Extracting the charm cross-section from its semileptonic decay at RHIC

We propose a sensitive measurement of the charm total cross-section at RHIC through muon identification from charm semileptonic decay at low transverse momentum (pT$p_T$). This can test the binary-collision scaling (Nbin$N_{\mathrm{bin}}$) properties of the charm total cross-section and be used to study whether heavy-flavor quarks, which are used as a probe, are produced exclusively at the initial impact in hadron–hadron collisions. The effect of the charm semileptonic decay form factor on extracting the total charm cross section and on the shape of the lepton spectra are also discussed in detail. We conclude that lepton spectra from charmed hadron decays at transverse momentum pT?1.0 GeV/c$p_T?1.0\text{GeV}/c$ are sensitive to the charmed hadron spectrum shape. Therefore, the interactions of heavy quarks with the medium created in relativistic heavy-ion collisions, especially the flow effects, can be extracted from the lepton spectra from charmed hadron decays at low pT$p_T$.     

On minor-minimally 3-connected binary matroids

A matroid M is called minor-minimally 3-connected if M is 3-connected and, for each e∈E(M), either M?e or M/e is not 3-connected. In this paper, we prove a chain theorem for the class of minor-minimally 3-connected binary matroids. As a consequence, we obtain a chain theorem for the class of minor-minimally 3-connected graphs.     

Cobalt Oxide Arrays Anchored to Copper Foam as Efficient Binder-free Anode for Lithium Ion Batteries

The development of lithium-ion batteries with simplified assembling steps and fast charge capability is crucial for current battery applications. In this study, we propose a simple in-situ strategy for the construction of high-dispersive cobalt oxide (CoO) nanoneedle arrays, which grow vertically on a copper foam substrate. It is demonstrated that this nanoneedle CoO electrodes provide abundant electrochemical surface area. The resulting CoO arrays directly act as binder-free anodes in lithium-ion batteries with the copper foam functioning as the current collector. The highly-dispersed feature of the nanoneedle arrays enhances the effectiveness of active materials, leading to outstanding rate capability and superior long-term cycling stability. These impressive electrochemical properties are attributed to the highly-dispersed self-standing nanoarrays, the advantages of binder-free constituent, and the high exposed surface area of the copper foam substrate compared to copper foil, which enrich active surface area and facilitate charge transfer. The proposed approach to prepare binder-free lithium-ion battery anodes streamlines the electrode fabrication steps and holds significant promise for the future development of the battery industry.     

Redox-Active Azulene-based 2D Conjugated Covalent Organic Framework for Organic Memristors

As a conjugated and unsymmetric building block composed of an electron-poor seven-membered sp² carbon ring and an electron-rich five-membered carbon ring, azulene and its derivatives have been recognized as one of the most promising building blocks for novel electronic devices due to its intrinsic redox activity. By using 1,3,5-tris(4-aminophenyl)-benzene and azulene-1,3-dicarbaldehyde as the starting materials, an azulene(Azu)-based 2D conjugated covalent organic framework, COF-Azu, is prepared through liquid-liquid interface polymerization strategy for the first time. The as-fabricated Al/COF-Azu/indium tin oxide (ITO) memristor shows typical non-volatile resistive switching performance due to the electric filed induced intramolecular charge transfer effect. Associated with the unique memristive performance, a simple convolutional neural network is built for image recognition. After 8 epochs of training, image recognition accuracy of 80 % for a neutral network trained on a larger data set is achieved.     

Janus-Type ESIPT Chromophores with Distinctive Intramolecular Hydrogen-bonding Selectivity

Excited-state intramolecular proton transfer (ESIPT)-based solid luminescent materials with multiple hydrogen bond acceptors (HBAs) remain unexplored. Herein, we introduced a family of Janus-type ESIPT chromophores featuring distinctive hydrogen bond (H-bond) selectivity between competitive HBAs in a single molecule. Our investigations showed that the central hydroxyl group preferentially forms intramolecular H-bonds with imines in imine-modified 2-hydroxyphenyl benzothiazole (HBT) chromophores but tethers the benzothiazole moiety in hydrazone-modified HBT chromophores. Imine-derived HBTs generally exhibit higher fluorescence efficiency, while hydrazone-derived HBTs show a reduced overlap between the absorption and fluorescence bands. Quantum chemical calculations unveiled the molecular origins of the biased intramolecular H-bonds and their impact on the ESIPT process. This Janus-type ESIPT chromophore skeleton provides new opportunities for the design of solid luminescent materials.