM)、傅里叶变换红外光谱(FT-IR)、紫外分光光度法(UV)、循环伏安扫描(CV)和交流阻抗(EIS)对生物膜表面形貌、成分组成、药物释放特性和电化学性能进行考察.FESEM结果显示,MWCNTs/Dex@PPy/Dex生物膜呈现纤维状纳米结构,FT-IR光谱中含有与地塞米松类似的特征吸收峰.经过循环伏安电刺激释放地塞米松后,与PPy/Dex生物膜相比,MWCNTs/Dex@PPy/Dex导电生物膜阻抗更低,释放Dex总量更多,且释放时间更久.此外,PPy/Dex膜在205个循环发生脱落,而经过300个循环后,MWCNTs/Dex@PPy/Dex生物膜无明显肉眼可见变化,稳定性好,为提高电极的使用性能提供了思路.     

基于PXI总线的温控盒自动测试系统设计

温控盒作为飞机温度调节系统中的核心部件,在飞机运行安全中起着举足轻重的作用,需要对温控盒的各项参数进行详细测试。传统的温控盒测试设备普遍存在测试数据不精确、扩展性差以及测试人员操作繁琐、工作量大等缺点。提出了基于PXI总线的温控盒自动测试技术,阐述了其基本的测试原理以及具体软硬件实现方法,重点介绍了阻值动态分段逼近闭环设计及脉冲输出的低延时处理算法,完成了测试过程的一键自动化,拥有通用性、扩展性强、功能全面、智能化程序高等特点。     

Synthesis and characterization of a novel quercetin magnetic molecularly imprinted polymer via reversible addition fragmentation chain transfer strategy

Molecularly imprinted polymer (MIP) will be modified on the surface of the core-shell structure silica magnetic nanoparticles, during which quercetin is used as a template molecule, acrylamide as a functional monomer, azo-bisisobutyronitrile as an initiator and ethylene glycol dimethacrylate as a cross-linker, to synthesize highly efficient and selective quercetin magnetic molecularly imprinted nanoparticles via Reversible Addition-Fragmentation chain Transfer (RAFT) polymerization. FT-IR and X-ray diffraction (XRD) patterns are used to monitor the reaction and show the characteristic groups of each reaction step. Compared with the conventional bulk polymerization (2.7029 mg/g), the adsorption test showed that the MMIP by RAFT activity controlled polymerization had better absorption capacity for quercetin which the saturated adsorption amount was 4.8471 mg/g. Kinetic studies indicate that pseudo first order model is suitable to describe the adsorption mechanism. Thermodynamics experiment revealed that Langmuir model was more applied for explains the adsorption of quercetin onto magnetic molecularly imprinted polymer.     

A stochastic discrete model of tissue and its ultrasonic backscattering coefficient

TheprojectissupportedbyNationalNaturalScienceFoundationofChina.I.IntroductionU1trasonicpropagationandscatteringinthebiologica1softtissuesisabasicprob-lemofbiomedica1u1trasonics,andu1trasonicbackscatteringfromthetissucsproduccs..importantinformationfortissuecharacterizationaswe11asfortissueimagind'.2].Tissuemodellingisfundamentalfortheanalysisofultrasonicbackscattering.Vari-ousmode1shavebeensuggestedwithapartialsuccess.Sofar,therearetwomajortypesofmodc1s,theinhomogeneouscontinuummode1andthed…     

电池正极材料中Li~+运动特性的~7Li NMR研究

利用变温７ＬｉＮＭＲ实验对Ｌｉ电池正极材料ＬｉＭｎ２Ｏ４和ＬｉＣｏＯ２中Ｌｉ＋的运动特性进行了研究，结果表明，随实验温度的提高，ＬｉＭｎ２Ｏ４的７ＬｉＮＭＲ谱线窄化，表明其中Ｌｉ＋迁移能力增加，而ＬｉＣｏＯ２的谱线无变化．此外随温度提高，ＬｉＭｎ２Ｏ４的７Ｌｉ的Ｔ１变短，而ＬｉＣｏＯ２的Ｔ１变长，产生这种不同变化趋势的原因在于ＬｉＭｎ２Ｏ４和ＬｉＣｏＯ２晶相结构的差异造成其中Ｌｉ＋迁移能力的差别，它们各自的相关时间τｃ使７Ｌｉ核的Ｔ１分别位于Ｔ１－τｃ曲线极小点两侧     

用于测量流量和含沙量的超声波液位测定系统

本文介绍了实验室内用于测量流量和含沙量的超声波液位测定系统，此系统采用气介式方案，选用复合材料高频换能器作为超声波发射／接收器件，结构简单，静态测量时测量误差在１５０ｍｍ范围内不超过１ｍｍ，并可与微机进行远距离通讯。     

The effects of cement density and pipe dimension on casing waves in oil wells

The acoustic field in a cased hole is studied through numerical modeling by combining experiment measurement when the first and scond interfaces are bonded well.The effects of the density of the cement,the diameter and thickness of the steel pipe on the amplitude of casing arrival(ACA) are investigated,and a part of the numerical results are compared with the experimental results.These results show that the ACA decreases with the increasing density of the cement.There exists a large difference between the ACAs for the low-and normal-density cements.Therefore,the different standard should be taken in the bonding evaluation for cements with different densities.As the thickness of the steel pipe increases while its diameter keeps as a constant,the arrival time of the casing wave remains unvaried,while the ACA increases. But,when the diameter of the pipe with a constant thickness increases,the arrival time of the casing wave is delayed,and the ACA decreases.As for three kinds of the steel pipe commonly used in oilfields,the relative amplitude of the casing arrival is larger in the big pipe. In addition,the numerical results of the varying trend of the relative amplitude of the casing arrival with the density of cements,on the whole,are in agreement with the experimental ones.     

套管井中偏心对声场的影响分析*

目前在油田的实际应用中,声幅-变密度水泥胶结测井(CBL/VDL)在套管井的水泥胶结质量评价中发挥重要作用。但是,在一些大斜度井或者水平井中,往往由于仪器或者套管的重量等原因导致套管井中出现偏心现象,这给利用声波测井资料进行水泥胶结质量评价带来一些难题。为此,本文建立了套管偏心和仪器偏心两种情况下的三维声学模型,利用柱坐标系下的三维交错网格有限差分算法数值模拟了两种偏心情况下的声波传播情况,并着重研究了偏心率的变化对套管井中声场波形特征,尤其是套管波及地层波特征的影响。另外,模拟了具有不同外径尺寸的套管和偏心率的组合情况下的声场传播情况,在此基础上研究了偏心率的大小对声场特征的影响规律。本文的研究结果表明,套管偏心和仪器偏心均会给声场波形特征带来影响,且随着偏心率的增加而增大;相比较而言,仪器偏心对套管波的影响更大。     

MOOC起步,从微课程开始

文章在分析MOOC（慕课）内涵及其在教育中的实际意义基础上,提出课程建设是MOOC的核心工作,MOOC起步需要从微课程建设开始.文章结合大学物理精品资源共享课建设实例,介绍微课程的基本结构和研制方法.     

亚微米外部电光检测技术

将固浸透镜技术与电光检测技术相结合，建立了具有亚微米空间分辨率的外部电光检测系统，通过使用GaAs半球作外部电光探头，用数值孔径为0.3的显微物镜对波长为1.3μm的探测光束进行聚焦，得到了半峰全宽直径为0.7μm的聚焦光斑，成功测量了微带线上10kHz的正弦波信号，验证了系统的线性响应特性，并得到了6mV/√Hz的电压灵敏度。